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.U0025/ Combi
nat
ion

Ki
bul
iSecSchool

UgandaAdv
ancedCer
ti
fi
cat
eExami
nat
ions

Mock2016

Chemi
str
yP525/
2

Ti
meal
l
owed:
2houi
rs30mi
nut e24thJune,
esDat 2016(
7.30-
10.
00pm)

I
nst
ruct
ions

Answeral
lquest
ionsi
nsect
ionAandanysi
xquest
ionsi
nsect
ionB

I
ll
ust
rat
eyouranswer
sful
l
ywi
thappr
opr
iat
edi
agr
amsandequat
ions.

Youranswer
sshoul
dbev
erycl
earandneat
.

Wher
enecessar
y,assumet
hef
oll
owi
ngconst
ant
s;

Av
ogadr
o’ 02x1023
snumber=6.

Uni
ver
sal
gasconst
ant=8.
314J/
K/mol

At
mospher
icpr
essur
eis101325Nm-2

Far
aday
sconst
ant=96500C.

SECTI
ONAAnsweranyt
hreequest
ionsf
rom t
hissect
ion

1.(
a)Expl
ainwhatismeantbyt
hef
oll
owi
ngt
erms
(i
)mol arconduct
ivi
ty (
2mar
ks)

(
ii
)Cel
lconst
ant (
2mar
ks)

(
b)Aconducti
vi
tycel
lfi
l
ledwi
th0.
1M aqueouspot
assi
um chl
ori
desol
uti
ongav
ea
o
r
esi
stanceat25Cof484.0

(
i)Cal
cul
atet
hecel
lconst
antgi
vent
hatt
hemol
arconduct
ivi
tyoft
hissol
uti
oni
s

01cm2mol
–1
129. (
4mar
ks)

1
 (
ii
)Expl
ainhowt
het
emper
atur
ecanaf
fectt
hecel
lconst
antofacel
l
.(3mar
ks)

(
c)Thef
oll
owi
ngdat
awer
eobt
ainedf
oraqueoussol
uti
onsofsodi
um i deat25oC.
odi

Concent
rat
i dm–3
on/mol Mol
arconduct
ivi
tycm2mol
/ –1

0.
0005 125.
15

0.
0010 122.
80

0.
0027 124.
35

0.
0050 121.
25

(
i) Drawasuitabl
egraphanduseitt
odetermi
net
hemol
arconduct
ivi
tyof
i
nfini
tedi
l
utionforsodi
um i deat25oC.
odi (5marks)
(
ii
)
(
ii
i) Expl
aint
heshapeoft
hegr
aphi
n(c)(
i) (
4mar
ks)

2 Copyandcomplet
ethefol
l
owi
ngequat
ionsandout
li
net
hepl
ausi
blemechani
sm
l
eadi
ngtothemajorpr
oduct.
a) COCH3+NH2CONHNH2 H+

b) (
CH3CH2)
3COH ConcH3PO4
heat

c) CHBr
CH3 CH3O-
Heat

d) C6H6 +CH3COBr FeBr

2

2
3a) Expl
aint
hepr
inci
plesofsol
ventext
ract
ion.(
5mar
ks)

b) Dur i
nganexperiment
,ammoni awaspart
iti
onedbetweenaqueous0. 025M
copper(I
I)sul
phat
esolut
ionandtr
ichl
oromethane.Theconcentr
ationsofammoni a
i
nt heaqueousandtr
ichl
oromet
hanelayerswere0.
075M and0.021M r espect
ivel
y.
Theparti
ti
oncoeff
ici
entforammoniabetweentheaqueousandt r
ichloromethane
mixtur
eis23.

i
) Det erminet hemolarconcentrat
ionoffr
eeammoni ai
naqueoussol ut
ionat
equi li
bri
um. (3marks)
i
i) Stat ethreeassumpt i
onsmade.
(1½mar ks)
i
ii
) Det erminet heformulaofcomplexofcopper(I
I)ionsi
nt heaqueoussolution.
(2½mar ks)
i
v) Wr i
teequationleadi
ngtoformationofcomplexionbetweencopper( II
)
ionsandammoni a.
( 1mar k)
c)Asol utioncont ai
ning12gofXi n60cm3ofwat erwasext r
actedwith30cm3of
et
her.Ifthedi stri
buti
onconstantforXbetweenwaterandet heri
s0.2;cal
culate:

i
) MassofXext r
actedinether
. (3mar
ks)
i
i
) TotalmassofXext r
actedift
hesol
uti
onofX abov
ewasext
ract
ed
successi
vel
ytwicewith15cm3ofet
herinst
ead.
(4marks)

