Fiitjee: Solutions To JEE (Main) - 2021

FIITJEE
Solutions to JEE(Main) -2021

Test Date: 22nd July 2021 (Second Shift)
PHYSICS, CHEMISTRY & MATHEMATICS

Paper - 1
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
5. Section – B : Do any 5 questions out of 10 Questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (01 – 10) contains 10 Numerical based questions with answer as numerical
value. Each question carries +4 marks for correct answer. There is no negative marking.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (22nd July-Second Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. A body is projected vertically upwards from the surface of earth with a velocity sufficient
enough to carry it to infinity. The time taken by it to earth reach height h is_________s.
3 3
2Re  h  2  1 2Re  h  2 
(A) 1   1 (B) 1   1
g  R e   3 g  R e  
   
3 3
1 R e  h  2  Re  h  2 
(C) 1  1 (D) 1   1
3 2g  Re   2g  Re  
   
Q2. An electron of mass me and a proton of mass mp are accelerated through the same
potential difference. The ratio of the de-Broglie wavelength associated with the electron
to that with the proton is :
mp
(A) (B) 1
me
me mp
(C) (D)
mp me
 
Q3. What will be the projection of vector A  î  ˆj  kˆ on vector B  î  ˆj ?

(A) 2 î  ˆj  kˆ  (B)  
2 î  ˆj

(C) î  ˆj  (D) 2  î  ˆj  kˆ 
Q4. A ray of light passes from a denser medium to a rarer

medium at an angle of incidence i. The reflected and
refracted rays make an angle of 90 with each other.
The angle of reflection and refraction are respectively i r
r and r’. The critical angle is given by :
(A) sin1 cot r 
r'
(B) tan1  sin i 
(C) sin1  tanr ' 
(D) sin1  tanr 
Q5. A nucleus with number 184 initially at rest emits an   particle. If the Q value of the
reaction is 5.5 MeV, calculate the kinetic energy of the   particle.
(A) 5.5 MeV (B) 5.38 MeV
(C) 5.0 MeV (D) 0.12 MeV
Q6. Intensity of sunlight is observed as 0.092 Wm2 at a point in free space. What will be the
peak value of magnetic field at that point?  0  8.85  1012 C2 N1 m 2 
(A) 5.88 T (B) 1.96  108 T
(C) 8.31 T (D) 2.77  10  8 T
Q7. In a circuit consisting of a capacitance and a generator

with alternating emf Eg  Eg sin t, VC and I C are the
0
voltage and current. Correct phase diagram for such Eg IC CVC

circuit is :
IC IC VC
VC
(A) (B)
t t
VC VC
t t
(C) (D)
IC IC
Q8. Consider a situation in which reverse biased current of a particular P – N junction

increase when it is exposed to a light of wavelength  621 nm. During this process,
enhancement in carrier concentration takes place due to generation of hole – electron
pairs. The value of band gap is nearly.
(A) 1 eV (B) 4 eV
(C) 0.5 eV (D) 2 eV
Q9. A porter lifts a heavy suitcase of mass 80kg and at the destination lowers it down by a
distance of 80 cm with a constant velocity. Calculate the work done by the porter in
lowering the suitcase.
 take g  9.8 ms  2
(A) 627.2 J (B) 62720.0 J

(C)  627.2 J (D) 784.0 J
Q10. Match List – I with List – II :
List – I List – II
1
(a) L  (i) Current is in phase with emf
C
1
(b) L  (ii) Current lags behind the applied emf
C
1
(c)  L  (iii) Maximum current occurs
C
(d) Resonant frequency (iv) Current leads the emf
Choose the correct answer from the options given below :

(A)  a    iv ; b    iii ;  c   ii  ;  d  i  (B)  a    ii ; b   i  ;  c   iv ;  d   iii 
(C)  a    iii ; b   i  ;  c   iv  ;  d  ii  (D)  a    ii ; b   i  ;  c   iii ;  d   iv 
Q11. T0 is the time period of a simple pendulum at a place. If the length of the pendulum is
1
reduced to times of its initial value, the modified time period is :
16
(A) T0 (B) 8  T0
1
(C) 4 T0 (D) T0
4
Q12. Statement I : The ferromagnetic property depends on temperature. At high temperature,

ferromagnet becomes paramagnet.
Statement II : At high temperature, the domain wall area of a ferromagnetic substance

increases.
In the light of the above statements, choose the most appropriate answer from the
options given below :
(A) Both Statement I and Statement II are false
(B) Statement I is true but Statement II is false
(C) Statement I is false but Statement II is true
(D) Both Statement I and Statement II are true
Q13. A bullet of ‘4 g’ mass is fired from a gun of mass 4 kg. If the bullet moves with the muzzle
speed of 50 ms-1, the impulse imparted to the gun velocity of recoil of gun are :
(A) 0.4kg ms1, 0.1 ms1 (B) 0.2 kg ms1, 0.05 ms1
(C) 0.4 kg ms1,0.05 ms1 (D) 0.2 kg ms1,0.1 ms1
Q14. What should be the height of transmitting antenna and the population covered if the
television telecast is to cover a radius of 150 km? The average population density
around the tower is 200 / km2 and the value of Re  6.5  106 m.
(A) Height = 1800 m
Population Covered  1413  108
(B) Height  1241 m

(C) Height = 1600 m

(D) Height  1731 m

Q15. Choose the correct option :

(A) True dip is not mathematically related to apparent dip.
(B) True dip is always greater than the apparent dip.
(C) True dip is always equal to apparent dip.
(D) True dip is less than the apparent dip.
Q16. The motion of a mass on a spring, with spring constant K is

as shown in figure. The equation of motion is given by
K
x  t   A sin  t  B cos t with  
. Suppose that at time
m x
t  0, the position of mass is x  0  and velocity   0  , then its
displacement can also be represented as x  t   Ccos  t    ,
where C and  are :
2 2
 0  2  x 0   2  0  2  x 0  
(A) C   x  0  ,   tan1  (B) C   x  0  ,   tan1 
 2    0    2  2  0  
   
2 2
 0 2   0  2  0  2   0  
(C) C   x  0  ,   tan 1
(D) C   x  0  ,   tan1 
 2  x  0     2  x  0   
   
Q17. What will be the average value of energy for a monoatomic gas in thermal equilibrium at
temperature T ?
3 1
(A) kBT (B) kB T
2 2
2
(C) kB T (D) kB T
3
Q18. Consider a situation in which a ring, a solid cylinder and a solid sphere roll down on the
same inclined plane without slipping. Assume that they start rolling from rest and having
identical diameter.
The correct statement for this situation is :
(A) The ring has the greatest and the cylinder has the least velocity of the centre of mass
at the bottom of the inclined plane.
(B) The sphere has the greatest and the ring has the least velocity of the centre of mass
at the bottom of the inclined plane.
(C) The cylinder has the greatest and the sphere has the least velocity of the centre of
mass at the bottom of the inclined plane.
(D) All of them will have same velocity.
Q19. A Copper  Cu  rod of length 25cm and cross – Cu
sectional area 3 mm2 is joined with a similar A
B
aluminium  Al  rod as shown in figure. Find the
Al
resistance of the combination between the ends A
and B.
(Take Resistivity of Copper  1.7  10 8 m
Resistivity of Aluminium  2.6  10 8 m )
(A) 0.858 m (B) 0.0858 m
(C) 1.420 m (D) 2.170 m
Q20. An electric dipole is placed on x – axis in proximity to a line charge of linear density
3.0  106 C / m. Line charge is placed on z –axis and positive and negative charge of
dipole is at a distance of 10 mm and 12 mm from the origin respectively. If total force of
4 N is exerted on the dipole, find out the amount of positive charge of the dipole.
(A) 0.485 mC (B) 8.8 C
(C) 815.1 nC (D) 4.44 C
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. The position of the centre of mass of a uniform semi – circular wire of radius ‘R’ placed in
x – y plane with its centre at the origin and the line joining its ends as x-axis is given by
 xR 
 0,  . Then, the value of | x | is __________.
  
