BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024 Page 1 of 9

PART : B 16. Calcuate reduction potential of hydrogen

electrode containing solution having pH =
Answer the following questions : (2 marks) 10.
1. State the difference between ideal and non- 17. Calculate EMF of following cell :
ideal solutons. Pt | Br2 |Br- (0.01 M)||H
+ (0.03M) |H2|Pt
2. Define : osmosis and derive the formula of
EoBr2/Br- = 1.09 V.
osmotic pressure.
18. State importance of cell potential of
3. Explain : Reverse osmosis.
electrochemical cell.
4. 2.5 g of CH3COOH is dissolved in 75 g of
19. When 1.5 A current is passed for 10 min.
benzene.
through CuSO4 solution, how much mass
5. 1 g of non electrolyte is dissolved 50 g of
of Cu would be deposited at cathode ?
benzene, which lowers the freezing point by
20. The conductance of 0.01028 M CH3COOH is
0.4 K. if Kf for benzene is 5.12 k Kg/mol
4.95 x 10-5 S.cm-1.
then calculate molar mass of solute.
21. Reaction : 2A→ product, concentration of A
6. Calculate molarity of 450 mL of solution
decreases from 0.5 M to 0.4 M in 10
containing 5 g of NaOH.
minutes. Calculate rate of reaction.
7. State difference between positive and
22. State examples of zero order reaction.
negative deviation from Raoult’s law.
23. State examples of first order reaction.
8. The boiling point of benzene is 353.23 K.
24. What is meant by half time reaction ? Derive
When 1.8 g of nonvolatile solute is dissolved
the formula of half life time for zero order
in 90 g of benzene, its boiling point was
reaction.
raised to 353.11 K. Calculate molar mas of
25. Derive the formula of half life time for first
solute. [Kb=2.53 k kg/mol]
order reaction.
9. At 37oC temperature, 1 g of polymer (molar
26. Explain the Boltzman-Maxwell graph of
mass = 1,85,000 g/mol) is dissolved in 450
mL water. Calculate osmotic pressure of  NE 
Fraction of molecules   vs temperature.
this solution.  NT 
10. If the density of 68 % HNO3 is 1.504 g/mL, 27. What is catalyst ? What is inhibitor ?
calculate molarity of the solution. 28. TiCl3 is paramagnetic, where TiCl4 is
11. Explain: SHE. diamagnetic. Explain.
12. Can ZnSO4 solution be filled in Cu vessel ? 29. The Transition metals and their compounds
[EoCu2+/Cu = 0.34 V] have catalytic properties in solid state. –
13. Explain the remedies of problem persists Explain.
during measurement of conductance by 30. Explan : Lanthanide contraction.
Wheastone bridge. 31. If the atomic mass of an element is 26, then
14. Explain : electrolysis of concentrated calculate magnetic moment of its trivalent
aqueous solution of NaCl by using inert ion in aqueous solution.
electrodes. 32. Which transiton element of 3d series
15. State anodic and cathodic reactions contains maximum number of oxidation
occurred n mercury cell. states ? Why?
33. Explain : preparation of K2Cr2O7 from
chromite ore.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024
34. Explain : interstitial compounds.
35. Explain : alloys.
36. Transition metals can form coordination
compounds. Explain with examples.
37. Explain : general physical characteristics of
lenthoids.
38. Fe2+ ion has more tendency to get +3
oxidation state than Mn2+, why ?
39. Eo values of M2+/M and M3+/M2+ of some
metals are given :
Cr2+/Cr -0.9 V Cr2+/Cr2+ -0.4 V
Mn /Mn -1.2 V
2+ Mn /Mn
3+ 2+ -1.5 V
Fe2+/Fe -0.4 V Fe3+/Fe2+ -0.8 V
Explain following statements by using
above data.
(1) The stability of Fe3+ ion in acid solution
as compared to that of Cr3+ or Mn3+.
(2) The ease with which iron can be oxidized
as compared to a similar process for
either chromium or manganese metal.
40. Why Cu metal cannot liberate hydrogen gas
from acid ?
41. Which is more stable : Cu2Cl2 or CuCl2 ?
why ?
42. When brown coloured compound (A) of
Manganese reacts with HCl, produces gas
(B). When this gas reacts with NH3 gives
explosive substance (C). Identify A, B and C.