4 Theatomicnumber
sandmel
ti
ngpoi
ntsoft
heoxi
desofper
iod3el
ement
sar
e
shownintheTabl
ebelow.

El
ement Na Mg Al Si P S Cl

Atomi
c 11 12 13 14 15 16 17
number

Oxi
de Na2O MgO Al
2O3 Si
O2 P2O5 SO3 Cl
2O7

Melt
ing 1275 2827 2007 1607 560 30 -
91
poi
ntoC

a)i
) Pl
otagr
aphofmel
ti
ngpoi
ntsofoxi
desagai
nstat
omi
cnumberof
el
ement
s.(
4mks)

i
i
)Expl
aint
heshapeoft
hegr
aph. (
6½ mar
ks)

b)Wr
it
eequat
iont
oshowt
her
eact
ionbet
ween,

3
 i
) Wat
erandP2O5 (
1½mar
ks)

i
i
) Sodi
um hy
droxi
deand

Al
2O3 (
2½mar
ks)

Si
O2 (2½mar
ks)

SO3 (
1½mar
ks)

i
i
i) Hy
drochl
ori
caci
dandAl
2O3 (
1½mar
ks)

SECTI
ONB:
Answeranyt
woquest
ionsf
rom t
hissect
ion

5 Ni
trogen(
II
)oxi
decombi
neswithoxygenat80oCand200at
mospher
est
ofor
m
ni
tr
ogen(I
V)oxi
deaccor
dingt
ot hef
oll
owingequati
on

-
1
2NO(
g)+O2(
g) 2NO2(
g), xkJmol
H=-

(
a)(
i)Wri
teanexpressi
onf
ortheequi
li
brium const
antkp,
fort
hereact
ion. (
01
mark)
(
ii
)Calcul
atekp,
ift
hemixt
urecont
ained67%ni t
rogen(I
V)oxi
deatequil
ibr
ium
(
3½mar ks)

(
b)Stat
ehowt
hev alueofkpwill
beaff
ect
edi
f
(i
) Temper aturei
sincreased (01mar
k)
(i
i
) Acat al
ystisadded (½mark)

(
c)Theki
net
icdat
afort
her
eact
ioni
n(a)i
sshowni
nthet
abl
ebel
ow

I
niti
alr e/Nm-2s-1
at 6.8 27.
2 61.
2 108
P2NO/
N2m-4 0.04 0.
16 0.
36 0.
64

PNO =part
ial
pressur
eofNO
(i
)Plotagraphofinit
ialr
at nstP2NO
eagai (03mar
ks)
(i
i)Usi
ngthegraph,deter
minetheorderoft
her
eact
ion.

6 Usi
ngequati
onsonl
y,showhowt hefol
l
owi
ngi
nterconv
ersi
onsofcompounds
canbecar
ri
edoutinthelabor
ator
y.

4
 a)Et
hanol
tomet
hyl
propanoat
e.

b)But
ane-
1,4-
dioi
caci
dfr
om br
omoet
hane.

c) NHCH3f
rom benzene.

d)(
CH3)
2COHCH2CH3f
rom 1-
chl
oropr
opane.

e)Ny
lon-
6,6f
rom cy
clohex
ene

7a) Sol
uti
onsofmi
sci
blel
i
qui
dsar
eei
theri
deal
ornoni
deal
.

i
) Expl
aint
het
ermi
deal
sol
uti
on. (
2mar
ks)

i
i
) Descr
ibewhatcausessol
uti
onsofmi
sci
blel
i
qui
dst
obehav
enon
i
deal
l
y.

(
4mks)

b) Wat er(
boi
li
ngpoint100oC)andmet
hanol
(boi
l
i nt65oC)f
ngpoi orm an
i
deal
sol
uti
onwhenmixed.

i
) Drawalabel
edvapourpr
essure-
composi
ti
ondi
agr
am f
ormi
xtur
eof
wat
erandmet
hanol. (2½marks)

i
i) Descr
ibehowpur
emethanolcanberecov
eredf
rom ami
xtur
e
cont
aini
ng60% wat
er. (5marks)

c) Ami xt
urecont
aini
ng2-ni
tr
ophenol
and4-
nit
rophenol
wasst
eam di
sti
l
led
at76cmHg pressure.

i
) Namet
hecompoundt
hatdi
sti
l
ledov
erandexpl
ainy
ouranswer
.
(
3½mar
ks)

i
i
) Ift
hesatur
atedv
apourpressur
eofwateratt
heboi
li
ngpointoft
he
mixtur
ewas73cmHg, cal
culat
eper
centageofwat
erindi
sti
ll
ate
col
lect
ed. (
3marks)

8 a) Out
li
net
her
eact
ionst
hatt
akepl
acedur
ingt
heext
ract
ionofi
ronf
rom

5
spat
hici
ronor
e,FeCO3. (
8mar
ks)

b) Br ief
lydescr
ibehowi
ronr
eact
swi
tht
hef
oll
owi
ng.Youranswershoul
d
i
ncl
udeequat
ions.

i
) Wat
er.

i
i
) Chl
ori
ne.

i
i
i) Di
l
utesul
phur
icaci
d.

i
v) Concent
rat
edsul
phur
icaci
d.

END|SUCCESS