Scale Prediction Excel workbook

How to use:
1- Input the water analysis data in ( Data Input sheet)
2- For scale calulations, the data must include (Measured pH , or CO 2 mole fraction in gas, tem
3- Go to report #1, and print or explore the results of hypothetical combinations.
4- Go to report #2, and or explore Carbonate scale prediction results, made by 3 methods
5- The caronate scale prediction using the second method (Oddo & Thomson), are made by b
6- The calculated pH, is a faactor of CO 2%, temperature, and pressure
7- The value of the calculated pH, exists in report #2
8- Go to report #3, and print or explore the sulfate prediction results.
9- You can use Mixture sheet for water mixtures.(Enable macro to use it)
10- You can save the data using the Macro button

Write in the green cells only in next sheets

Prepared by: Yasser Kassem Book site (here)

Free parts of fundamentals of oil and gas processing book

http://oilprocessing.net/data/documents/oil-and-gas-processing-fundamentals.pdf

‫اب بالعربية عن معالجة البترول والغاز وهو ترجمة للكتاب اإلنجليزي‬

http://oilprocessing.net/data/documents/ogparabic.pdf
‫ ) وتقوم بتنزيله مباشرة على الالب‬...‫ ومن الممكن أن تختار من يمين الماوس وهو على الرابط (احفظ الملف أو الهدف ك‬,‫ف وتحفظه بعد ذلك‬
‫توب أو الكمبيوتر‬.

Discussion board
http://www.oilprocessing.net/oil/

http://www.oilprocessing.net/ Books and main site

 CO 2 mole fraction in gas, temperature, and pressure
combinations.
ults, made by 3 methods
& Thomson), are made by both measured pH in data input, or calculated pH,

Book site (here)

ssing-fundamentals.pdf

‫ ومن الممكن أن تختار‬,‫ممكن تفتح الملف وتحفظه بعد ذلك‬

 Data Input (single)

Water from Write in the green cells only .

Analysis Mg/L Then print reports 1, 2, and 3.
Ca++ 1600 PH 6.2
Mg++ 240 Temp.(0f). 100
Cl- 12294 Press. (psig) 100
SO4-- 1800 Sp.Gr.60/60 1.036
HCO3- 550 CO2 Mole fraction in gas % 2
TDS By Evaporation. 0 Stiff & Davis (K) . 2.86
Iron 0 Ionic strength (u). 0.4937401
H2S In Water 0 Ca-Sulfate (Ksp). 0.001075
CO2 In Water 0 BaSO4 KSP. 6.50E-09
Ba++ In Water 0 SrSO4 KSP . 7.00E-06
Sr++ In Water 0

Page 4
 Data Input (single)

Book site (here)

Other books are included

Page 5
 Mixtures

WATER COMPOSITION & MIXING RATIOS

Mixing ratio% 50 50 0 0
WATER A B C D
Ca++ 600 3000
Mg++ 535 702 Ca++
Cl- 55814 3545 Mg++
SO4-- 900 100 Cl-
HCO3- 700 50 SO4--
TDS By Evaporation. 120125 15154 12121 2322 HCO3-
Iron TDS By Evaporation.
H2S In Water Iron
CO2 In Water 0 0 H2S In Water
Ba++ In Water CO2 In Water
Sr++ In Water Ba++ In Water
PH 6.5 6.5 Sr++ In Water
Temp.(0f). 120 120 PH
Press. (PSI) 30 10 Temp.(0f).
Sp.Gr.60/60 1.06 1.012 Press. (PSI)
CO2 Mole fraction in gas % 0 0 Sp.Gr.60/60
CO2 Mole fraction in gas %

Page 6
 Mixtures

1800
618.5
29679.5
500
375
67639.5
0
0
0
0
0
6.5
120
20
1.036
0

Page 7
 WATER ANALYSIS REPORT

Sample from 0
Status OIL WELL
Date collected 1/1/1999

IONS Mg/L Compounds Mg/L

Na++K+ 8332 Calcium Carbonates 451
Ca++ 1600 Magnesium Carbonates 0
Mg++ 240 Calcium Sulphates 2551
Cl- 12294 Magnesium Sulphates 0
SO4-- 1800 Calcium Chloride 1851
HCO3- 550 Magnesium Chloride 940
(Na-K) Chloride 18737
TDS Calculated. 24530
TDS By Evaporation. 0

Physical properties

Sp.Gr. 60/60 deg f 1.036

PH at 20 deg C 6.2
Salinity as Cl- mg/L 12294
Salinity as NaCl mg/L 20285.1 Discussion boar
Total Alkalinity as CaCO3 451 http://www.o
Total Hardness as CaCO3 4978
Temporary Hardness as CaCO3 451
Permanent Hardness as CaCO3 4528 http://www.oilp

Other constituence

GASES Mg/L IONS Mg/L

H2S In Water 0 Iron 0
CO2 In Water 0 Ba++ In Water 0
Sr++ In Water 0
 WATER ANALYSIS REPORT

