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µ
where the Einstein’s summation rule is applied. The dissipation elements of D̄l govern coupling between coherence and
µ µ
rates Dl , D̄l are given in the Supplementary Materials, which population dynamics for different coordinates αµ and αl in
contains parameters of the form nTω = 1/(eh̄ω/kB T − 1), i.e., the coherent space. Since the coherent state |αi i is the superpositions
µ
mean number of bosons with frequency ω in thermal equilibrium of Fock states |ni i for sites i, The off-diagonal term of D̄l
at temperature T. The non-equilibrium dynamics can emerge naturally represents the coherence in Fock states |ni i for site i,
which is introduced by interaction terms i6=j 1ij a†i aj . When
P
under different temperatures of the two environments while
assuming identical coupling strengths to both environments: coupling between different sites 1ij → 0, the diffusion matrix
fki(1) = fki(2) ; i = 1, 2, ..., N. will have no off-diagonal terms between different sites and the
One conventional way to solve QME in Equation (3) was to density matrix P(α, α ∗ ) in coherent space can be decomposed
write the density matrix as a supervector in Liouville space [20, into the production of density matrices in sub-space of different
21]. However, this strategy gives rise to an infinite dimensional coherent coordinates: P(αi , αj , αi∗ , αj∗ ) = Pi (αi , αj )Pj (αi∗ , αj∗ ).
Fock space for bosons, which makes it difficult to manipulate. On the other hand, with no interaction between different sites,
Here we will consider the coherent representation, which obviously the coherence of density matrix ρs in Fock space |ni i
was first developed by Glauber [18], with the establishment will vanish as well. Later, we will uncover the important link to the
of a close analog to classical Fokker-Planck equations. The geometrical curvature introduced by non-equilibrium dynamics.
coherent state is the eigenstate of the annihilation operators and
satisfies: âj |{αi }i = αj |{αi }i. The coherent state is introduced 3. FORCE DECOMPOSITION, FLUX
in a wide range of physical systems, from quantum harmonic
oscillators, quantum optics, superconductivity, superfluid, to In classical non-equilibrium dynamical systems, the dual
string theory. Coherent states mostly describe the classical-like description with both potential and flux has been identified
states by displacing the ground-state wave packet from its origin, and quantified to determine the global dynamics [11, 13, 23].
which minimizes the uncertainty relation. On the basis of Fock There, in the continuous space, the non-equilibrium dynamics
states, the coherent state can be written as: are governed by Fokker-Planck equations with a driving force
which can be decomposed into the gradient of a potential and a
∞
|αi |2 X α ni curl flux, quantifying the degree of the detailed-balance-breaking.
|αi i = e− 2 √ i |ni i (4)
ni ! Therefore, by observing the analogous form of the density matrix
n =0
i
dynamical equation (5), a similar investigation can be applied for
with the probability of in state |ni i following Poissonian non-equilibrium quantum systems.
distribution and the average boson number hn̂i i = |αi |2 . Defining the probability flux J as Jµ = F̃µ P − D̃µν ∂ν P,
Then the density and quantum Fokker-Planck equation (5) can be written as a
R QNmatrix2 can be expanded by the coherent
∗ }, t)|{α }ih{α }|. continuity equation ∂t P + ∇ · J = 0 in coherent space. F̃µ is the
states as: ρs (t) = m=1 d αm P({αi }, {αi i i
By introducing the short notation α ≡ {αi }, the resulting PDE driving force in the complex coherent state space xµ ≡ {αi , αi∗ }
takes the form of the classical Fokker-Planck equation: with i = 1, 2, ..., N representing N different sites, and D̃µν are
symmetric diffusion coefficients:
!
∂ ∗ µ µ ∂ ∂ ∗ N h
P(α, α , t) = (Dl − D̄l ) αl + ∗ αl X i
∂t ∂αµ ∂αµ F̃a = − (γa(1) + γa(2) )δal αl ,
!