Q2. The total charge enclosed in an incremental volume of 2  10  9 m3 located at the origin is
________nC, if electric flux density of its field is found as
D  e x sin yiˆ  e  x cos y ˆj  2zkC
ˆ / m2 .
Q3.  
A ray of light passing through a prism   3 surface minimum deviation. It is found that
the angle of incidence is double the angle of refraction within the prism. Then, the angle
of prism is ________(in degrees).
Q4. The centre of a wheel rolling on a plane surface moves with a speed 0 . A particle on the
rim of the wheel at the same level as the centre will be moving at a speed x 0 . Then
the value of x is _________.
Q5. Three students S1 ,S2 andS3 perform an experiment for determining the acceleration due to
gravity (g) using a simple pendulum. They use different lengths of pendulum and record
time for different number of oscillations. The observations are as shown in the table.
Student Length of No. of oscillations Total for n Time
No. Pendulum (cm) (n) oscillations period (s)
1 64.0 8 128.0 16.0
2 64.0 4 64.0 16.0
3 20.0 4 36.0 9.0
(Least count of length = 0.1 cm
least count for time = 0.1 s)
If E1 , E2 and E3 are the percentage errors ‘g’ for students 1, 2 and 3 respectively, then
the minimum percentage error is obtained by student no.__________.
Q6. In 5 minutes, a body cools from 75 C to 65 C at room temperature of 25 C. The
temperature of body at the end of next 5 minutes is _________  C .
Q7. The area of cross – section of a railway track is 0.01 m2 . The temperature variation is
10 C, Coefficient of liner expansion of material of track is 10  5 / C. The energy stored per
meter in the track is __________J/m.
(Young’s modulus of material of track is 1011 Nm2 )
Q8. In an electric circuit, a cell of certain emf provides a potential difference of 1.25 V across
a load resistance of 5  . However, it provides a potential difference of 1 V across a load
x
resistance of 2  . The emf of the cell is given by V. Then the value of x is _________.
10
Q9. In a given circuit diagram, a 5 V zener I I2

diode along with a series resistance is I1
R
connected across a 50 V power supply.
The minimum value of the resistance RL Vz
Vi=50V z
required, if the maximum zener current
is 90 mA be _________  .
 
Q10. Three particles P,Q and R are moving along the vectors A  î  ˆj, B  ˆj  kˆ and

C  î  ˆj respectively. They strike on point and start to move in different directions. Now
 
particle P is moving normal to the plane which contains vector A and B. Similarly particle
 
Q is moving normal to the plane which contains vector A and C. The angle between the
 1 
direction of motion of P and Q cos1   . Then the value of x is _________.
 x
PART – B (CHEMISTRY)
SECTION - A
Q1. Which one of the following compounds will provide a tertiary alcohol on reaction with
excess of CH3MgBr followed by hydrolysis?
O
OCH2CH3
NC
(A) (B)
C
O CH
O
O CH3
CH3
(C) (D)
O
OH
Q2. When silver nitrate solution is added to potassium iodide solution then the sol produced
is:
(A) AgI / I  (B) AgNO3 / NO3
(C) KI / NO3 (D) AgI / Ag
Q3. Isotope(s) of hydrogen which emits low energy   particles with t 1 value > 12 years is /
2
are:
(A) Protium (B) Tritium
(C) Deuterium (D) Deuterium and Tritium
Q4. Which one of the following 0.06 M aqueous solutions has lowest freezing point ?
(A) KI (B) C6H12 O6
(C) K 2SO4 (D) Al2 SO 4 3

(Species) (Hybrid Orbitals)
(a) SF4 (i) sp3 d2
(b) IF5 (ii) d2 sp3
(c) NO 2 (iii) sp3 d
(d) NH4 (iv) sp3
(v) sp

(A) (a) (iii) , (b) (i), (c) (v) and (d) (iv)
(B) (a) (ii), (b) (i), (c) (iv) and (d) (v)
(C) (a) (i), (b) (ii), (c) (v) and (d) (iii)
(D) (a) (iv), (b) (iii), (c) (ii) and (d) (v)
Q6. Which one of the following compounds does not exhibit resonance?
(A) CH3 CH2 CH2CONH2
(B) CH3 CH2 CH  CHCH2NH2
(C) CH3 CH2 OCH  CH2
CH2OH
(D)
Q7. The set having ions which are coloured and paramagnetic both is :
(A) Ni2  ,Mn7  ,Hg2  (B) Cu ,Zn2  ,Mn4 
(C) Sc 3 , V 5  ,Ti4 (D) Cu2 ,Cr 3  ,Sc 
Q8. An organic compound A  C6H6 O  gives dark green colouration with ferric chloride. On
treatment with CHCl3 and KOH, followed by acidification gives compound B. Compound B
can also be obtained from compound C on reaction with pyridinium chlorochromate
(PCC). Identify A, B and C.
OH CH2OH OH
OH CHO
(A)
A= B= C=
CH2OH OH OH
OH CHO
(B)
A= B= C=
OH CH2OH OH
CHO OH
(C)
A= B= C=
OH OH
OH CHO CH2OH
(D)
A= B= C=
Q9. Given below are the statements about diborane.

(a) Diborane is prepared by the oxidation of NaBH4 With I2.
(b) Each boron atom is in sp2 hybridized state.
(c) Diborane has one bridged 3 centre – 2 – electron bond.
(d) Diborane is a planar molecule.
The option with correct statement(s) is :
(A) (a) only (B) (c) only
(C) (a) and (b) only (D) (c) and (d) only

(a) Chloroprene (i)
Cl
(b) Neoprene (ii)
Cl
(c) Acrylonitrile
(iii)
CH2
(d) Isoprene (iv) CH2 = CH - CN

(A)  a    iii , b    i , c   iv  ,  d  ii  (B)  a    iii , b    iv ,  c    ii ,  d   i 
(C)  a    ii , b   i  ,  c   iv  ,  d  iii  (D)  a    ii , b   iii , c   iv  ,  d   i 
Q11. Which one of the following molecules does not show stereo isomerism ?
(A) 3 – Ethylhex – 3 – ene (B) 3 – Methylhex – 1 – ene
(C) 3,4 – Dimethylhex – 3 – ene (D) 4 – Methylhex – 1 – ene
Q12. Sulphide ion is soft base and its ores are common for metals.
(a) Pb (b) Al
(c) Ag (d) Mg
(A) (c) and (d) only (B) (a) and (c) only
(C) (a) and (d) only (D) (a) and (b) only
Q.13. N2 Cl
CH2CH3
B, Anhyd. AlCl 3
+ A + H 2O
Major Product
In the chemical reactions given above A and B respectively are:
(A) CH3 CH2 OH and H3PO2 (B) CH3 CH2 Cl and H3PO2
(C) H3PO2 and CH3 CH2 OH (D) H3PO2 and CH3 CH2 Cl

(Elements) (Properties)
(a) Ba (i) Organic solvent soluble compounds
(b) Ca (ii) Outer electronic configuration 6s 2
(c) Li (iii) Oxalate insoluble in water
(d) Na (iv) Formation of very strong monoacidic base
(A) (a) (ii), (b) (iii), (c) (i) and (d) (iv)
(B) (a) (iv), (b) (i), (c) (ii) and (d) (iii)
(C) (a)  (i), (b) (iv), (iii) (ii) and (d) (iii)
(D) (a) (iii), (b) (ii), (c) (iv) and (d) (i)
Q15. Which one of the following group – 15 hydride is the strongest reducing agent ?
(A) AsH3 (B) SbH3
(C) BiH3 (D) PH3
Q16. Thiamine and pyridoxine are also known respectively as :

(A) Vitamin B1 and Vitamin B6 (B) Vitamin E and Vitamin B2
(C) Vitamin B6 and Vitamin B2 (D) Vitamin B2 and Vitamin E
Q17. Which one of the following reactions does not occur?

