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Chapter (15)
CHEMISTRY IN SOCIETY
Photosynthesis Reaction
sun light in green plants
6CO2 (g) + H2O (l) → C6H12O6 (s) + 6O2 (g)
Soil
The soil is the source of plant
nutrients. It supplies water and other
elements to the plants. Plants absorb
their mineral nutrients from the soil
in the form of dissolved salts.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Fertilizers
Fertilizers are substances that supply nutrients to plants. They may
be classified as natural and chemical fertilizers.
Natural Fertilizers
There are two types of natural fertilizers.
- manure and
- humus.
Manure
Manure is obtained by the decomposition of animal dung and urine.
Humus
Humus comes from plant residues.
The Reason of Using Chemically synthesized Fertilizers
Although natural fertilizers are excellent nutrients for plants, these
are not enough for adequate yields. Therefore chemically synthesized
fertilizers are used to supplement this need.
Chemical Fertilizers
Chemical fertilizers are salts and other compounds containing
elements necessary for plant growth. Roots of plants absorb the food from
the soil in the form of soluble salts.
Nitrogen, Phosphorus and Potassium (NPK)
The most important elements required by plants from the soil are
nitrogen, phosphorus and potassium (NPK) because these elements are
essential for the growth of plants. The basic composition of chemical
fertilizers may constitute any one, two or all three of these elements.
Effects of Nitrogen, Phosphorus and Potassium on Plants
Nitrogen and phosphorus are essential and important constituents of
plant’s body. Potassium is not a constituent element of the plant. It occurs
in plants as soluble salts. Its role is catalytic.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Phosphate Fertilizers
Superphosphate
The important phosphate fertilizer is superphosphate.
The formula of superphosphate is Ca(H2PO4).2CaSO4.
Superphosphate is marketed in two grades containing 18 and 42
percent phosphoric acid respectively.
18% superphosphate contains 18 % P4O10 solution in water.
42% superphosphate contains 42 % P4O10 solution in water.
Superphosphate is a white or grey powder or granule.
Bone Meal
It is not a chemical fertilizer. It is prepared by crushing defatted
bones. It contains about 3 % nitrogen and 22 % phosphoric acid.
Therefore it is used as phosphate fertilizer.
Potassium Fertilizers
The important potassium fertilizers are potassium chloride and
potassium sulphate.
Test for Soil Reaction
Soil reaction is easily tested by litmus paper.
Acidity and Alkalinity of the Soil
Acidity and alkalinity of the soil is one of the important factors
because the plants do not grow well on the soil of high acidity and
alkalinity.
Neutralization of Soil Acids
Lime is added to the soil to neutralize the soil acids. Lime is usually
supplied to the soil as limestone(CaCO3), quicklime (CaO) and slaked
lime (Ca(OH)2).
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Cement Production
Cement
Cement is a grey powder which is used in construction of building.
It is used as binder in construction works. It is mixed with sand and water,
and sometimes with quicklime, CaO.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
(i) Mixing
Limestone, haematite and clay are finely ground and mixed in the
right proportions.
(ii) Heating
The ground mixture is fed continuously from the top end of the
Rotary Kiln and heated by the burning gas at the lower end of the Kiln.
As the mixture moves slowly down the inclined Kiln, it meets an
increasingly higher temperature. The roasted product which is called
clinker comes out from the lower end of the Kiln.
(iii) Cooling
The roasted clinker is allowed to cool in a rotation cylinder by cool
air.
(iv) Grinding
After cooling, the clinker is mixed with the right percentage of
gypsum, CaSO4.2H2O, and ground in a grinding mill. The resultant
powder is cement. The gypsum regulates the setting time of cement.
POP
Plaster of Paris (POP) is a fine white powder which is used for
making cast of various objects and for cementing glass to metals. It is
hydrated calcium sulphate (2CaSO4.H2O).
POP is obtained by heating gypsum, CaSO4.2H2O to about1250C.
∆ 1250 𝐶
2CaSO4.2H2O → 2CaSO4.H2O + 2H2O
gypsum POP
Usage of POP
POP is used for making casts and for cementing glass to metals.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Salt Production
solubilities
Al2O3 KCl
Increasing
CaCO3 MgSO4
CaSO4 MgCl2
MgBr2
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
(ii) Wood fires are used and considerable areas of forest are
destroyed yearly. Approximately, 15,000 acres of forest are
depleted every year due to the use of firewood in this method.
Prevention of Forest
Prevention of unnecessary wastage of forests may be achieved by
using solar evaporation for production of salt.
Bittern
The water that flows out from the fifth solar pond consists of
dissolved MgSO4, MgCl2 and MgBr2. This water is called bittern. Bittern
is the source from which MgSO4, MgCl2 and MgBr2 can be extracted.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Synthesis Polymers
Synthesis polymers called plastic are to be found everywhere in
modern technological societies, made into bulky objects, films and fibers.
They have properties to suit particular need, ranging from car and aircraft
components, to packaging and clothing.
Polymers
Polymers are large organic macromolecules. They are made up of
small repeating units known as monomers.
Homopolymers
Homopolymers are polymers just containing one monomer.
Poly(ethene), poly(propene) and poly(chloroethene) are examples of
homopolymers.
Copolymers
Copolymers are made of two or more different types of monomers.
For example, nylon is made from two monomers, and biological proteins
are made from 20 different monomers, the amino acids.
