ANSWER: Quiz-3: Class-XII

PHYSICS CHEMISTRY MATHEMATICS

Ans1. D Ans1. B Ans1. A
Ans2. C Ans2. D Ans2. B
Ans3. A Ans3. B Ans3. D
Ans4. D Ans4. C Ans4. C
Ans5. C Ans5. A Ans5. D
Ans6. B Ans6. B Ans6. A
Ans7. D Ans7. A Ans7. C
Ans8. B Ans8. A Ans8. D
Ans9. A,C Ans9. C,D Ans9. A,B,C
Ans10. C,D Ans10. A,B Ans10. A,C
Ans11. B,D Ans11. A,B,C Ans11. A,D
Ans12. A,C,D Ans12. B,D Ans12. C,D

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SOLUTION: Quiz-3: Class-XII
PHYSICS
Sol7. The electric flux through the surface
(A) is the same for al the figures. [as charge enclosed is same for all].

Sol8.
q
 E . ds  
s 0
( B) E on the LHS of the above equation will have a q1 S
contribution from all charges while q on the RHS will have a
q2
contribution from q2 and q4 only.
q4
q3
q5

Sol9.
qin Q Gaussian surface
Total    Option ( A)
0 0
 0 due to 5Q charge  Option ( C)

R
Q
5Q
-2Q

Sol10. If  E. ds  0 , then
s
( C) number of flux lines entering the surface must be equal to the number of flux lines
leaving it
( D) All chargers must necessarily outsides the surface.

Sol11. If there only one type of charge in the universe, then

( A)  E. dS  0 if charge is outside
S

q
(C)  E. dS  
S 0
, if charge were inside the surface.

Sol12.

2
CHEMISTRY
Sol1. Reaction is Nucleophilic addition, then reactivity order is
O O O O

C H C C OH
C Cl
Concept Involved: - Reduction of carbonyl compound

Sol2. (+M) effect operative in (II) and (III), and (+M) effect of N is greater than O.
Concept Involved: -Carbonyl reduction.

Sol3.
O OH

C CH3 C CH3
(A) (B) (C) H*
(R + S) form
Enantiomer

Concept Involved: - Aromatisation Reaaction.

Sol4.
OH Me OH
Me CHCl3/NaOH

 CHO Br2 / Fe

CH3 OH

Br CHO
Concept Involved: - Reimer Tiemann Reaction.

Sol5. Higher the electronegativity between C-X Higher Will be the dipole moment.
Concept Involved: -Dipole moment

Sol6. Here after generation of carbocation 1, 2 alkyl shifts takes place. Then Br attacks the
stable 3o carbonium ion.
Concept Involved: - Preparation of Alkyl halide.

Sol7. As we know from hyperconjugation more substituted alkene are stable than less
substituted alkene. And here after the generation of carbocation alkene formation take
place.
Concept Involved: - Dehydration Reaction.

Sol8.
CH3
H3C C OH
CH3

It is 3o Alcohol which reacts fastest with Lucas reagent

3
Concept Involved: - Test of Alcohol.

Sol11.
conc H2SO4

OH

OH
conc H2SO4 Ring expansion

+
1, 2 Me shift


+
H Ring expansion
OH

Concept Involved: - Ring expansion.

Sol12.
OH O OH
CHO
CHCl 3
+
OH

H3C CHCl 2
CH3 (minor) CH3 (major)
OH O
CCl 2
+ CCl 2 H

CH3 CH3

4
 O
OH
CHCl 2
CHO
OH

CH3
CH3 (Major)
O O O

H2O

CCl 2
H3C CCl 2 H3C CHCl 2
CH3 (Minor)
Concept Involved: - Reimer Tiemann Reaction.

5
MATHEMATICS
n
 a  1 n b 
Sol1. We have lim  
n  a 
 
n  n b 1
  n b  1  lim n
n  a 

 lim 1     e 
n   a 
  
1 b1/n 1 1
 e    b1/a  a b
lim lnb 1/a
ln b
 e a n 1/n
 ea

cot x  cos x
Sol2. lim
   2x 
x  /2 3

1 cos x 1  sin x 
 lim . 3
x  /2 8
 
sin x   x 
2 
   
cos   h  1  sin   h  
1 2  2 
 lim . 3
h0 8
    
sin   h    h 
2  2 2 
1 sinh 1 cosh
 lim
8 h 0 cosh. h3
 h h
sinh  2sin2  sinh.sin2  
1  2 1 2
 lim 3
 lim 3
8 h  0 cosh. h 4 h  0 h cosh
2
 