NH2 NH2
+ +
(A) AlCl 3
CH3
NH2 NH2
+
(B) HNO 3 / H2SO
NO 2
NH2 NHCOCH3
(C) +
(CH3CO)2
NH2 NH2
+
(D) H2SO
SO 3H
Q18. Which one of the following statements for D.I. Mendeleeff, is incorrect?
(A) At the time, he proposed periodic table of elements structure of atom was known.
(B) Element with atomic number 101 is named after him.
(C) He invented accurate barometer.
(D) He authored the textbook – Principles of Chemistry.
Q19. The water having more dissolved O 2 is :

(A) Water at 80 C (B) boiling water
(C) polluted water (D) water at 4 C
Q20. Which purification technique is used for high boiling organic liquid compound
(decomposes near its boiling point) ?
(A) Fractional distillation (B) Steam distillation
(C) Simple distillation (D) Reduced pressure distillation
SECTION - B
decimal place).
Q1. The total number of unpaired electrons present in Co NH3 6  Cl2 and Co NH3 6  Cl3 is -.
1
Q2. N2 O5 g  2NO2 g  O
2 2  g
In the above first order reaction the initial concentration of N2 O5 is 2.40  102 mol
L1 at 318K. The concentration of N2 O5 after 1 hours was 1.60  102 mol L1 . The rate
constant of the reaction at 318K is _________ 103 min1 . ( Nearest integer )
[Given : log3  0.477,log5  0.699 ]
Q3. Number of electrons that Vanadium  Z  23  has in p-orbitals is equal to ----------.
Q4. If the standard molar enthalpy change for combustion of graphite powder is
2.48  102 kJ mol1, the amount of heat generated on combustion of 1 g of graphite
powder is _________ kJ. (Nearest integer)
Q5. 

Value of K p for the equilibrium reaction N2 O4g 
 2NO2 g at 288 K is 47.9. The K c for this
reaction at same temperature is __________. (Nearest integer)
( R  0.083 L bar K 1 mol1 )
Q6. A copper complex crystallizing in a CCP lattice with a cell edge of 0.4518 nm has been
revealed by employing X-ray diffraction studies. The density of a copper complex is
found to be 7.26 gcm3 . The molar mass of copper complex is __________ g mol-1.
(Nearest integer)
[Given : NA  6.022  1023 mol1 ]
Q7. The number of acyclic structural isomers (including geometrical isomers) for pentene is
_.
Q8. Assume a cell with the following reaction

Cu s  2Ag 1 10 3 M  Cu 2  0.250M   2 Ag s  Ecell

 2.97 V
Ecell for the above reaction is ____________V. (Nearest integer)
[ Given : log2.5  0.3979,T  298K]
Q9. Methylation of 10g of benzene give 9.2g of toluene. Calculate the percentage yield of
toluene __________. (Nearest integer)
Q10. If the concentration of glucose  C6H12O6  in blood is 0.72 g L1, the molarity of glucose in
blood is __________ 103 M. (Nearest integer)
(Given : Atomic mass of C  12,H  1,O  16u )
PART – C (MATHEMATICS)
SECTION - A
Q1. Let the circle S : 36x 2  36y 2  108x  120y  C  0 be such that it neither intersects nor
touches the co-ordinate axes. If the point of intersection of the lines, x  2y  4 and
2x  y  5 lies inside the circle S, then :
(A) 81  C  156 (B) 100  C  165
25 13
(C) 100  C  156 (D) C
9 3
Q2. If the shortest distance between the straight lines 3  x  1  6  y  2   2  z  1 and

1
4  x  2   2  y      z  3 ,   R is , then the integral value of  is equal to :
38
(A) 3 (B) 2
(C) 1 (D) 5
Q3. Let n denote the number of solutions of the equation z2  3z  0, where z is a complex

1
number. Then the value of n
k 0
k
is equal to :
(A) 1 (B) 2
3 4
(C) (D)
2 3
100  sin2 x 3

Q4. If  dx  ,   R , where  x  is the greatest integer less than or equal
0  x x 1  4 2
   
E
 
to x, then the value of  is :
(A) 100 1  e  (B) 150  e1  1
(C) 200 1  e 1  (D) 50  e  1
Q5. Let [x] denote the greatest integer less than or equal to x. Then, the values of
2
x  R satisfying the equation  ex    ex  1  3  0 lie in the interval :
(A) 1, e  (B) loge 2, loge 3 
(C) 0, loge 2  (D) 0, 1/ e 
Q6. Which of the following Boolean expressions is not a tautology?

(A)  ~ p  q   ~ q  p  (B)  q  p    ~ q  p 
(C)  p ~ q   ~ q  p  (D)  p  q   ~ q  p 
Q7. Let a line L : 2x  y  k, k  0 be a tangent to the hyperbola x 2  y 2  3. If L is also a tangent

to the parabola y 2  x, then  is equal to :
(A) 24 (B) 24
(C) 12 (D) 12
Q8. Let y  y  x  be the solution of the differential equation

  2
cosec 2 x dy  2dx  1  y cos2x  cosec 2 x dx, with y    0 .Then, the value of
4
 y  0   1 is
equal to :
1 1
(A) e 2 (B) e 2
(C) e 1 (D) e
Q9. Let f : R  R be defined as

 4 3 2
 x  2x  3x , x  0
f  x   3
 ,x  0
 3xe x
Then f is increasing function in the interval.
 1   3
(A)   ,2  (B)  1, 
 2   2 
(C)  3,  1 (D)  0, 2 
   
Q10. Let a vector a be coplanar with vectors b  2iˆ  ˆj  kˆ and c  î  ˆj  kˆ . If a is perpendicular
      
to d  3iˆ  2jˆ  6kˆ and a  10 . Then a possible value of abc   abd  acd is equal to :
(A) 40 (B) 38
(C) 42 (D) 29
Q11. Let Sn denote the sum of the first n-terms of an arithmetic progression. If
S10  530, S5  140, then S20  S6 is equal to :
(A) 1852 (B) 1842
(C) 1872 (D) 1862
  ,x  0
 x3  1  2xe
2x

 log e
Q12. Let f : R  R be defined as f  x    1  cos 2x 2  2  . If f is continuous at
  
1  xe  x  
  , x0
x = 0, then  is equal to :
(A) 0 (B) 1
(C) 2 (D) 3
Q13. The number of solutions of sin7 x  cos7 x  1, x  0,4  is equal to :

(A) 7 (B) 11
(C) 5 (D) 9
         
Q14. Let three vectors a, b and c be such that a  b  c, b  c  a and a  2 . Then which one of
the following is not true?
     
