Professional Documents
Culture Documents
IN
2020
Course Description:
Principles of technology of fire and its behavior. It also emphasizes fire
investigation and the role of fire fighters during fire suppression and
investigation, the study of Fire and Building Code, and law on destructive
arson including arson investigation.
The study of fire technology and investigation is divided into two parts;
the chemistry of fire, and fire investigation. The first part covers the analysis of
chemical and physical properties of fire, characteristics of combustible
matters, heat energy, oxidation and combustion process. Origin and theory of
fire, fire behavior, fire prevention, and fire fighting. The second part deals with
fire scene investigation, arson motives, and modus operandi of fire-setters,
prima facie evidence of arson, laws relative to fire/arson investigation, and
other legal issues about arson.
WHAT IS FIRE?
Fire is the manifestation of rapid chemical reaction occurring between
fuel and an oxidizer- typically the oxygen in the air. Such rapid chemical
reaction releases energy in the form of heat and light.
Fire is heat and light resulting from the rapid combination of oxygen,
or in some cases gaseous chlorine, with other materials. The light is in the
form of a flame, which is composed of glowing particles of the burning
material and certain gaseous products that are luminous at the temperature of
the burning material.
CHEMISTRY OF FIRE
Obviously, three things are required for combustion or fire: FUEL
(Combustible materials to vaporize and burn), OXYGEN (Oxygen in air is the
common oxidizing agent, to combine with fuel vapor, air contains 28% O, 78
N, 1% inert gas), and HEAT (to raise the temperature of the fuel vapor to its
ignition temperature). The combinations of these three elements form the so-
called Fire Triangle.
Figure 1
ELEMENTS OF FIRE
Fire happens at whatever point ignitable fuel within the sight of oxygen
at an incredibly high temperature becomes gas. Flares are the visual pointer
of the warmed gas. Fire can likewise happen from lower-temperature sources.
After some time, burnable materials, for example, seething ashes can arrive
at their start temperature.
1. Heat – a form of energy generated by the transmission of some other form
of energy, as in combustion or burning; the quality of being hot; high
temperature Heat Sources.
A heat source is responsible for the basic start of fire, and is likewise
expected to keep up the fire and empower it to spread. Warmth permits fire
to spread by drying out and preheating close by fuel and warming
encompassing air.
a. Open flame
b. Electrical circuit
c. Sparks
d. Hot surfaces
e. Friction
f. Ignition
3. Fuel - any substance which reacts chemically with oxygen and produces
flames.
-is any kind of combustible material. It’s characterized by its moisture
content, size, shape, quantity and the arrangement in which it is spread
over the landscape. The moisture content determines how easily it will
burn.
Fuel Sources
a. Solid – molecules are closely packed together
b. Liquid – molecules are loosely packed
c. Gas – molecules are free to moved
Common Types of Solids
a. Bulky: coal, wood, wax, grease
b. Finely divided: plastic, paper, cork, leather
c. Dust: saw dust, sugar, grain, others
LESSON II
In order to understand how fire extinguishers work, you first need to
know a little about ignition. Sadly, it is incomprehensible in this short
introduction to totally describe all the mind confusing compound and physical
responses that occur during a fire. Anyway this page will endeavor to present
the principal hypotheses of fire and blast.
FIRE TETRAHEDRON
The fire tetrahedron is a four-sided mathematical portrayal of the four
variables fundamental for fire: fuel (any substance that can go through
burning), (heat energy adequate to deliver fume from the fuel and cause
start), oxidizing operator (air containing oxygen), and uninhibited compound
chain response (adequate exothermic response energy to create start). The
fuel/air proportion must inside combustible cut off points, which portrays the
measure of fume in air important to engender fire. Eliminating any of these
four elements will forestall, stifle, or control the fire.
The Fire Tetrahedron (A pyramid)
For a long time the
idea of fire was represented
by the Triangle of
Combustion and spoke to,
fuel, warmth, and oxygen.