∂2 ∂2 l=1 (6)
µ
+D̄l + P(α, α ∗ , t) (5) D̄al + D̄la
∂αµ∗ ∂αl ∂αµ ∂αl∗ D̃al∗ =
2
with a quasiprobability distribution P(α, α ∗ ). The non-negative
Here, starred indexes indicate complex components
quasiprobability P(α, α ∗ ) acts like an ordinary probability
corresponding to the coordinates {αi∗ }. γa(i) =
distribution in Fokker-Planck equations with dependence on
complex variables [22]. π N (ν̄)(fν̄a(i) )2 /h̄2 , i = 1, 2 is the damping coefficient depending
µ µ on the site index and N (ν̄) is the density of states.
The driving force (Dl − D̄l )αl represents the environmental
influences from tracing out the baths. This driving force is linear The steady-state quasiprobability distribution satisfies ∂t Pss =
in the coherent coordinate αl , which will push the system to the 0 and the steady-state probability flux Jss is given by
coherent state with larger |α|. Since |α|2 represents the average
boson number and the large boson number represents a higher Jµss = F̃µ Pss − D̃µν ∂ν Pss (7)
average energy of the system, this driving force, which is due to
the coupling to the environment heat baths, will effectively drive which implies that Jss is a curl flux (a solenoidal vector field)
the quantum system to a higher energy level. satisfying ∇ · Jss = 0. This does not necessarily mean that
µ
The diffusion term D̄l represents the transitions between the flux Jss = 0. Instead, due to the detailed-balance-breaking,
different energy levels of each site (for diagonal diffusion matrix the divergence-free condition implies that the net non-zero
elements) and between different sites (for off-diagonal diffusion coherent state space dependent flux is a rotational curl field
matrix elements). In particular, the off-diagonal diffusion matrix in complex coherent state space. For general non-equilibrium
systems without detailed balance: Jss 6= 0, the force term F̃µ can As we discussed in the previous section, the interactions between
not be written as the gradient of a potential. From Equation (7), different sites introduce the coherence. When the coupling δij
the driving force for non-equilibrium quantum dynamics can be between different sites vanish, the coherence between different
decomposed into two parts in the complex coherent state space: sites will go to zero. Meanwhile, the diffusion matrix D̃µν and its
a potential gradient term −D̃µν ∂x∂ ν U where U(x) = − ln Pss and inverse matrix D̃−1µν will be diagonal. Then, following the linear
flux term −JµSS /PSS ≡ −vµSS , where vSS represents a probabilistic
µ driving force F̃µ as in Equation (6), we have the gauge field Aµ ∝
velocity. In the next section, we can see that this potential- xµ and the curvature of the internal charge space Rµν = 0. In
flux landscape provides new insights into the non-equilibrium this way, we linked the coherence from the quantum systems to
quantum dynamics. the internal curvature of coherent state space, which only become
Analogous to the classical non-equilibrium systems, using Ito non-zero in non-equilibrium quantum dynamics.
