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Hussin
BSN 1 F
Questions:
1) How are carbohydrates defined?
The most prevalent and widely distributed organic substance in nature, carbohydrates are
a necessary component of all living things. During the process of photosynthesis, green
plants convert carbon dioxide and water into carbohydrates. In addition to providing
energy for organisms, carbohydrates are crucial structural elements in living things. They
also make up a portion of the nucleic acids, which carry genetic information.
Saccharide- Sugar
Ketose- Monosaccharides, which are essential fuel molecules and the building blocks of
nucleic acids, include ketoses. Dihydroxyacetone is the most basic kind of ketose.
Pyranose- Pyranose is the catchall term for saccharides that have a six-membered ring
made up of five carbon atoms and one oxygen atom in their chemical makeup.
Monosaccharide- Monosaccharides are sugar molecules that are incapable of being
hydrolyzed2 into simpler (smaller) sugar molecules.
Aldose- A simple sugar called an aldose is a monosaccharide with a carbon backbone
chain, an aldehyde group on the last carbon atom, and hydroxyl groups attached to every
other carbon atom.
Furanose- Carbohydrates with a chemical structure that includes a five-membered ring
system made up of four carbon atoms and one oxygen atom are collectively referred to
as furanoses.
7) What is the bond that joins together the monosaccharide units to form a more complex
polysaccharide?
Animals and plants build them from simpler monosaccharide molecules by fusing a large
number of the smaller molecules together using glycosidic bonds (-O-). In some of the
largest polysaccharide structures, 10,000 separate units may be connected.
8) Explain the meaning of the designations D and L as used to specify the configuration of
carbohydrates.
In front of the names of sugars and amino acids, the letters D- and L- are frequently used.
What are they saying? The (R,S) CIP system predates D- and L- as a description of the
absolute configuration of molecules. A dated but still useful abbreviation for expressing
that molecules are enantiomers is D- and L-.
10) Explain the conventions for using and to designate the configuration of cyclic
forms of monosaccharides.
-used when the terminal -CH2OH is on the same side of the ring as the -OH on the
anomeric Carbon (up)
-used when the terminal -CH2OH is on the opposite side of the -OH on the anometric
carbon (down)
17) Write ring and opened-chained structure of ribose, deoxyribose, glucose, galactose,
fructose?
18) What is the most important monosaccharide in the human body?
Glucose, which serves as the body's main source of cell fuel and is abundant and
important nutritionally, can be found unbound in body tissues and fluids. Several
polysaccharides can be formed from glucose. Additionally used as cell fuel are galactose
and fructose.
19) Draw the structure of the following hexoses in the Haworth and Fischer projection:
a) Mannose
b) Galactose
a) Glucose b) Fructose
The observed change in the optical rotation of the - and - anomers of glucose upon solvent
dissolution is referred to as "mutarotation" (literally, "change in rotation"). The - and - forms
gradually interconvert until equilibrium is reached as a result of ring-chain tautomerism.