(A) Projection of a on b  c is 2   (B) abc   c ab   8
  2      
(C) 3a  b  2c  51   
(D) a  b  c  b  c  0 
 
Q15.   
Let L be the line of intersection of planes r. î  ˆj  2kˆ  2 and r. 2iˆ  ˆj  kˆ  2 . If P  , ,   is 
the foot of perpendicular on L from the point 1,2,0 , then the value of 35        is equal
to :
(A) 101 (B) 143
(C) 134 (D) 119
Q16. Let A  aij be a real matrix of order 3 x 3, such that ai1  ai2  ai3  1, for i  1,2,3. Then, the
sum of all the entries of the matrix A3 is equal to :
(A) 9 (B) 3
(C) 1 (D) 2
cos 1 x 2  x  1
Q17. If the domain of the function f  x   is the interval  ,  , then    is equal
 2x  1 
1
sin  
 2 
to :
1
(A) 1 (B)
2
3
(C) 2 (D)
2
Q18. The values of  and  such that the system of equations
x  y  z  6, 3x  5y  5z  26, x  2y  z   has no solution, are :
(A)   2,   10 (B)   3,   10
(C)   3,   5 (D)   2,   10
x2 y 2
Q19. Let E1 :   1, a  b. Let E2 be another ellipse such that it touches the end points of
a2 b2
major axis of E1 and the foci of E2 are the end points of minor axis of E1. If E1 and E2
have same eccentricities, then its value is :
1  5 1  3
(A) (B)
2 2
1  8 1  6
(C) (D)
2 2
Q20. Four dice are thrown simultaneously and the numbers shown on these dice are recorded
in 2 x 2 matrices. The probability that such formed matrices have all different entries and
are non-singular, is :
22 45
(A) (B)
81 162
43 23
(C) (D)
162 81
SECTION - B
decimal place).
Q1. Let A  0,1,2,3,4,5,6,7 . Then the number of bijective functions f : A  A such that
f 1  f  2   3  f  3  is equal to……………
  x  if x  2
3  1  
Q2. Let f : R  R be a function defined as f  x     2 
 if x  2
 0
Let g : R  R be given by g  x   f  x  2   f  x  2 . If n and m denote the number of points
in R where g is the continuous and not differentiable, respectively, then n + m is equal
to………….
Q3. Let y  y  x  be the solution of the differential equation

 y 1 
   
  x  2  e x  2    y  1  dx   x  2  dy, y 1  1. If the domain y  y  x  is an open interval
 
 
 , , then    is equal to………
Q4.  n
The number of elements in the set n  1,2,3,....100 11  10    9  is………
n n

Q5. The area (in sq. units) of the region bounded by the curves
x 2  2y  1  0, y 2  4x  4  0 and y 2  4x  4  0, in the upper half plane is………
0 1 0
 
Q6. Let A   1 0 0  . Then the number of 3 x 3 matrices B with entries from the set
0 0 1 

1,2,3,4,5 and satisfying AB = BA is………..
Q7. If the digits are not allowed to repeat in any number formed by using the digits 0,2,4,6,8,
then the number of all numbers greater than 10,000 is equal to…….
Q8. The sum of all the elements in the set n  1,2,.....,100 H.C.F. of n and 2040 is 1 is equal
to……….
10
 1 
Q9. If the constant term, in binomial expansion of  2xr   is 180, then r is equal to…….
 x2 
Q10. Consider the following frequency distribution :

Class : 0–6 6 – 12 12 – 18 18 – 24 24 – 30
Frequency : a b 12 9 5
309 2
If mean  and median = 14, then the value  a  b  is equal to………………
22
FIITJEE
KEYS to JEE (Main)-2021
SECTION - A
1. B 2. D 3. C 4. D
5. B 6. D 7. B 8. D
9. A 10. B 11. D 12. B
13. B 14. D 15. D 16. C
17. A 18. B 19. A 20. D
SECTION - B
1. 2 2. 4 3. 60 4. 2
5. 1 6. 57 7. 5 8. 15
9. 500 10. 3
SECTION - A
1. C 2. A 3. B 4. D
5. A 6. B 7. D 8. D
9. A 10. D 11. A 12. B
13. D 14. A 15. C 16. A
17. A 18. A 19. D 20. D
SECTION - B
1. 1 2. 7 3. 12 4. 21
5. 2 6. 106 7. 6 8. 3
9. 78 10. 4
SECTION - A
1. C 2. A 3. D 4. C
5. C 6. A 7. B 8. C
9. B 10. C 11. D 12. B
13. C 14. C 15. D 16. B
17. D 18. A 19. A 20. C
SECTION – B
1. 720 2. 4 3. 4 4. 96
5. 2 6. 3125 7. 96 8. 1251
9. 8 10. 4
FIITJEE
Solutions to JEE (Main)-2021
SECTION - A
Sol1. Using conservation of energy :
2
 GMm 1  2GM   GMm 1
  m    mv 2
R 2  R  r 2
1 GMm
 mv 2 
2 r
2GM
V
r
dr 2Gm
 
dt r
R h t
  r1/ 2 dr  2GM  dt
R 0
2 3/ 2
 R  h   R3/ 2   2GM t
3  
3/ 2
2  h 
 R3/ 2  1    1  2GM t
3  R  
3/ 2
1 2R  h 
t  1    1
3 g  R  
h h h
Sol2.    
mv 2km 2  ev  m
1 e mp
  
m p me
 
Sol3. Component of A an B


 A  Bˆ Bˆ 
 î  ˆj     î  ˆj 


  î  ˆj  kˆ 
2
  2
 
1
 1  1 î  ˆj
2
 
 î  ˆj
Sol4. r  r '  90

 r '  90  r  90  i
Snell’s law :
 i r
 sini  1sinr ' 90 
  sin i  sin  90  i 
 1 i'
1
 tani 

Critical angle :
 sin ic  1 sin90  1
1
 sin ic   tani  tanr

ic  sin1  tanr 
Sol5. Using conservation of momentum 184 180

 180V1  4 V2 4

 V2  45 V1
Q  KE180  KE
V1 V2
1 1
Q  180V12  4V22
2 2
2
1 V  1
  180   2   4V22
2  45  2
1  45   1 
  4  V22  2  1  KE    1
2  45   45 
5.5MeV
KE    5.38MeV
 46 
 
 45 
1 1 2 1
Sol6. I  C0E02  C0  CB0   C3  0B02
2 2 2
2I
 B0 
0 C3
2  0.092

8.85  1012  27  1024
 2.27  10 8 T
Sol7. for capacitor : current leads emf

by 90.
ic
vc
hc 1242eV  nm
Sol8. E    2eV
 621 nm
 minimum 2eV is required to emit.
Sol9. W  mgh i
 80 
 80  9.8   
 100 
 627.2J 80cm
 w f  wg  0
 w f   627.2 J
1 V
Sol10. (A) L 
C i
1
(B) L 
C V i
1
(C) L 
C i
V
(D) resonant frequency Maximum current occurs.