calculus, dynamically quantum Fokker-Planck equation (5) is Similar to Abelian gauge theory, we can define the Wilson loop
equivalent to Langevin equations in the coherent state space: or Wilson line along any specific path ζ (t) = {α(t), α ∗ (t)} as:
dxµ
= F̃µ + Bµν ξν (t) (8)
R
dt Uζ (t) (x, y) = e−1sm = e− ζ (t) Aµ dζµ (12)
where [·] indicates a commutator of two operators. According where 6 is the surface of the closed loop C, dσij is the area
to Equation (7), for the detailed balance case: JSS = 0, element on this surface, and Rij is the curvature due to the gauge
Aµ = ∂µ ln(PSS ) is a pure gradient and the curvature is zero: field A. Under the gauge transformation Aµ → Aµ + ∂µ φ, the
Rµν = 0 which corresponds to a flat internal space. While for Wilson loop U(x, y) or the exponential of the quantum work,
non-equilibrium cases, A cannot be written as a gradient and or heat dissipation, transforms as: U(x, y) → eφ(x) U(x, y)e−φ(y) ,
Rµν 6= 0 which corresponds to a curved internal space. On while Rij and U(x, x), or the exponential of quantum work/heat
the other hand, Rµν = 0 also means that Aµ can be written dissipation are gauge invariant. Therefore, the non-equilibrium
as a pure gradient which can lead to a steady state solution PSS quantum dynamics and thermodynamics relate to an internal
to ensure JSS = 0. In other words, JSS = 0 and Rµν provide curved coherent space. Here, the gauge field A can also be
equivalent measures of whether the detail balance is broken or considered as a Berry connection and the curvature Rij as a
not. Therefore, by checking the internal phase space curvature Berry curvature. The non-zero flux in quantum dynamics breaks
Rµν , we can know if the system is in detail balance or not without the detailed balance, which leads to non-zero internal curvature
knowing the steady state solution or by solving the steady state in the coherent state space and a global topological non-trivial
flux. In addition, Rµν is a gauge invariant tensor: for a gauge phase analogous to quantum mechanical Berry phase [11]. This
transformation Aµ → Aµ + ∂µ φ, Rµν → R′µν = Rµν . can also lead to quantum work and heat dissipation, which is
Furthermore, the probabilistic velocity v and the flux J are also important for quantum thermodynamics. The phase factor of
related to this internal curvature as: Wilson line 1sm in Equation (13) plays an important role in the
time irreversibility for non-equilibrium systems [14, 24–27] and
∂µ (D̃−1 −1
νσ vσ ) − ∂ν (D̃µσ vσ ) = Rµν (11) generalized FDT for non-equilibrium dynamics [14].
A(x, x′ , t − t ′ ) (20)
Equation (15) provides a general relation between the response SS ′ ′ ′ SS ′ ′
functions and the correlation functions, which is a general = P (x )P(x, t|x , t ) − P (x)P(x , t|x, t )
PSS (x)
Z
extension of FDT to non-equilibrium quantum systems [19,
= PSS (x′ ) D[x]P̃(x, t|x′ , t ′ ) 1 − SS ′ e−1sm
26, 27]. Here, h...i represents the average over the steady- P (x )
state quasiprobability distribution PSS . In particular, if the
perturbation is independent on α, α ∗ : δFµ′ = δFµ′ µ , we obtain Here, D[x] is the path integral from x′ (t ′ ) to
x(t). Then, we can rewrite the response function,
′ SS
R
µ (t − t ) = −h(t)∂µ ln[P (x)]i (16) as
h i
= − h(t)F̃ν (t ′ )D̃−1
µν (t ′
)i + h(t)vν
SS ′ −1 ′
(t ) D̃ µν (t )i hd i
′ −1
R
µ (t − t ) = −D̃µη hxη (t)(t ′ )i
Equation (16) is a quantum generalization of FDT for non- Zdt
equilibrium systems. The response of the system can be −D̃−1
µη dxdx′ (x)Fη (x′ )A(x, x′ , t − t ′ )
decomposed to two terms. The first term, which is present in FDT
of equilibrium systems obeying the detailed balance is related to −D̃−1 SS ′
µη h(t)vη (t )i (21)
the equilibrium contribution due to the correlation of the variable
with the driving force. The second term is directly related to With the operator (x) = xν , the response function
the nontrivial non-zero flux which violates the detailed balance reads
and measures the degree of non-equilibrium (how far away the
hd
system is from equilibrium).