43. State geometrical isomers of [MABXL].
44. What is chelating ligand ? Give 2 examples.
45. State optical isomers of cis-[Cr(Cl)2(OH)2]3-.
46. Which type of isomerism is represented by
[Co(NH3)5SO4]Br & [Co(NH3)5 Br] SO4?
Define.
47. State name, hybridization, shape and
magnetic moment of complex : [Ni(CO)4].
48. State the limitaitons of valence bond theory.
49. Explain : Chelate therapy.
50. Explain : biological importance of complex
compounds.
51. Explain : hydroboration oxidation of alkene
compounds.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
Page 2 of 9
52. Explain : acid catalyzed hydration of alkene
with its mechanism.
53. Give conversion : aniline to phenol.
54. Explain : industrial production of phenol by
cumene process.
55. State chemical equation : methanal to iso-
butyl alcohol.
56. Explain : acidity of alcohol.
57. Acidity of phenol is more than alcohol.-Give
reason.
58. Explain : Lucas Test.
59. Write only chemical reactions of
dehydration of primary alcohol.
60. Explain : oxidation of primary alcohol in
different conditions.
61. Explain : bromination of phenol.
62. Explain : Koble’s reaction.
63. Explain : Riemer Tieman reaction.
64. Explain : Acidity of ortho and pera
nitrophenol is more than phenol.
65. (i) State product of mononitration of
phenyl ethanoate.
(ii) State chemical reaction, structure and
name of product obtained by oxidation
of phenol.
66. Give reason : the boiling point of o-nitro
phenol is less than p-nitro phenol.
67. State industrial production of methanol.
68. For preparation of ether, primary alcohol is
more preferable, where dehydration of
secondary and tertiary alcohol is not
possible.
69. Explain prepration of ether from
dehydration of alcohol.
70. Explain : physical properties of ether.
71. Give conversion : phenol→ phenitole.
72. State chemical reaction of bromination and
acylation of anisole.
73. (i) State chemical reaction of dehydration
of 1-methyl cyclo hexanol.
(ii) State reduction reaction of methyl (2-
oxo cyclo hexyl) ethonate by NaBH4.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024
74. Give conversion : propanone to tertiary
butyl alcohol.
75. Give conversion : chlorobenzene to phenol.
(in 2 steps)
76. Give conversion : propene to acetone.
77. Explain : ozonolysis of alkene.
78. Give conversion : acetylene to acetaldehyde. 103. State the chemical reaction of prepration of
79. Give 1-1 example of Stephen and
Gattermann-koch reaction.
80. Explain : preparation of ketone from acyl
chloride.
81. Give conversion : propane nitrile to
propiophenone.
82. Give reason : reactivity of benzaldehyde is
less than propanal.
83. Explain : detection tests of aldehyde.
84. Explain : Aldehyde compounds are less
reactive than ketone compounds towards
nuclephilic addition reaction.
85. Explain : reaction of ketone with alcohol.
86. State chemical reactions of acetone with
hydroxyl amine, hydrazine, 2,4-DNP,
semicarbazide.
87. Explain : Wolf Kishner reduction.
88. Explain : Tollens test.
89. Explan : Fehling test for detection of
aldehyde.
90. Explain : Haloform test.
91. Explain : aldol condensation reaction of
ketones.
92. Give conversion : benzyl alcohol to aceto
phenone.
93. Explain : preparation of carboxylic acid
from Grignard reagent.
94. Give conversion : 1-bromo 3-nitro benzene
to 3-nitro benzoic acid.
95. Give conversion : toluene to terrephthalic
acid.
96. Give reason : Carboxylic acids are more
acidic than phenol.
97. State the chemical reaction of prepration of
phthalimide from phthalic acid.
98. Explain : Decarboxylation reaction.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
Page 3 of 9
99. Explain : Hell Wolhard Zeilensky reaction.
100. State uses of carboxylic acids.
101. Give conversion : benzene to methyl
benzoate.
102. Give conversion : benzoic acid to
benzaldehyde.
1-phenyl ethanol from bromo benzene.