2
T g
Sol11.
T'  
2 16
g
T 1
  4
T'  1
 
4
T
 T' 
4
Sol12. I : at high temperature, ferromagnet becomes paramagnet.
II : at high temperature, domains of ferromagnet will break
Sol13. for bullet :

I  p  mv  0
4 20
  50   0.2kg  m / s
1000 100
Using conservation of momentum :
 Pi  Pt
4
  50  4  v
1000
 v  0.05 m / s
Sol14. d = 150 km
d  2hR
2
d2 150  10 
3
h   1731 m.
2R 2  6.5  106
Population covered
 r 2    3.14  1502  2000  1413  105
Sol15. True dip is less than the apparent dip.
Sol16. x  t   A sin t  B cos t

  
 x  t   A 2  B2 sin  t     A 2  B 2 cos  t      
  2 
At t  0 :
x  0   A 2  B2 sin   
v  0    A 2  B 2 cos   
2
2  v 0 
  x 0   2
  A  B
2
  
2
2  v 0 
C  x 0      
 
x 0 x 0  
tan   
v 0 v 0

  v 0
tan   tan      cot  
2  x 0 
 v 0 
   tan1 
 x  0   
 
Sol17. Total energy of monoatomic gas at equilibrium

3
 KB T
2
Sol18. Using conservation of energy :

1 1 1 V2 1
mgh  Icm 2  mv 2  Icm 2  mv 2
2 2 2 r 2
mgh
v2 
I
1 cm
 mv 2
2 r2
So, sphere has greatest velocity of COM and ring has least.
 
Sol19. R1  1 R 2  2
A A
1 1 1 A1 1
     
R R1 R2   1 2 
3  106  1 1 
 1.7  10 8  2.6  108 
1  
4
R  0.858  10 3 
 2k 2k  1 1
Sol20. F     q  2kq   
 r1 r2   r1 r2 
1000 1000 
 2  9  109  3  10 6   q
 10 12 
 4  9  105 q
 q  4.44C
SECTION – B
Sol1. y
com
2R

x
Sol2. Using gauss law in differential form

  
 E 
0
 
 
   0 E  
 
  D  
   ˆ  ˆ 
  î  j  k  D  
 x y z 
    e sin y  e  x sin y  2  2
x
 Q  2  Volume   4  109 c  4nc
Sol3. At minimum deviation :

i  i'
r  r'
A
r  r'  A  r 
2
Snell’s law :
i
1sin i  3 sin r  3 sin
2
i
 2cos  3
2
i 3 i
 cos    30
2 2 2
 i  60
i  2r  r  30 
 A  60
V0
Sol4. VP  V02  V02  2 V0 V0

R
P V0
V0

Sol5. T  2
g

 g  4 2
T2
g  2T
  
g  T
Student 1 will get least error because it has more number of oscillation
Sol6. from newtan’s law of cooling :

dT
  k  T  T0 
dt
Using average value :
75  65   75  65  
 k   25 
5  2 
 65  T    k   65  T   25 
 
5  2 
10 45
 
65  T 65  T
 25
2
 T  57 C
1 1 1
Sol7. Energy density (u) =       Y     2 Y
2 2 2
1
 energy stored / m2  2 YA
2

Strain       T  10 5  10  10  4
0
1
 energy stored / m2   10 8  1011  102  5
2
Sol8. i 
 R
Rr
R
vR  i
Rr
 5
1.25  
5r r
 2
1 
2r
r 1
3 15
Using above equ :    V
2 10
Sol9. For 90mA in zener diode, current in R should be greater than 90mA.
45 45
 90  103  R   500 
R 90  103
Sol10. Cross product will represent a vector perpendicular to both the vector.
  
Dir. Of Motion of P :  î  ˆj  ˆj  kˆ 
 kˆ  ˆj  î
  
Dir. Of Motion of Q  î  ˆj  î  ˆj 
 2kˆ
 
a.b 2 1  1 
cos        cos 1  
ab 2 3 3  3
SECTION - A
Sol1. Esters on treating with excess CH3MgBr followed by hydrolysis gives 3o alcohol.
O CH3 OMgBr O
CH3MgBr
+
O H3C CH3
O OMgBr OH
CH3 Mg Br H2O
H3C C CH3 H3C C CH3
H3C CH3
CH3 CH3
o
3 alcohol
Sol2. When AgNO3 is added to KI solution, precipitate of AgI is formed which adsorb I ion
from
Dispersion medium to give negatively charged sol
AgNO3  KI  AgI  KNO3
AgI/ I - negatively charged sol.
Sol3. Only tritium is the isotope of hydrogen which is radioactive in nature that emits low
n
energy  particles since its ratio is above stability belt.
p
Sol4. Depression in freezing point will be maximum for Al2  SO4 3 since its Van’t Hoff factor is
highest. So its solution will have lowest freezing point.
Sol5.
Species Sigma bonds lone pairs Hybridisation
SF4 4 1 Sp3 d
IF5 5 1 Sp3 d2
NO2 2 0 Sp
NH4 4 0 Sp3
O
||
Sol6. CH3  CH2  CH2  C NH2    p conjugation
CH3  CH2  CH  CH  CH2  NH2  No conjugation
CH3  CH2  O  CH  CH2    p conjugation
CH2 OH
  conjugation in benzene ring
Sol7. (A) Ni2   4s0 3d8  Paramagnetic & coloured

7 0 0
Mn  4s 3d  Diamagnetic & colourless
Hg2  6s0 4f 14 5d10  Diamagnetic & colourless
(B) Cu  4s0 3d10  Diamagnetic & colourless
2 0 10
Zn  4s 3d  Diamagnetic & colourless
Mn4   4s0 3d3  Paramagnetic & coloured
(C) Sc 3   4s0 3d0
V 5   4s0 3d0
Ti4   4s0 3d0
All are diamagnetic & colourless
(D) Cu2  4s0 3d9
Cr 3   4s0 3d3
Sc   4s13d1
All are paramagnetic & coloured
All d- & f block paramagnetic cations are coloured also.
Sol8. Compound A is phenol since phenol gives dark green colour with FeCl3.
OH OH
CHO
(i) CHCl3, KOH
(ii) H+
A Reimer-Tiemann B
reaction
OH OH
CH2OH CHO
PCC
Oxidation
C B
Sol9. 2NaBH4  I2  2NaI  H2  B2H6

Diborane is produced when NaBH4 is reacted with I2
H
H H
B B
H H
H
3 3
Sp Sp
Both boron atoms are sp3 hybridised & molecule is non- planar. Diborane as two bridged
3 centre-2- electron bonds.
Sol10.
Cl
Chloroprene
Cl
Neoprene is polymer of chloroprene

n
Isoprene
CH 2 CH CN Acrylonitrile
Sol11. 3- Ethylhex-3-ene will not show stereo isomerism
3-Methylhex-1-ene will show steroisomerism (optical isomerism)
Since it has chiral carbon.

3,4-Dimethylhex-3-ene will show stereoisomerism (Geometrical isomerism)
4-Methylhex-1-ene will show stereoisomerism (optical) since it has one chiral carbon
Sol12. Sulphide ion  S2   form ores commonly with Pb & Ag as PbS and Ag2S
Sol13. +
N2Cl H2C CH3
CH3 CH2 Cl
+ H3PO 2 + H2O
Anhyd
AlCl3
So; A is H3PO2 & B is CH3  CH2  Cl
Sol14. Ba has outer electronic configuration 6s2.