Addition Polymerization
(1) Ethene to Polyethene (Polyethylene)
high pressure
ethene heat,catalyst polyethene
H H H H
high pressure
n C C heat,catalyst C C
H H H H n
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
propene polypropene
H H H H
n C C C C
H CH3 H CH3 n
chloroethene polychloroethene
(vinyl chloride) (PVC)
H H H H
n C C C C
H Cl H Cl n
tetrafluoroethene poly(tetrafluoroethene)
F F F F
n C C C C
F F H F n
1. Polyethene or polyethylene
monomer - ethene CH2=CH2
properties - tough, durable
uses - plastic bags, bowls, bottles, packaging
2. Polypropene or polypropylene (PP)
monomer - propene CH2-CH=CH2
properties - tough, durable
uses - crates and boxes, plastic rope
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
3. Polychloroethene or polyvinyl chloride (PVC)
monomer - vinyl chloride CH2=CHCl
properties - strong, hard
uses - insulation, pipes and guttering
4. Polytetrafluoroethene or polytetrafluoroethylene (PTFE)
monomer - tetrafluoroethene CF2=CF2
properties - non-stick surface, withstand high temperature
uses - non-stick frying pans, non-stick taps and joints
5. Polyphenylethene or polystyrene (PS)
monomer - phenylethene or syrene C6H5-CH=CH2
properties - light, poor conductor or heat
uses - insulation, packaging (foam)
Condensation Polymerization
Nylon (polyamide)
Nylon is a copolymer of two different monomers, a diamine and a
dicarboxylic acid. Each monomer consists of a chain of carbon atoms. At
both ends of the monomers are functional groups. An amine group
(NH2) on the first monomer reacts with a carboxylic acid group ( -COOH)
on the second monomer to make a link between the two molecules. Each
time a link is made, a water molecule is lost:
These type of polymer is known as a condensation polymer.
Because an amide link (or peptide link) is formed during polymerization,
nylon is known as polyamide. A version of nylon polymerization can be
carried out in the laboratory.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Polyester
Condensation polymerization can also be used to make other
polymer with properties different from those of nylon. Polyester are
condensation copolymers made from two monomers. One monomer has
an alcohol group (-OH) at each end. The other monomer has a carboxylic
acid group (-COOH) at each end. When the monomers react, an ester
link is formed, with water being lost each time.
One such polymer has the trade name of terylene. Like nylon,
terylene can be turned into fibres and woven into clothing. Terylene
clothing is generally softer than that made from nylon.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
Soaps
Soap is manufactured by heating natural fats and oils of either plants
on animals with a strong alkali. The fats and oils, called triglycerides, are
complicated ester molecules.
Saponification
Fat is boiled with aqueous sodium hydroxide to form soap. The
esters are broken down in the presence of water-hydrolysed. This type of
reaction is called saponification.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
H35C17-COOCH2 HO-CH2
H35C17-COOCH + 3NaOH → 3C17H135COONa + HO-CH
H35C17-COOCH2 HO-CH2
Soapless Detergent
Soapless detergents do not form scum with hard water since they do
not react with Ca2+ and Mg2+ present in such water. Furthermore, these
soapless detergent molecules have been designed so that they are
biodegradable. Bacteria readily break down these new molecules so that
they do not persist in the environment.
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Chapter (15)
CHEMISTRY IN SOCIETY
Compiled by
Minn Thant
Reference
Grade 11 Chemistry Text
Chemistry in Society by Dr. Soe Kyaw Kyaw
Second time edition published at
FUTURE LIGHT
Cover design and Layout
Minn Thant
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
1. What is cement?
2. Name the four main stages in the manufacturing process of cement.
3. What are the raw materials used in the manufacturing process of
cement?
4. What are the chief compounds present in cement?
5. Why is gypsum mixed with clinker and ground in the final stage of
cement production?
6. Write down the chemical composition of POP. Illustrate its uses.
7. What is POP? Describe how POP is obtained from gypsum.
8. Why is gypsum mixed with clinker and ground in the final stage of
cement production?
9. Explain the usage of Plaster of Paris.
The only real failure in life is not to be true to the best one knows. (Buddha)
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
6. Name the principal areas for the production of common salt from
sea water. What is the major impurity that causes common salt to
become damp?
7. Why does common salt become damp when it is exposed to the air?
8. What are the disadvantages for the production of common salt by
the traditional method?
9. Why is common salt obtained by traditional method not very stable
for industrial use?
10. Common salt obtained by traditional method is not pure? Why?
11. Describe the substances that remain in the solution after the
crystallization of sodium chloride.
12. What is bittern? What compounds can be extracted from the bittern?
13. In the traditional method of salt production, considerable areas of
forest are destroyed. How would you prevent it?
14. Write down the advantages of salt production by solar evaporation.
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Saya Minn Thant (B.Ed.) MATRICULATION CHEMISTRY Chemistry in Society
10. What monomer will polymerize to produce PVC? Write the
equation. What type of polymerization would chloroethene
undergo?
11. Draw the structural formula of tetrachloroethene and suggest the
name of the polymer formed from it. Write down the equation.
Draw the structural formula and suggest the trade name of the
polymer formed from tetrafluoroethene.
12. (i) What type of polymerization would CH3CH=CH2 undergo?
Write down the equation.
(ii) What type of polymerization can occur for the following
compounds can undergoes? Write down the equations.
CH3-CH=CH2, CF2=CF2, C6H5CH=CH2, OH-CH2-CH2
HOOC-CH2-CH2-COOH, HOCH2CH2OH
13. What type of polymerization can occur for the following
compounds? Write down the equations.
H2N NH2 and HOOC COOH
14. How do you understand the term ‘polyester’?
15. Draw the structural formulae of nylon and terylene.
16. What are the differences between ‘polyamides’ and ‘polyesters’?
17. Discuss any two properties of addition polymers.
18. What are the methods for recycling plastic wastes?
19. Classify the type of nylon based on the type of reaction, type of bond
formed and monomers used. Define the type of bond formed.
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