104. An organic compound with the molecular
formula C9H10O forms 2,4-DNP derivative,
reduces Tollens’ reagent and undergoes
Cannizzaro reaction. On vigorous oxidation,
it gives 1,2-benzenedicarboxylic acid.
Identify the compound.
105. Give conversion : Ethanol to 3-hydroxy
butanal.
106. State only chemical reactions of preparation
of amine compounds from ethane nitrile
and propenamide.
107. State structures of isomeric amines from
C4H11N and write their IUPAC names.
108. Give conversion : benzyl chloride to 2-
phenyl ethanamine.
109. State benzoylation reaction of primary
amine having 2 carbon atoms.
110. State chemical reactions of primary and
secondary amines with benzene sulphonyl
chlorides.
111. What is diazotization ? State chemical
reaction and state two physical properties of
benzene diazonium chloride.
112. State chemical reactions of prepration of
fluoro benzene and nitro benzene from
benzene diazonium fluoro borate.
113. State reactions of BDC with (i) phosphinic
acid (ii) ethanol.
114. Give conversion : aniline to orange azodye.
115. State chemical equation of reaction of alkyl
and aryl amine with nitrous acid.
116. State chemical equation of aniline with
methyl iodide in excess in presence of
sodium carbonate solution.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024
117. Give reason : Diazonium salts of aromatic
amines are more stable than that of
aliphatic amines.
118. What is Oligosaccherides ? Explain.
119. What is meant by reducing and non-
reducing sugars ? Give an example of each.
120. Explain : chemical reactions of preparation
of glucose.
121. Give 2-2 differences between amylose and
amylopectin.
122. Explain : Glycogen.
123. Explain : Zwitter ion of amino acids.
124. Explain : denaturation of protein.
125. State chemical names of vitamins : B1, B2,
B6 and C.
126. How can you explain the absence of
aldehyde group in pentaacetate of D-
glucose ?
127. Why is sucrose non-reducing sugar ?
128. What is Glycogen ? How is it differed from
starch ?
PART : B
Answer the following questions (3 marks)
1. Explain : Henry’s law and state its uses.
2. Explain : Raoult’s law for non volatile solute
and volatile solvent.
3. What is elevation in boiling point ? Derive
the formula to find molecular mass.
4. What is depression in freezing point ? Derive
the formula to find molecular mass.
5. When 45 g of C2H6O2 is dissolved in 600 g
of water, calculate (a) depression in freezing
point and (b) freezing point of solution.
6. At what temperature, solution containing
18 g glucose in 1 kg water will boil at 1.013
bar pressure ? Kb for water is 0.52 K
kg/mol. Molar mass of glucose is 180 g/mol
7. Calculate mole fraction of ethylene glycol in
solution containing 20 % ethylene glycol by
weight. Molar mass of ethylene glycol is 62
g/mol.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
Page 4 of 9
8. At 350 K temperature, vapour pressure of
pure liquids A and B are 450 and 700 mm
Hg respectively. If total pressure of mixture
is 600 mm Hg, calculate composition of
liquid mixture and composition of
components in gaseous phase.
9. Calculate the mass of a non-volatile solute
(molar mass 40 g/mol) which should be
dissolved in 114 g octane to reduce its
vapour pressure to 80 %.
10. Heptane and octane form an ideal solution.
At 373 K, the vapour pressures of the two
liquids components are 105.2 kPa and 46.8
kPa respectively. What will be the vpaour
pressure of a mixture of 26.0 g of heptane
and 35 g of octane ?
11. Explain : rusting of iron.
12. Calculate cell potential of this non standard
cell : Al | Al3+ (0.02 M)|| Zn2+ (0.03 M) |Zn
13. State conductivity of ultrapure water and
state factors which are dependent for
increase of conductivity of the solution
while dissolving electrolyte.
14. When 5 A of current is passed for 1 hour 20
minutes through CuSO4, how much mass
of Cu (g) at cathode and volume of O2 at
STP at anode would be obtained ? (Atomic
mass of Cu=63.5 u)
15. The electrical resistance of a column of 0.05
M NaOH solution of diameter 1 cm and
length 50 cm is 5.55 x 103 ohm. Calculate
its resistivity, conductivity and molar
conductivity.