CaC2O4 is insoluble in water.
Compound of Li are covalent so soluble in organic solvent.
Na forms strong monoacidic base.
Sol15. Reducing power for group-15 hydrides increases down the group, so BiH3 is strongest
reducing agent.
Sol16. Vitamin B1 is thiamine while vitamin B6 is pyridoxine
Sol17. Aniline being a base does not give Friedel Craft reaction because it react with AlCl3
used in Friedel Craft reaction.
Sol18. At the time when Mendeleeff proposed periodic table structure of atom was not known.
Sol19. Solubility of gas in liquid increases on decreasing the temperature. So water at 4oC will
have more dissolved O2.
Sol20. Reduced pressure distillation technique is used for purification of high boiling organic
liquid which decompose near its boiling point. By reducing pressure they boil below their
normal boiling point.
SECTION - B
Sol1. NH3 behaves as strong field ligand with Co2  & Co3 
Co  NH3   Cl2
 6
Co2   4s0 3d7
3 4 4 4
It has one unpaired electron.
Co  NH3   Cl3
 6
Co3   4s0 3d6
3d 4s 4p
It has no unpaired electrons
So, total unpaired electrons in both compounds is 1.
Sol2. For first order reaction, using

2.303 R 0
K= log10
t R 
2.303 2.4  10 2
K= log10 min1
1 60 1.6  102
2.303 3
K= log min1
60 2
2.303
K=  0.477  0.301 min1
60
K = 6.7  103 min1
Ans. is 7 (nearest integer)
Sol3. 23 V  1s2 2s2 2p6 3s2 3p6 4s2 3d3

So; total electrons in p orbitals are 12.
Sol4. Molar enthalpy of combustion of graphite is 2.48  102 kJ/ mol, that means 2.48  102 kJ
heat generates when combustion of 1 mol graphite takes place.
So, heat generated on combustion of 1g graphite
2.48  102
= kJ
12
= 20.67 kJ
Ans. is 21 (nearest integer)
Sol5. K p  47.9 T = 288K

KC  ? R = 0.083 L bar / K mol
N2 O 4 (g)  2NO2 (g)
Using
ng
K p  K C RT 
Here;
ng  1
1
47.9  K C  0.083  288 
KC  2
Sol6. Density,   7.62gcm3

Cell edge, a  0.4518nm  0.4518  107 cm
Effective number of atoms, Z = 4 for CCP.
Z A
Using ;  
NA  a 3
4A
 3

6.022  10  0.4518  10 7
23

4 A
7.62  3
6.022   0.4518   102
A = 105.79 g/ mol
Ans. is 106 (nearest integers)
Sol7. Acyclic isomers of pentene are:-
=1 No Geometrical isomerism
= 1+1 Show geometrical isomerism (Cis-trans)

=1 No geometrical isomerism
So; total isomers are 6

Sol8. Using; Nernst equation
0.06 Cu2  
o
Ecell  Ecell  log10  
n  2
 Ag 
 
0.06 0.25
Ecell  2.97  log10 6 V
2 10
= 2.97  0.03 log2.5  5  V
= 2.97  0.03  0.3979  5  V
Ecell  2.8V
Ans is 3 (nearest integer)
Sol9. CH3
Anhyd.AlCl3
+ H3C Cl
Theoretically; 1 mol benzene gives 1 mol toluene

10
Moles of benzene = mol
78
10
Moles of toluene (Theoretical) = mol
78
9.2
Mole of toluene (observed) =  0.1mol
92
0.1
% yield =  100
10
78
= 78%
Sol10. Strength = 0.72 g/ L

Using;
Strength
Molarity =
Molar massof solute
0.72
M M
180
= 4  103 M
Ans is 4.
SECTION - A
Sol1. 36x2  36y 2  108x  120y  c  0
10 c
 x 2  y2  3x  y 0
3 36
The circle not interesting either axes
 g2  c & f 2  c
9 c 25 c
   c  81   i &   c  100 ……(ii)
4 36 9 36
 i  ii   c  100 …….(iii)
Point of intersection between x  2y  4  0 & 2x  y  5  0 is  2  1 lies inside the circle.
10 c
 4  1 6    0  c  156 ……..(iv)
3 36
 iii   iv   100  c  156
x 1 y  2 z 1
Sol2.   ……. (i)
2 1 3
x2 y  z3
  ………(ii)
1 2 4
 

OA   i  2j  k  OB  2iˆ  ˆj  3kˆ 
 
a  2i  j  3k & b  i  2j  4k
 
a  b  2i  5j  3k
   

OB  OA . a  b   1
 shortest distance =   
ab 38
 14  5  1
13
   3&
5
Integer value of   3
Sol3. z2  3z  0
Let z  x  iy
 x 2
 y 2  2i xy   3  x  iy   0
 
 x 2  y2  3x  i  2xy  3y   0
 2xy  3y  0
3
 y  0 or x 
2
For y  0 3
2
For x 
x  3x  0 2
x  x  3  0 9 9 27
y2    .
x  0, x  3. 4 2 4
 z  0,3i 3 3
y
2
3

z  1 3 i
2

 the equation has n  4 solution .

1 1 1 4
  k  1  2     
k 0 n 4 4 3
100 
sin2 x dx
Sol4.  x 
I
0  
 
e
sin2 x
f x  x is periodic with period = 
 
e 

sin2 x
I  100 x /  dx.
0 e
  
1  cos 2x
 50  x/ 
dx = 50  e x /  dx  50 e  x /  cos 2x dx
0 e 0 0

  x/  1 
ex/ 
  e    cos 2x  2sin 2x  
 50  50   
1/  0  1 
 2
4 
  0
  1   1 
50 e 1    1   
 50   e1  1        
1
 4.
2
50 2 1  1

 50  1  1    1
e 1  42   e 
 1  50 1  e 4
1 3


 50  1  1 1  
e  1  42 

1  4 2
   200 1  1 e 
2
Sol5.  ex   e x   2  0
Let  ex   t
 t2  t  2  0   t  2  t  1  0
x
t  2   e   2 not possible
 t  e x   1  1  ex  2
 0  x  ln2
Sol6. Option (A)

p q ~p ~q pq  qp qp  ~ p  q    q  p 
T T F F T T T T
T F F T T T T T
F T T F T T F T
F F T T F F T F
Option (B)
p q ~p ~q pq  qp qp  q  p     q  p
T T F F T T T T
T F F T T T T T
F T T F T T F T
F F T T F F T T
Option (C)
p q ~p ~q p ~ q  qp qp  p ~ q    q  p 
T T F F F T T T
T F F T T T T T
F T T F T T F T
F F T T T F T T
Option (D)
p q ~p ~q pq  qp pq  p  q    q  p 
T T F F T T T T
T F F T T T F T
F T T F T T T T
F F T T F F T T
Sol7. L : 2x  y  k.
x2 y 2
y  2x  k. is tangent  1
3 3
2
 k 2  3  2   3  9  k  3 as k  0

y  2x  3 is also tangent to y 2  4   x
4
/4
 3    24
2
Sol8. cosec 2 x dy  2dx  1  y cos 2x  cosec 2 x dx.