1  sinh   sinh  1 1 1 1 1
 lim    . .   
4 h  0
 h   h  cosh 4 4 4 16
 
 2 

e   x  1
x

Sol3. LHL = lim 

x
2
x  a 

 lim
a h

e    a   h  1 
a  h
h0 2

e1h  1  h  1
 lim  e2
1 h
h0 2

e   x  1
x

RHL = lim 
x
2
x  a 

 lim
a h

e    a   h  1 
a  h
h0 2

6
 eh  h  1
 lim  P (say)…………(i)
h0 h2
Replacing h by – h in P, then
eh  h  1
P  lim ………..(ii)
h 0 h2
Adding Equations (i) and (ii), then
eh  eh  2
2P  lim
h0 h2
e 
2
h
1
 lim
h0 eh . h2

1
2

 1
1
1
 RHL = [from equation (i)]
2
Hence, LHL  RHL

Sol4. Given equation, p  x   x 2  x  2   x  2  x  1 having a positive root , so  = 2.

 p x  
2 sin  
Now, lim

1  cos p  x    lim  2 
 
x  x4 x  2 x2
   x  2  x  1  
 sin  
  2 
 lim  2     sin   0, if   0 
x 2  x2  
 
 
   x  2  x  1  
 sin   
  2   x  1
 lim  2   
x 2   x  2 x  1  2 
 
 2 
3 3
 2  
 2 2

1
Sol5. lim  2  tan x  ln tan x 

x
4
lim
 1

 

x
e ln 2  tan x ln tan x 
 
4

 
ln 2  tanx 
lim
x
 ln tanx 
e 4

1
lim 2  tan x

  sec2 x 
 1
x  sec2 x
e
4
tan x e0/0 form
 

7
 [by Hospital’s rule]
 tanx
lim
x  2  tanx


e 4

1
e 2 1
 e 1

f  x  a  f a
Sol6. f ' a   lim
x a x
ln  a  x   lna lr x  lne
and lim  k lim 1
x 0 x x e xe
 f ' a   k f ' e   1 [where f  x   ln x ]
1 k  1
   1  k  e 1 
a e  a 

  1  2   15  
Sol7. lim x        ...    
x 0
x x  x 
We know,  x   x  x
 1 1  1
     
x  x x 
n n n
Similarly,      
x x x
 Given limit
 1  1 2 2  15 15  
 lim x          ...    
x 0
 x x x x x  x 
 n 
 0     1, therefore 
 120  0  120  x  
 n n 
0  x    x  lim x    0
 x  x 0
x 

1/21  cos2x  sin x

Sol8. lim  lim
x  x x  x
 LHL = -1 and RHL = 1
x 2n  1
Sol9. f  x   lim 2n
n x 1
Option (A) x  1
1
1
1 0
Then f  x   lim
2n
x  1
n 1 1 0
1  2n
x
Option (B) x  1
x 2n  1 0  1
Then f  x   lim   1
n x 2n  1 0 1
Option (C) from alternate (A) and (B), 1  1

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  f  x  is not defined for any value of x.
Option (D) x  1
Then f  x   0

lim  cosx  asinbx 

1/x
Sol10.  e2  form 1 
x 0  
1
lim  cos x  a sinbx 1
 e x0 x
 e2


 lim a sinbx  1  cos x  .
x 0
 x1  2
a sinbx  1  cos x 
 lim 2
x 0 x

 limb.
asinbx
 lim
1 cos x   2
x 0 bx x 0 x
  ab1  0  2
 ab  2

1  cos2ax  1  cos2ah
Sol11. lim  lim
x 0 sinbx h0 sin bh
2 sinah
 lim
h0 sin bh
2 sinah  a  0 ,h  0
 lim  
h0 sin bh  ah  0 
sinah
 ah
a
 2 lim ah  2
h sinbh b
 bh
bh
2a

b

 /x
 a x  bx  cx 
Sol12. lim   [form 1 ]
x 0
 3 
 ax bx  cx  
lim  
x 0  3  x
e  

 ax bx  cx 3 
 lim  
x 0  3x 
e  

e
 /3 lim
x 0 

 ax  1

 
bx  1

cx  1    
 x x x 
 
e 
 /3 ln a  ln b ln c

  abc
 /3 ln  a b c  /3
e