Further fire research
discovered that a fourth
component, a substance
chain response, was a vital
part of fire. The fire triangle
was changed to a fire
tetrahedron to mirror this
fourth component. A
tetrahedron can be depicted
as a pyramid which is a
strong having four plane countenances. Basically every one of the four
components must be available for fire to happen, fuel, warmth, oxygen, and a
substance chain response. Expulsion of any of these basic components will
bring about the fire being stifled.
Figure 2.
PROPERTIES OF FIRE
A. The Physical properties
1.Specific Gravity – the ratio of the weight of a solid or liquid
substance to the weight of an equal volume of water.
2. Vapor density – the weight of a volume of pure gas composed to
the volume of dry air at the same temperature and pressure.
3. Vapor Pressure – the force exerted by the molecules on the surface
of a liquid.
4. Temperature – the measure of the degree of thermal agitation of
molecules.
5. Boiling Point – the constant temperature at which the vapor
pressure of the liquid is equal to the atmospheric pressure.
6. Ignition/Kindling temperature – the minimum temperature at which
the substance must be heated in order to initiate combustion.
7. Fire point – the lowest temperature of a liquid in an open container
at which vapors are evolved fast enough to support combustion.
8. Flash point – the temperature at which a flammable liquid forms a
vapor-air mixture that ignites (mixture with in the explosive range).
LESSON IV
PRODUCTS OF COMBUSTION
Fire gases - chemical composition of the fuel, percent of oxygen
present, and the temperature of the fire.
Flame - The luminous body of a burning gas. It is the manifestation of
fire when the fire is in its gas phased combustion.
Heat - a form of energy generated by the transmission of some other
form of energy.
Smoke - a visible product of incomplete combustion, a mixture of
oxygen, nitrogen, CO, CO2 and finely divided particles released from
the burning material.
CO
CO2
Hydrogen gas
Nitrogen
Other poisonous gases
Hydrogen Sulfide (H2S), Hydrogen Cyanide (HCN), Hydrogen Chloride
(HCL)
Types of Flames:
a. Based on Color and Completeness of Combustibility of Fuel
1. Luminous Flame – is orange-red, deposit soot at the bottom
of a vessel being heated due to incomplete combustion and has
a low temperature.
2. Non-Luminous Flame – is blue, there is complete
combustion of fuel and has relatively high temperature.
c. Based on Smoothness
1. Laminar Flame – when a particle follows a smooth path
through a gaseous flame.
2. Turbulent Flame – are those having unsteady, irregular
flows. As physical size, gas density or velocity is increased, all
laminar gas flows tend to become turbulent.
THE FUELS
FUELS (Combustible Materials) – fuel is matter and matter
exist in three physical states: solid, liquid and gas. Solids melt to
become liquids, and these may vaporize and become gases. The basic
rule is that at high enough temperature all fuels can be converted to
gases. And each of the physical states exhibits different physical and
chemical properties that directly affect a fuel’s combustibility. For
example, gasoline as a liquid does not burn, it is the vapors rising from
the liquid that burn. Likewise, wood, the most common solid fuel, is not
flammable, but gives of flammable vapors (free radicals).
FUEL is also a material that provides useful energy. Fuels are
used to heat and cook food, power engines, and produce electricity.
Some fuels occur naturally and others are artificially created. Such
natural fuels are coals, petroleum, and natural gases obtained from
underground deposits that were formed million years ago from the
remains of plants and animals. They are called fossil fuels, which
account for about 90% of the energy people use today.
Synthetic fuels can be made from fossil fuels, certain types of
rock and sand, and biomass.
Most fuels release energy by burning with oxygen in the air. But
some – especially chemical fuels used in rockets – need special
oxidizers in order to burn. Nuclear fuels do not burn but release energy
through the fission (splitting) of fusion (joining together) of atoms.