Discussion board
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 Ca-Carbonates scale prediction.
Water from 0

Temp. 0f 100 PH measured 6.20

Press. (PSI) 100 P calc.
H
6.50 "According to press,temp &%co2 in gas"
%CO 2 in gas 2 K value 2.86
Ionic strength ( u ) 0.49374

(1) Stability Index (SI) calculation using Stiff & Davis method
SI = -0.10 SCALE IS NOT LIKELY
The + ve value indicates that scle is likely to form
The greater the +ve the greater the scale tendency .
(2) Saturation Index (Is) calculation using Oddo & Tomson method (2)
If the PH is measured Is = -0.01 SCALE IS NOT LIKELY
If the P is not measured ( calc.)
H
Is = 0.29 SCALE IS LIKELY
The + ve value indicates that scle is likely to form.
The greater the +ve the greater the scale tendency .
(3) Calculation for the amount of Ca-Carbonate scale in PTB
According to Valone and Skillern Method.

Amount of scale in PTB = 0

NO SCALE IS EXPECTED

NOTES :-
Method # 1 SI=PH-K-PCa -PALK
The value of K is a function of salinity, composition of water and temp.
Values of K are obtained from a graphical correlation with ionic strength & temp .
The curves are based on experimental data measured over the following range :-
0-3.6 molar ionic strength 0 , 30 & 50 deg c.
All curves outside this data curves are extrapolated .
( PH is the actual measured ) .
Method # 2
This method includes the effect of pressure and co 2 % in gas.
This method is said to be valid over the following range :-
Molar ionic strength : 0 - 4 Temp. 0 - 200 deg. c
press. 0 -20 000 psig This method can use the pHmeasured or calculated .
Is=LOG [ TCaAlk 2/ PTX CO2 ] + 5,89+1,549*10-2T-4,26*10-6 T2-7,44*10-5P-2,52 U1/2+0,919 U
Or. Is = LOG (TCaA lk)+PH-2,78+1,143*10-2T-4,72*10-6T2-4,37*10-5P-2,05U1/2+0,727U

Method # 3
This method is used to calc.the max amount of CaCO3 which could precipetate.
This method depends on the method # 1 calculaations .
KSP = 10K-PH PTB = 17500 {G-[X2 + 4 ( 10K-pH )]1/2}
Where G =Ca++ + HCO3- Moles /L K = Stiff & Davis constant.
X =Ca++ - HCO3- Moles /L PH is the actual measured .

SCALE PREDICTION REPORT PAGE 1 OF2

 SULFATE SCALE PREDICTION .

Water from 0

Calculation of Calcium Sulfate soluibility (Skilman, McDonald and Stiff method).

S ( meq/L ) = 1000 [(X2 + 4KSP )1/2- X ]

S ( meq/L ) = 47.72333 ACTUAL meq/L = 37.5

THE WATER IS UNDERSATURATION WITH CaSO4 . SCALE IS UNLIKELY .

-10.2
0 Max. Scale amount = 0 Mg/L

Calculation of Barium Sulfate soluibility .

S ( meq/L ) = 0.000694 ACTUAL meq/L = 0

THE WATER IS UNDERSATURATION WITH BaSO4 . SCALE IS UNLIKELY .

-0.000694
0 Max. Scale amount = 0 Mg/L

Calculation of Struntium Sulfate soluibility .

S ( meq/L ) = 0.733098 ACTUAL meq/L = 0

THE WATER IS UNDERSATURATION WITH SrSO4 . SCALE IS UNLIKELY .

-0.733098
0 Max. Scale amount = 0 Mg/L

Note :-
When S ( meq/L ) = Actual concentration , The water is saturated .
When S ( meq/L ) > Actual concentration , The water is undersaturation and scale is unlikely .
When S ( meq/L ) < Actual concentration , The water is supersaturated and scale is likely .

SCALE PREDICTION REPORT. PAGE 2 OF 2

Water from date Na++K+ Ca++ Mg++ Cl- SO4-- HCO3- Total calc. TDS PH Sp.Gr.60/60
Water from date Na++K+ Ca++ Mg++ Cl- SO4-- HCO3- Total cal

0 1/1/1999 8332 1600 240 12294 1800 550 24530

0.00 1/1/1999 19772 4000 619 29680 5000 375 59240
PH Sp.Gr.60/60

6.2 1.036
6.00 1.04
 scale index
Water from date Temp.(0f). PH Press. (PSI) CO2 Mole fraction in gas % For pH calculatd
scale index
For pH measured
Water from date Temp.(0f). PH Press. (PSI) CO2 Mole fraction in gas % pH calculatd pH measured
0 1/1/1999 100 6.2 100 2 0.29 -0.01
0 1/1/1999 150.0 6.0 2500.0 2.0 -0.67 0.24