16. State Nernst equation for following cell :
Mg | Mg2+ || Cl- |Cl2 | Pt
17. State the anodic-cathodic reactions, cell
potential and the electrolyte used in Lead
storage cell.
18. State two differences between order of
reaction and molecularity.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024 Page 5 of 9

19. The rate of reaction becomes doubled when

30. Explain : enthalpy of atomization of
temperature is increased by 10 K from 298 elements of transition series.
K, calculate Ea. 31. Explain the statement : The properties of
20. For a first order rection, show that time first transition elements are different than
required for 99 % completion is twice the that of heavy transition elements.
time required for the completion of 90 % of
32. Explain : magnetic properties of [Co(NH3)6]3+
reaction. by crystal field theory.
21. Explain the graph for first order reaction
33. State primary valency, secondary valency
and give info obtained from it. and IUPAC name of [Co(en)2(H2O)]Cl2.
22. What is meant by zero order reaction ?34. The magnetic moment of [NiCl4]2- is higher
Derive the integrated rate equation for zero
than that of [Ni(CN)4]2-. Explain.
order reaction : R→ P 35. Which complex is stable: [Fe(en)2Cl2]Cl or
23. Explain the order of complex reactions with
[Fe(H2O)4Cl2]Cl ? State geomatrical isomer
examples . of stable complex compound.]
24. The decomposition of N2O5 in CCl4 at 318
36. Explain : Crystal field theory for tetrahedral
K hs been studied by monitoring the compounds.
concentration of N2O5 in the solution.37. State 3 differences between double salts
Initially the concentration of N2O5 is 2.23
and complex salts.
M and after 184 minutes, it is reduced to
38. Explain : preparation of alcohol from alkene
2.08 M. The reaction takes place accordingby acid catalyzed hydration with
to the equation : mechanism.
2N2O5 (g) → 4 NO2 (g) + O2 (g) 39. Explain : preparation of primary alcohol
Calculate the average rate of this reaction in
from alkene.
terms of hours, minutes and seconds. What
40. Explain : preparation of alcohol from
is the rate of production of NO2 during this
aldehyde, ketone, carboxylic acid and ester
period ? by reduction.
25. What is meant by pseudo first order 41. Explain : preparation of alcohol from
reaction ? explain with examples. carbonyl compounds by Grignard reagent.
26. What is interstitial compounds ? state its
42. The acidity of phenol is higher than alcohol
characteristics. by resonance structures.
27. Give reason : 43. Explain : preparation of ester from alcohol
(i) Transition elements have high and phenol compounds.
enthalpy of atomization. 44. Explain : dehydration of alcohol with
(ii) In aqueous solution, Cr2+ is strong
mechanism.
oxidizing agent than Fe2+. 45. Draw the structure of PCC and write its
(iii) The second ionization enthalpy of Cu
name. Explain oxidation reaction of primary
is greater than that of Zn. alcohols by strong and weak oxidizing
28. Explain : preparation of KMnO4. State ionic
reagents.
equation of chemical reaction between 46. Explain : nitration of phenol. Give reason :
acidic permanganate ion and oxalic acid. the boiling point of o-nitro phenol is less
29. State chemical equation of preparation of than that of p-nitro phenol.
KMnO4 and state its properties. 47. Explain : industrial production of ethanol
and its denaturation.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024 Page 6 of 9

48. Explain: preparation of ether by

dehydration of alcohol and explain its
mechanism.
49. Explain: Williamson synthesis.
50. State chemical reaction of HI with tert.-alkyl
alcohol, anisole and benzyl phenyl ether
and state major products.
51. State electrophilic addition reaction of
anisole.
52. State chemical reactions of following :
(i) Preparation of 1-phenyl ethanol from
alkene.
(ii) Preparation of cyclohexyl methanol
from alkyl halide by SN2 reaction.
(iii) Reaction between sodium ethoxide and
tert-butyl chloride.
53. Write the following reactions :
(i) Preparation of aspirine.
(ii)
(iii) Bromination of phenol.
54. Explain : reactions of -CHO and -CO- with
alcohol.
55. Write chemical reactions : preparation of
primary, secondary and tertiary alcohols by
reaction between Grignard reagent and
aldehyde and ketone.
56. Explain : preparation of alkane
hydrocarbon from aldehyde and ketones.
