TELANGANA STATE MODEL SCHOOL & JR.

COLLEGE
INTERMEDIATE II YEAR – PRE-FINAL EXAMINATION
SUBJECT: CHEMISTRY
Time: 3 hours Max.Marks:60

SECTION: A
Answer all questions: (10x2=20M)
1. What are antibiotics? Give example.
2. Calculate the mole fraction of H2SO4 in a solution containing 98% H2SO4 by mass.
3. What is metallic corrosion? Give one example.
4. What is the role of cryolite in the metallurgy of Aluminium?
5. What happens when Cl2 reacts with dry slaked lime?
6. How is XeOF4 prepared? Describe its molecular shape.
7. What is Vulcanization of rubber?
8. What are artificial sweetening agents? Give example.
9. What is Lanthanoid contraction?
10. Compare the acidic strength of Acetic acid,Chloroacetic acid,Benzoic acid and Phenol.
SECTION: B
Answer any SIX questions (6x4=24M)
11. Derive Bragg’s equation.
12. Define molarity. Calculate the molarity of a solution containing 5g of NaOH in 450ml
solution.
13. What are different types of adsorption? Give any four differences between characteristics
of these different types.
14. Explain Werner’s theory of coordination compounds with suitable examples.
15. Differentiate roasting and calcination with examples.
16. What are hormones? Give example for each of the following
a) Steroid hormones b) Polypeptide hormones c) Amino acid derivatives.
17. Explain the mechanism of nucleophilic bimolecular substitution (SN2) reaction with one
example.
18. Explain a) Hoffmann’s bromamide reaction
b) Carbylamine reaction
SECTION: C
Answer any TWO questions (2x8=16M)
19. i) State Faraday’s first and second laws of electrolysis.
A solution of CuSO4 is electrolysed for 10 minutes with a current of 1.5 amperes. What is the
mass of copper deposited at the cathode?
ii) What is molecularity of a reaction? How is it different from order of a reaction? Name one
bimolecular and one trimolecular gaseous reactions.
20. (a) How is Ozone prepared? How does Ozone react with
i) PbS ii) Moist KI iii) Hg iv) Ag
Give equations.
b) Write the balanced equations for the following
i) NaCl is heated with conc H2SO4 in the presence of MnO2.
ii) Chlorine is passed into a solution of NaI in water.
21. Explain the following reactions with equations
i) Hell-volhard-zelinsky reaction (HVZ)
ii) Decarboxylation
iii) Gatterman-Koch reaction
iv) Clemmensen reduction