dy
  2 sin2 x  1  y cos2x.
dx
dy
  y cos 2x  1  2 sin2 x  cos2x .
dx

 cos 2x dx

sin 2x
I.F. = e e 2
sin 2x sin 2x
  sin 2x
 Solution ye 2
 e 2
.cos 2x dx. Put  t  cos2x dx  dt
2
sin 2x

ye 2
  e  t dt  e t  c .
sin 2x sin2x
 
ye 2
 e 2
c
sin 2x
y  1  c e 2

For x  ,y  0
4
1 1 1
 0  1  c e 2
c 1
e 2
e 2
1 sin 2x

y  1  e .e 2 2
2
y  0   1  e
1
2
  y 0   1  e
2
  1
2
 e 1
 4 3
 x  2x 2  3x, x  0
Sol9. f  x   3
 x
 3x e , x0
  4x 2  4x  3 x0

f '  x   3 x0

 3  xe  e 
x x
x0
f '  x   0 for x  0 e x  x  1  0  x  1  x   1, 0 

for x 0  4x 2  4x  3  0

 x  0, 3
2 
Again at x  0 f '  0   3  0
 f  x  is increasing in 1, 3 2 
  
Sol10. a   b   c   2    i       J       k

is perpendicular to d  3iˆ  2jˆ  6kˆ
 3  2     2       6       0
 14   7   0    2 …….(i)

 a  3j  k
 
| a |  9 2   2  10    1    1 , for   1, a  3ˆj  kˆ

for   1, a  3ˆj  kˆ
  
abc   ab d  ac d
     
 
= 0  dab   dac 
     
   
= d  a .b  d  a .c
   
  
= d a . b  c
i j k
 
da   3 2 6
0 3 1
   
    
 d  a . b  c  20iˆ  3ˆj  9kˆ . 3iˆ  2kˆ 
  42
Sol11. S10  530  5 2a  9d  530

2a  9d  106 ……….(i)
5
S5  140 
2
2a  4d  140
a  2d  28 ………..(ii)
Solving (i) & (ii) a = 88 d = 10
 S20  S6  14a  175 d  1862
Sol12. f : R  R.
  2x 
 x3  1  2xe  x  0
log
f  x    1  cos 2x 2  1  xe x 2 
   
 x0

As f is continuous at x = 0
   Lim f  x 
x 0
x3  n 1  2x e2x    2xe2x  2log 1  xe x  

= Lim
x 0 4

2x e 2x xe x
  xe x
 
 sin x   
4x 4  
 x 
1
= Let  2x e 2x  e x 
x 0 4x
1 1
= Lim e2x  e x    2  1
x 0 2 2
  1
Sol13. sin7 x  cos7 x  1, x 0, 4

will satisfy for sin x  1,cos x  0
 5
x & .
2 2
or, cos x  1, sin x  0
x  0, 2, 4 total 5 solutions
  
Sol14. a  b  c - (i)
   
bc  a a 2 - (ii)
 
Taking dot product with c & a respectively in (i) & (ii) we have
 2
c ab   c
 
 2
abc   a  4
 
2 2 
 c  a 4  c 2
     
Again (i) & (ii)  a. b  b.c  c.a  0
  
   a. b  c
Opt 1. Projection of a on b  c      2
4  
b c 2
  
Opt 2. (2) abc   c ab   2 abc   8
    
(1)  b  a  b  b  c  
 2       2    
 
 b a  b.a b  b  c  b a  b  c  b  1
  2 2 2 2      
Opt 3. 3a  b  2c  9 a  b  4 c  2 3a.b  6a.c  2b.c  
 36  1  16  2  0   53
    

Opt 4. a  c  b  b  c 
        
   
 2a  c  b  2 a.b c   a.c  b  0 


Sol15. r. î  ˆj  2kˆ  2 

 
& r. 2iˆ  ˆj  kˆ  2 are two planes the direction ratio of the line of intersection of
î ˆj kˆ
them is collinear to 1 1 2  î  5ˆj  3kˆ
2 1 1
Any point on the line in given by x  y  2
& 2x  y  2
 x  4 , y  2 , z  0
3 3
x4 y2
 equation of line L : 3  z r
3
1 5 3
 4 
Any point on this line is P   r  ,5r  2 ,3r 
 3 3 
1 8
A 1,2,0   d.r. of AP   r  ,5r  ,3r
3 3
 1  8
AP is  r to L  1   r    5  5r    3  3r   0
 3  3
41 41
35r  .  r 
3 3  35
 33 45 41 
 point P  , ,    , ,  
 35 35 35 
 35         119
a11 a12 a13 

Sol16. A  aij  33  a 21 a22 a23 
a31 a32 a33 
ai1  ai2  ai3  1; i  1,2,3
 1
Let X   1  them
 1 
 a11 a12 a13 1 1
given a21 a22 a23 1 
 
1
 
a31 a32 a33 
 1  1
 AX  X …………….(i)
replace x by A x we have
A  AX   AX
 A 2 X  AX  X …………….(ii)
Again replace X by AX
A 3 X  AX  X.
1 
As X  1  , Sum of all entries in A 3  sum of entries in X  1  1  1  3
1 
cos1 x 2  x  1
Sol17. f  x  
 2x  1 
sin1  
 2 
For domain 0  x2  x  1  1
& x 2  x  1  0 x  R.
x2  x  0 & x  x  1  0  x  0,1 ………(i)
2x  1
Again 0  1
2
 0  2x  1  2
1
  x  3 …………………(ii)
2 2
1 
(i)  (ii) x   ,1   , 
2 
then     3 2
Sol18. System of equations can be written as

 1 1 1  x   6 
    
 3 5 5  y    26 
 1 2   z    
    
R '3  R3  R1,R'2  R2  5R1 
 1 1 1 x  6 
    
 2 0 0 y   4 
 0 1   1  z     6 
    
0 1 1  x   4 
1     
R "1  R'1  R '2   2 0 0  y     4 
2  0 1   1 z     6 
    
0 1 1  x   4 
    
Again R "3  R '3  R '1   2 0 0  y     4 
 0 0   2  z     10 
    
The system will have no solution for
  2 and   10.
x2 y 2
Sol19. E1 :  1
a2 b2
b2
e12  1  2 - (i) H1 E
a 1
x2 y2
Let E2 : 2  2  1
a B E2
H2
B>a
a2
e22  1  and given Be2  b
B2
 B2 e22  B2  a2
 b 2  a 2  B2
a2 b2 b2 / a2
 e22  1   
a 2  b2 a2  b 2 1  b2 / a2
1  e12
 e22  given e1  e2  e (say)
2  e12
1  e2
 e2   e4  3e2  1  0
2  e2
2
3  5  5  1
e2  
2  2 
 
5 1
e
2
Sol20. All entries different which can be selected as 6 C4 ways

there arrangement in matrix in 6 C4  4! ways
a b
Let A    be such matrix
 c d
A  ad  bc
Now A  0  ad  bc  0 cases
1, 6 3, 2 222
2, 6 3, 4 222
as 1,6  total arrangement in one case  2  2  2  8 ways
 3,2

2!

2!
2!
6
C4  4!  8  8 43
 For such non singular matrix required probability  4

6 162
SECTION - B
Sol1. f : A  A is bijective.
where A  0,1, 2,3,4,5,6,7
and f 1  f  2   f  3   3
→ 0 1 2 3! ways
f 0 f  4 f 5  f 6 f 7 
3 4 5 6 7  5! ways
Total such required functions  3!  5!  720
  x |
3  1   ; x2
Sol2. f  x    2 
0 ; x 2

  x2 
3  1   ; x  2  2  4  x  0
f  x  2    2 
 0 ; x  2  2  x    ,  4    0,  

  x2 
 3  1   ; x  2  2  0  x  4.
f  x  2    2 
0 ; x  2  2  x  0 or x  4

 0 x  4

 3 1  x  2  4  x  0
  2 

 
 g  x   f  x  2  f  x  2
  x2  0x4
3  1  
   2 
 x  4.
 0
y  g x 
x
-4 -2 2 4
g  x  is continuous every where but not differentiable

at x   4, 2,2and 4.
 n  0 &m  4  n  m  4
y 1
 
 x  2  e   y  1  dx   x  2  dy.
x2
Sol3.
 