57. Explain : detection test of aldehyde
compounds.
58. An organic compound with the molecular
formula C9H10O forms 2,4-DNP derivative,
reduces Tollens’ reagent and undergoes
Cannizzaro reaction. On vigorous oxidation,
it gives 1,2-benzenedicarboxylic acid.
Identify the compound.
59. Explain : aldol condensation.
60. (i) Write cannizzarro (disproportion)
reaction of fromaldehyde.
(ii) Complete the reactin :
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
(iii) Write IUPAC name of the product
obtained by heating cyclo hexene with
acidic KMnO4. Write chemical reaction also.
61. An organic compound (A) (molecular
formula C8H16O2) was hydrolysed with
dilute sulphuric acid to give a carboxylic
acid (B). (C) on dehydration gives but-1-ene.
Write equations for the reactins involved.
62. Explain : Preparation of carboxylic acid
from alkyl benzene.
63. Explain: preparation of ketone from acyl
halide and nitrile compounds.
64. Explain : Gabriel phthalimide synthesis.
65. Explain : Hoffmann degradation reaction of
benzamide and ethanamide.
66. Compare basicity of alkanamine and
ammonia.
67. Explain : nitration of primary aromatic
amine.
68. State isomers of molecular formula C3H9N.
State the IUPAC names of isomers which
produces nitrogen gas while reacting with
nitrous acid.
69. Explain : coupling reactions occurring in
acidic and basic medium.
70. State the structures and IUPAC names of
A, B and C :
71. State the structures and IUPAC names of
A, B and C :
72. Explain : sandmayer and Gatterman
reaction.
73. Explain : Acylation of amine compounds.
74. Write the chemical reactions of glucose with
(i) Hydrogen cyanide, (ii) Hydroxyl amine
and (iii) Acetic anhydride. These reactions
represents presence of what in glucose ?
75. Explain : sucrose.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024
76. Explain : classification of amino acid.
77. State differneces between Fibrous protein
and Globular protein.
78. Explain : secondary structure of protein.
79. Explain : chemical composition of nucleic
acid.
80. Explain : work function of hormones.
Que. Answer the following questions : (4
marks)
1. Explain : Raoult’s law for volatile solute
and volatile solvent.
2. If N2 gas is bubbled through water at 293
K, how many milimoles of N2 gas would
dissolve in 1 L of water ? Assume that N2
exerts a partial pressure of 0.987 bar.
Given that Henery’s law constant for N2 at
293 K is 76.48 kbar.
3. Vapour pressure of CHCl3 and CH2Cl2 at
298 K are 200 mm Hg and 415 mm Hg
respectively. (i) Calculate the vapour
pressure of the solution prepared by
mixing 25.5 g of CHCl3 and 40 g of CH2Cl2
at 298 K and (ii) mole fractions of each
component in vapour phase.
4. 2 g of benzoic acid (C6H5COOH) dissolved
in 25 g of benzene shows a depression in
freezing point equal to 1.62 K. Molal
depression constant for benzene is 4.9 K
kg/mol. What is the percentage
association of acid if it forms dimer in
solution ?
5. 0.6 mL of acetic acid (CH3COOH) having
density 1.06 g/mL, is dissolved in 1 L of
water. The depression in freezing point
observed for this strength of acid was
0.0205oC. Calculate the van’t Hoff factor
and the dissociation constant of acid.
6. How many mL of 0.1 M HCl are required
to react completely with 1 g mixture of
Na2CO3 and NaHCO3 containing
equimolar amounts of both ?
7. A solution containing 30 g of non-volatile
solute exactly in 90 g of water has a
vapour pressure of 2.8 kPa at 298 K.
Further, 18 g of water is then added to the
solution and the new vapour pressure
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
Page 7 of 9
becomes 2.9 kPa at 298 K. Calculate : (i)
molar mass of the solute. (ii) vapour
pressure of water at 298 K.
8. Two elements A and B form compounds
having formula AB2 and AB4. When
dissolved in 20 g of benzene (C6H6). 1g of
AB2 lowers the freezing point by 2.3 K
whereas 1.0 g of AB4 lowers it by 1.3 K.
The molar depression constant for
benzene is 5.1 K kg/mol. Calculate atomic
masses of A and B.
