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Outline of Lecture 1

Carbohydrates

Chemistry of Carbohydrates • Definition

Dr. Md. Golam Mortuza • Classification


Professor
Dept of Biochemistry & Molecular Biology • Structures of D-aldoses
BAU, Mymensingh
• Q &A

Definition of Carbohydrates Definition of Carbohydrates

The Carbohydrates are composed of C, H, and O;


the H & O being present ordinarily in the same Composition: C, H, and O
proportion as they are in water.
Empirical formula: (CH2O)n; n ≥ 3
Thus carbohydrates have the empirical formula (CH2O)n
where n is three or more.

Definition of Carbohydrates Definition of Carbohydrates


However, some carbohydrates do not conform to this
empirical formula such as – The Carbohydrates are composed of C, H, and O; the
• Deoxyribose (C5H10O4) H & O being present ordinarily in the same proportion
as they are in water…..the empirical formula (CH2O)n.
• Rhamnose (C6H12O5)

On the other hand, some compounds conform this


empirical formula, but they are not carbohydrates Conditions for a compound to be carbohydrate
- lactic acid (C3H6O3) are as follows:
- acetic acid (C2H4O2) • It must possess carbonyl group
Moreover, a large number of carbohydrates contain N, • It must possess at least two hydroxyl groups.
P or S in addition to C, H and O. Hence this is not a
definition.

1
Definition of Carbohydrates Classification
A satisfactory definition of carbohydrates is as follows: Carbohydrates
Polyhydroxy aldehydes or ketones and their
derivatives or as substances that yield one of these
compounds on hydrolysis. As for example, glucose, Monosac. Derived CHO Oligosac. Polyosac.
sucrose, starch etc. Carbohydrates are often called eg. Glucose eg. Glucoseamine eg. Maltose eg. Amylose
“saccharide” which is derived from the Greek word
Triose
“saccharon” meaning sugar. Pentose
Aldose
Ketose
Hexose
Classification
Carbohydrates Aldohexose
Ketohexose

MonoSac. Derived CHO Oligosac. Polyosac.


eg. Glucose eg. Glucoseamine eg. Maltose eg. amylose

A. Classification according to complexity


B: Classification according to functions
Monosaccharides Oligosaccharides Polysaccharides Derived CHO

Number of Functional Kind of


Carbon Group Sugar unit Function Origin
atoms
I. Building block carbohydrates.

Homoglycan Structural Plant


eg. monosaccharides (glucose)
Trioses
Aldoses Ketoses eg. Starch, eg. Cellulose, eg.
eg. Glyceralde-
eg. eg. Cellulose etc Chitin etc Cellulose
II. Storage carbohydrates
hydes Glyceral- Dihydroxy Heteroglycan Storage
Dihydroxy -
dehyde, acetone eg. Heparin, eg. Starch, Animal
eg. starch, glycogen and inulin.
acetone
Erythrose Erythrulose Peptidoglycan Glycogen Eg.
Tetrose
Ribose, Ribulose Hyaluronic Glycogen
III. Structural carbohydrates
eg,. Erythrose
Glucose Fructose acid etc
Erythrulose eg. cellulose and chitin.
Pentose
eg. Ribose, Sugar Sugar acids Amino Sugar Deoxy
Ribulose alcohols Gluconic acid sugars phosphate sugar
Hexoses  Sorbitol Glucouronic D-Glc- 4-Glucose - eg. Deoxy-
eg. Glucose,  Mannitol acid amine 6-P ribose
Fructose
Heptoses
eg. Disaccharides Trisaccharides Tetrasaccharides Pentasaccharides
Sedoheptulose o Maltose o Raffinose o Stachyose o Verbascose
o Sucrose

Structures of
D-aldoses Notes
 Glycose = Monosac.
 Glycan = Polysac.
 Glucan = Glucosan …
 Fructan = fructosan = Levan
 Mannan = ?
 Pentosan = ?
 Cellulose ≠ Hemicellulose
 Dextran = ….. (Dextrin ?)
 Dextrose = …. ?

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