Classification of Fibers
a. Natural Fibers – they come from plants (Coir – coconut fiber, Cotton
– seed fiber, pulp – wood fiber) , from animals (wool, silk, protein fibers
– leather), from minerals (asbestos)
b. Synthetic/Artificial Fibers – organic fibers, cellulose fibers,
cellulose acetate, non- cellulose, and inorganic fibers like fiber glass,
steel
Chemical Fuels
Chemical fuels, which are produced in solid and liquid form,
create great amounts of heat and power. They are used chiefly in
rocket engines. Chemical rocket propellants consist of both a fuel and
an oxidizer. A common rocket fuel is the chemical hydrazine. The
oxidizer is a substance, such as nitrogen tetroxide, that contains
oxygen. When the propellant is ignited, the oxidizer provides the
oxygen the fuel needs to burn. Chemical fuels are also used in some
racing cars.
Nuclear Fuels
Nuclear fuels provide energy through the fission or fusion of
their atoms. Uranium is the most commonly used nuclear fuel, though
plutonium also provides nuclear energy. When the atoms of these
elements undergo fission, they release tremendous amounts of heat.
Nuclear fuels are used mainly to generate electricity. They also power
some submarines and ships. Nuclear energy can also be produced
through the fusion of hydrogen atoms.
• Nuclear Fission – split of the nucleus of atoms
• Nuclear Fusion – combination of two light nuclei of atom
Specific Heat
The heat capacity or the measure of the amount of heat required
raising the temperature of a unit mass of a substance one-degree. If
the heating process occurs while the substance is maintained at a
constant volume or is subjected to a constant pressure the measure is
referred to as a specific heat at constant volume.
Latent Heat
A number of physical changes are associated with the change of
temperature of a substance. Almost all substances expand in volume
when heated and contract when cooled. The behavior of water
between 0° and 4°C (32° and 39° F) constitutes an important
exemption to this rule. The phase of a substance refers to its
occurrence as a solid, liquid, or gas, and phase changes in pure
substances occur at definite temperatures and pressures. The process
of changing from solid to gas is referred to as SUBLIMATION, from
solid to liquid as melting and from liquid to vapor as VAPORIZATION.
If the pressure is constant, the process occurs at constant temperature.
The amount of heat to produce a change of phase is called LATENT
HEAT, and hence, latent heats of sublimation, melting and vaporization
exist. If water is boiled in an open vessel at a pressure of 1 atm, the
temperature does not rise above 100°C (212°F), no matter how much
heat is added. For example, the heat that is absorbed without changing
the temperature of the water is the latent heat, it is not lost but
expended in changing the water to steam and is then stored as energy
in the steam, it is again released when the steam is condensed to form
water (Condensation). Similarly, if the mixture of water and ice in a
glass is heated, its temperature will not change until all the ice is
melted. The latent heat absorbed is used up in overcoming the forces
holding the particles of ice together and is stored as energy in the
water.
Heat Production
There are five ways to produce heat:
1. Chemical – chemically produced heat is the result of rapid
oxidation.
2. Mechanical – mechanical heat is the product of friction. The
rubbing of two sticks together to generate enough heat is an example.
3. Electrical – electrical heat is the product of arcing, shorting or
other electrical malfunction. Poor wire connections, too much
resistance, a loose ground, and too much current flowing through an
improperly sized wire are other sources of electrical heat.
4. Compressed gas – when a gas is compressed, its molecular
activity is greatly increased producing heat.
5. Nuclear – Nuclear energy is the product of the splitting or
fusing of atomic particles (Fission or fusion respectively). The
tremendous heat energy in a nuclear power plant produces steam to
turn steam turbines.
Classification of Fires
Based on Cause
1. Natural causes – such as
• Spontaneous heating – the automatic chemical reaction that
results to spontaneous combustion due to auto-ignition of organic
materials, the gradual rising of heat in a confined space until ignition
temperature is reached.