 y 1 
dy    y 1
  e x  2     - (i)
dx  x  2
dy dv
Let y  1  v  x  2    v   x  2 .
dx dx
dv
(1)  v   x  2   ev  v.
dx
dv dx
 v  Integrating both side
e x2
  e  v  n x  2  c
y 1

 e x 2
 n x  2  c
y 1  1
 e2/3   n3  c
 c  e 2/3  n3
1
  y 1 
 n3  e2/3  n x  2
 
 x2 
e
2  y 1 
 
 x2 
 e 3  ln3  ln x  2  0 as e 0
2
x2 
 ln e 3
3
x2 2/3
0  ee
3
2/3 x2
Let ee a0 a
3
x2
 a   a a  2
3
 3 a  2  x  3a  2
   3a  2 &   3a  2
   4
Sol4. 11n  9n  10n

n n
 10  1  10  1  10n
 2  n c 110n1  nC3 10n 3       10n.
 For n  5 the inequality satisfies.
For n  4 . 2  4  103  4  10   10 4
 8  1010  10 4 which is a contradiction
 n  5 all values satisfies. Hence possible values of n is 96
y
Sol5. 
x 2  2 y  1
2 
(0,2)
y  4  x  1
2
y 2  4  x  1 -1 1 x
0
0  1 x2  1
Required area  21 2 x  1   dx
 2  2 3
0
3
4 3 1 x 
 2   x  1 2   x   
3 2 3   1
 2
0 1 0
 
Sol6. A   1 0 0
 0 0 1
 3  3
B is a matrix of same order with entries from 1,2,3,4,5. and satisfying AB  BA.
 a11 a12 a13 
Let B   a21 a22 a23 
a 
 31 a32 a33 
 0 1 0   a11 a12 a13   a11 a12 a13  0 1 0 
     
  1 0 0   a21 a22 a23    a21 a22 a23  1 0 0 
 0 0 1  a   a33  
   31 a32 a33   a31 a32  0 0 1 
 a21 a22 a23   a12 a11 a13 
   
  a11 a12 a13    a22 a21 a23 
a   
 31 a32 a33   a32 a31 a33 
a21  a12 , a22  a11, a23  a13 , a31  a32
 there exist only 5 distinct entries in the matrix B so that possible case = 55  3125
Sol7. 1st position can be filled in 4 ways as zero cannot 0, 2, 4, 6, 8

appear in 1st position.
2nd position can be filled in 4 ways and so on.
Total cases  4  4  3  2  1  96 4 × 4 × 3 × 2 × 1
Sol8. 2040  23  3  5  17.

If HCF between n & 2040  1
 n can not be multiple of 2, 3, 5, 17.
Let S  n  denote sum of numbers divisible by n.
50  51
S  2   2  4      100  2   50  51
2
33  34
S  3   3  6      99  3   33  51
2
20  21
S  5   5  10    100  5   50  21
2
56
S 17   17  34    85  17   5  51
2
16  17
S  6   6  12      6   16  51
2
10  11
S 10   10  20      10   50  11
2
S  34   34  68  102
67
S 15   15  30      90  15   45  7
2
S  51  51
S  85   85,S  30   30  60  90  180 S(all other combinations) = 0
 Sum of all numbers which are either divisible by 2,3,5, or 17 is
 50  51  33  51  50  21  5  51
 16  51  50  11  102  45  7  51  85  180  3799
100  101
Again sum of all number of 1,2,   100   5050
2
 Sum of required number  5050  3799  1251
10
 r 1
Sol9.  2x  2 
 x 
th
Let the constant term is  k  1 term.
10  k
 10
Ck  2xr  . x 2k
10
 Ck 210k. x10r rk  2k
For constant term 10r  rk  2k  0.
10r
 k k I
r2
 r  3,k  6 and r  8,k  8.
10
For k  6 Ck 24  180.
10
For k  8 Ck 22  180
 r8
Sol10.
Class Frequency xi xi f i
0–6 a 3 3a x f i i
6 – 12 b 9 9b Mean x 
N
12 – 18 12 15 180 309 3a  9b  504
18 – 24 9 21 189  
22 a  b  26
24 - 30 5 27 135
a+b+26
 81a  37b  1018
=N
- (i)
N
 c,
For Median  L  2 xh
f
ab
 13   a  b 
14  12  2 6
12
 a  b  18 - (ii)
Solving (i) & (ii) a  8 & b  10
2
 a  b  4

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FIITJEE

Solutions to JEE(Main) -2021

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 300

5. Section – B : Do any 5 questions out of 10 Questions.

Q4. A ray of light passes from a denser medium to a rarer

Q7. In a circuit consisting of a capacitance and a generator

voltage and current. Correct phase diagram for such Eg IC CVC

Q8. Consider a situation in which reverse biased current of a particular P – N junction

(A) 627.2 J (B) 62720.0 J

Choose the correct answer from the options given below :

Q12. Statement I : The ferromagnetic property depends on temperature. At high temperature,

Statement II : At high temperature, the domain wall area of a ferromagnetic substance

(B) Height  1241 m

(C) Height = 1600 m

(D) Height  1731 m

Q15. Choose the correct option :

Q16. The motion of a mass on a spring, with spring constant K is

Q9. In a given circuit diagram, a 5 V zener I I2

Q5. Match List – I with List – II :

Choose the correct answer from the options given below :

Q9. Given below are the statements about diborane.

Q10. Match List – I with List – II :

(d) Isoprene (iv) CH2 = CH - CN

Q.13. N2 Cl

Q14. Match List – I with List – II :

Q16. Thiamine and pyridoxine are also known respectively as :

Q17. Which one of the following reactions does not occur?

Q19. The water having more dissolved O 2 is :

Q3. Number of electrons that Vanadium  Z  23  has in p-orbitals is equal to ----------.

Q8. Assume a cell with the following reaction

Q2. If the shortest distance between the straight lines 3  x  1  6  y  2   2  z  1 and

100  sin2 x 3

Q6. Which of the following Boolean expressions is not a tautology?

Q7. Let a line L : 2x  y  k, k  0 be a tangent to the hyperbola x 2  y 2  3. If L is also a tangent

Q8. Let y  y  x  be the solution of the differential equation

Q9. Let f : R  R be defined as

Q13. The number of solutions of sin7 x  cos7 x  1, x  0,4  is equal to :

Q3. Let y  y  x  be the solution of the differential equation

Q10. Consider the following frequency distribution :

Sol4. r  r '  90

Sol5. Using conservation of momentum 184 180

Sol7. for capacitor : current leads emf

(D) resonant frequency Maximum current occurs.

Sol12. I : at high temperature, ferromagnet becomes paramagnet.

II : at high temperature, domains of ferromagnet will break

Sol13. for bullet :

Sol15. True dip is less than the apparent dip.

Sol16. x  t   A sin t  B cos t

Sol17. Total energy of monoatomic gas at equilibrium

Sol18. Using conservation of energy :

Sol2. Using gauss law in differential form

 Q  2  Volume   4  109 c  4nc

Sol3. At minimum deviation :

Sol6. from newtan’s law of cooling :

  conjugation in benzene ring

Sol7. (A) Ni2   4s0 3d8  Paramagnetic & coloured

Sol9. 2NaBH4  I2  2NaI  H2  B2H6

Neoprene is polymer of chloroprene

Sol11. 3- Ethylhex-3-ene will not show stereo isomerism

3-Methylhex-1-ene will show steroisomerism (optical isomerism)

Since it has chiral carbon.

Sol14. Ba has outer electronic configuration 6s2.