i
Rνµ (t − t ′ ) = −D̃−1
µη hxη (t)xν (t ′ )i
For the quantum equilibrium system with detailed balance, Zdt
we have JSS = 0 and time reversal invariant: h(t)Fν (x(t ′ ))i =
−D̃−1 dxdx′ xν Fη (x′ )A(x, x′ , t − t ′ )
hFν (x(t))(t ′ )i. Using the Langevin equation (8) in coherent µη
FIGURE 1 | Coherence C(ρ) varies as the function of the curvature R. Red, Blue, and Green lines represent F2 = 4ps, F2 = 8ps, and F2 = 16ps, respectively. (A)
1ε = ε1 − ε2 = 0.2ev and (B) 1ε = ε1 − ε2 = 0.4ev. Other parameters are F1 = 2ps, T1 = 2100K, ε1 = 0.5ev, 1 = 0.3ev.
by studying an explicit example: a simple model describing Then, Abelian gauge field can be written as
energy transfer simulated by two harmonic oscillators coupled to
Y1 F̄1 α1∗ + Y3 F̄2 α2∗
two environments with different temperatures.
Y1 F̄1 α1 + Y3 F̄2 α2
Aµ = −D̃−1
µν F̃ν = − Y F̄ α ∗ + Y F̄ α ∗
(26)
3 1 1 2 2 2
H0 = ε̄1 a†1 a1 + ε̄2 a†2 a2 + 1̄(a†1 a2 + a†2 a1 ) Y3 F̄1 α1 + Y2 F̄2 α2
2 X
(23) where inverse matrix reads
h̄ωk b(ν),† bk(ν)
X
+ k
ν=1 k
0 Y1 0 Y3
Y1 0 Y3 0
and the interactions are D̃−1
µν =
0
(27)
Y3 0 Y2
2 X
2 X Y3 0 Y2 0
fki(v) (a†i b(v) (v),†
X
Hint = k + ai bk ) (24)
i=1 v=1 k D̄22 D̄11
with elements Y1 = D̄11 D̄22 −D̄∗D̄
, Y2 = D̄11 D̄22 −D̄∗D̄
, and
The operator Fokker-Planck equation (in the interaction picture) D̄
Y3 = D̄∗D̄−D̄11 D̄22
. It easy to calculate the curvature of the
in the coherent state space Equation (5) reads
internal charge space due to the non-trivial Abelian gauge
∂P(αβ , αβ∗ )
field Aµ :
∂ ∂
= F̄1 α1 + F̄2 α2 + c.c. P(αβ , αβ∗ )
∂t ∂α1 ∂α2 0 0 0 R
0 0 R 0
∂2 ∂2
+ D̄11 + D̄ 2 Rµν =
0 −R 0 0
(28)
2
∂α1∗ ∂α1 ∂α2∗ ∂α2
2
−R 0 0 0
∂2
∂
+ 2D̄ + P(α, α ∗ ) with
∂α1∗ ∂α2 ∂α1 ∂α2∗
promote the emergence of the steady state coherence. On the gauge field is non-trivial, the detailed-balance is broken with
the other hand, as we mentioned in the beginning of the non-local quantum coherence. This provides a new fundamental
article, when the coupling between different sites vanishes, it view in quantum physics: the non-local coherence can emerge
leads to vanishing coherence between different site D̄ = 0 from the non-equilibrium detailed-balance breaking which can
or zero quantum correlations and the zero internal curvature be measured by an internal curvature of the gauge field in
Rµν = 0. The detailed-balance is more broken as the phase space.