LESSON VI
Fire Extinguishers
A Fire Extinguisher is a mechanical device, usually made of
metal, containing chemicals, fluids, or gasses for stopping fires, the
means for application of its contents for the purpose of putting out fire
(particularly small fire ) before it propagates, and is capable of being
readily moved from place to place.
It is also a portable device used to put out fires of limited size.
LESSON VII
Arson Investigation
What Constitutes Arson?
1. Burning – to constitute burning, pyrolysis must takes place.
In other words, there must be burning or changing, i.e. the fibber
of the wood must be destroyed, its identity changed.
2. Wilfulness – means intentional, and implies that the act was
done purposely and intentionally.
3. Malice – it denotes hatred or a desire for revenge.
4. Motive – is the moving cause that induces the commission of
the crime.
5. Intent – is the purpose or design with which the act is done
and involves the will.
Why is arson very hard to investigate?
-Arson is one of the most difficult offenses to investigate because the
arsonist can be able to set a fire and escape undetected. The fire can
consume the scene and destroy much physical evidence of the offense.
Harder forms of evidence are often buried in debris and grossly altered in
appearance.
Some of the Arson Evidence that the Investigator should seek at the Fire
scene are the following:
Motives of Arsonist
1. Economic Gain
a. Insurance fraud – benefiting
b. Desire to dispose merchandise – loss of market value
being out of season, lack of raw materials, over supply of
merchandise can be a big reason for arson.
c. Existing business transaction that the arsonist would
like to avoid such as impending liquidation, settlement of
Types of Pyromania
a. Abnormal Youth – epileptics, imbeciles and morons
b. Hero Type – a person set a building on fire and pretends to
discover it, turn on the alarm or make some rescue works to
appear as “hero”
c. Drug addicts and alcoholics
d. Sexual deviates and perverts.
2. Prime Suspects (and the Prima Facie Evidences)
The development of prime suspects - this involves identification
results from the full development of leads, clues and traces, the
testimony particularly eyewitnesses and the development of expert
testimony, the following technique may serve the investigation:
1. Search of the fire scene for physical evidence:
a. Protection of the scene
b. Mechanics of search
c. Collection and preservation of evidences
DEFINITION OF TERMS
ABATEMENT - Any act that would remove or neutralize a fire hazard.
ADMINISTRATOR – any person who acts as agent of the owner and
manages the use of a building or establishments.
ARSON - intentional or malicious destruction of property by fire.
BLASTING AGENT – any material or mixture consisting of fuel and
oxidizer used to set off explosives.
CELLULOSE NITRATE OR NITRO CELLULOSE – a highly
combustible and explosive compound produced by the reaction of nitric
acid with a cellulose material.
CELLULOSE NITRATE PLASTIC (PYROXYLIN) - any plastic
substance, materials or compound having cellulose nitrate as base.
COMBUSTIBLE/FLAMMABLE OR INFLAMMABLE - Descriptive of
materials that are easily set on fire.
COMBUSTIBLE FIBER – any readily ignitable and free burning fiber
such as cotton, rags, waste clothes, papers, kapok, hay, straw,
Spanish moss and other similar materials commonly used in
commerce.
COMBUSTIBLE LIQUID - any liquid having a flash point at or above
37.8 degrees Celsius or 100 degrees Fahrenheit.
COMBUSTION – a chemical process accompanied by the evolution of
heat and light. More accurately, it is the rapid oxidation of fuel so as to
produce flame (burning gases), heat, and light.
CORROSIVE LIQUID – any liquid which causes fire when in contact
with organic matter or with certain chemicals.
CURTAIN BOARD - a vertical panel of non-combustible or fire resistive
materials attached to and extending below the bottom chord of the roof
trusses, to divide the underside of the roof into separate compartments
so that heat and smoke will be directed upwards to a roof vent.
CRYOGENIC - descriptive of any material which by its nature or as a
result of its reaction with other elements produces a rapid drop in
temperature of the immediate surroundings.
DAMPER - A normally open device installed inside an air duct system
which automatically closes to restrict the passage of smoke or fire.