temperature difference between two baths increases, leading to The steady state curl quantum flux is of
higher coherence. the form:
In addition, the steady state of the two quantum oscillators
under the two baths is exactly solvable, which has the JαSS1
vαSS1 = = (vαSS∗ )∗ (36)
form of: PSS 1
F̄1
1 −[A1 |α1 |2 +A2 |α2 |2 +BRe(α1 α∗2 )] D̄ ∗ D̄( 21 − )A1 F̄1 1
PSS (α, α ∗ ) = e (30) =
F̄1 +F̄2
α1 +( − )D̄A2 α2
A (F̄1 + F̄2 )D̄2 2 F̄1 + F̄2 2
with JαSS
vαSS2 = 2 = (vαSS∗ )∗ (37)
PSS 2
(F̄1 + F̄2 )D̄22
A1 = (31) 1 F̄2
D̄ ∗ D̄( 2 − F̄ +F̄ )A2
D̄11 D̄22 F̄1F̄+F̄2 − 4 F̄ F̄+2F̄ D̄ ∗ D̄ 1 2 F̄2 1
1 1 2 = α2 +( − )D̄A1 α1
(F̄1 + F̄2 )D̄11 F̄1 + F̄2 2
(F̄1 + F̄2 )D̄11
A2 = (32)
D̄11 D̄22 F̄1F̄+F̄2 − 4 F̄ F̄+1F̄ D̄ ∗ D̄ Here, from steady state curl quantum flux, we have the same
2 1 2
observations as from the internal curvature Rµν discussed above.
2D̄
B= (33) On the other hand, from the coherent space {α, α ∗ } to the
D̄11 D̄22 F̄F̄1 +F̄F̄2 − 4 F̄ 1
D̄ ∗ D̄ Fock space, the coherence between αi and αj is equivalent
1 2 1 +F̄2
to the coherence or coupling between eigenstate of different
With a given density matrix, the coherence sites: |ni i and |nj i, since the coherence is introduced by the
interaction term i6=j 1ij a†i aj . If the coupling between different
P
∞
∞ X
C(ρ) = Tr(ρs a†1 a2 ) =
X
hn1 − 1, n2 |ρs |n1 , n2 − 1i (34) sites vanishes, we have D̄ → 0 and no interactions between sites,
n1 =1 n2 =1 which leads to the curvature Rµν → 0 and steady curl quantum
flux vµSS → 0. Therefore, there will be no quantum correlations
can be used to quantify the non-local correlations between regardless of the environmental conditions.
the vibrational modes of spatially separated sites, from the
combination of off-diagonal elements of the density matrix
7. CONCLUSION
in the Fock space. In our model, the coherence can be
written as: In this study, we have uncovered that non-equilibrium quantum
dynamics gives rise to an intrinsic geometric curvature which
2D̄ can enhance quantum coherence. The non-equilibrium can
C(ρ) = (35) be characterized by the curvature. This may help reveal an
F̄1 + F̄2
intrinsic connection between the space time geometry/topology
When the coupling between different sites D̄ = 0, we have and the quantum nature. On the one hand, curved space time
B = 0, which leads to C(ρ) = 0 and the curvature may emerge from the non-equilibrium quantum dynamics,
R = 0. This means, when the coupling between different sites on the other hand, the intrinsic underlying curved space
vanishes, the coherence between spatially separated sites vanishes time may provide a possible channel (space time shortcut) or
at the steady state. In Figures 1A,B, we plot the coherence physical origin for the non-local quantum correlations such as
C(ρ) vs curvature R with different sets of parameters. One coherence and entanglement. Furthermore, we illustrated that
observation is that all curves cross the same points: when the intrinsic curvature could lead to new fluctuation-dissipation
coherence C(ρ) is zero, the curvature R is 0. The coherence theorem for non-equilibrium quantum systems. Therefore, the
C(ρ) depends on the curvature R in a nonlinear and non- curved space time geometry/topology from non-equilibrium
monotonic way. In the near-equilibrium region where R ≈ can give rise to new types of fluctuations in addition to
0, the quantum coherence C(ρ) increases with the internal the original spontaneous fluctuations. The non-equilibrium
curvature R. response is now linked not only to the spontaneous fluctuations
Therefore, quantum coherence is naturally connected to around the equilibrium but also to the non-equilibrium
the internal curvature of the gauge field. Without quantum fluctuations that originated from the curved geometry/topology
coherence, the gauge field is trivial associated with flat internal or non-equilibrium. We have also shown that the curved
space. On the other hand, when the internal space is not flat and geometry/topology characterized by the intrinsic curvature
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