9. 19.5 g of CH2FCOOH is dissolved in 500 g
of water. The depression in the freezing
point of water observed is 1.0oC. Calculate
the van’t Hoff factor and dissociation
constant of fluoroacetic acid. Kf=1.86 K
kg/mol.
10. Calculate the depression in the freezing
point of water when 10 g of
CH3CH2CHClCOOH is added to 250 g of
water. Ka = 1.4 x 10-3, Kf=1.86 K kg/mol.
11. For Deniell cell, (1) Ecell < 1.1 V (2) Ecell
> 1.1 V, state the direction of flow of
electron. For which value of Ecell, the
electrochemical cell will be in equilibrium
?
12. (1) State the laws of Faraday for
electrolysis. (2) What is specific
conductance ? Depict its unit.
13. State Kohlrausch’s law for strong
electrolyte. The values of om of NaCl,
HCl and NaAc are 126.4, 425.9 and 91 S
cm2 mol-1, then Calculate om for HAc.
14. Calculate the required amount of
electricity in coloumb for conversion of
−
Cr3+ from 2.5 mol of Cr2O72 and Mn2+
from 2.5 mol MnO −. 4
15. Two electrolytic cells A and B contain
AgNO3 and CuSO4 solutions, which are
connected in series. If 1.45 g of Ag is
formed by passing steady current of 1.5 A
for how much time ? What mass of Cu will
be obtained ? cell efficiency is 75 %.
16. Pt|Br2|Br−(0.01M)||H+(0.03 M)|H2|Pt.
Calculate Ecell. EBr
O
/ Br −
= 1.09V
2
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024 Page 8 of 9

17. Explain the effect of change in temperature (e) In which compound, transition
on rate of reaction and rate constant of element has low (zero) oxidation states ?
reaction. why ?
18. The rate constant for reaction at 500 K
and 700 K temperature are 0.02 s-1 and 25. Explain : metal oxides of 3d series.
26. Explain : atomic volume and ionic volume
0.01 s-1, calculate Ea and A. of lanthanoids.
19. C2H5I (g) → C2H4(g) + HI (g). For given 27. State Eo values of lanthanoids and state
reaction, rate constant is 1.6 x 10-5 s-1. reactions of lanthanoids with following :
It’s energy of activation is 209 kJ/mol. (i) H2 (ii) carbon (iii) dilute acid (iv)
Calculate rate constant at 700 K halogen (v) O2 (vi) H2O.
temperature.
20. During nuclear explosion, one of the 28. Compare actinoids and lanthanoids with
products is Sr90 with half life of 28.1 years. respect to following terms :
If 1 g of Sr90 was absorbed in the bones (i) appearance (ii) structure
of a newly born baby instead of calcium, (iii) magnetic properties
how much of it will remain after 10 years
and 60 years if it is not lost metabolically. (iv) ionization enthalpy
21. For a first order reaction, show that time
required for 99 % completion is twice the (v) lanthanoid contration.
time required for the completionof 90 % of
29. State the conclusion of following magnetic
reaction.
moment for respective complex
22. The time required for 10% completion of a
compounds :
first order reaction at 298 K is equal to
that required for its 25 % completion at Complex Magnetic moment
308 K. If the value of A is 4 x 1010 s-1.
Calculate K at 318 K and Ea. K4[Mn(CN)6] 2.2
23. Explain : lanthanide contraction and its
consequences. [Fe(H2O)6]2+ 5.3
24. (a) Transition metals have various
oxidation states in their compounds.- K2[MnCl4] 5.9
Explain the
statements with suitable examples.
(b) The middle elements of transition 30. State no. of electrons present in following
series show more no. of oxidation ions : Ti2+, V2+, Cr3+, Mn2+, Fe2+, Fe3+, Co2+,
Ni2+ and Cu2+. In given hydrated ions, how
states,where
five 3d orbitals will be filled ? expain.
side elements show less no. of 31. Compare actinoids with lanthanoids with
oxidation states.- Explain with suitable respect to following terms.
examples. (a) electronic configuration (b)
atomic and ionic volume
(c) State most stable oxidation states
of elements of first transition series. (c) oxidation state (d)
chemical reactivity.
(d) Explain : conversion of oxidation
states of transition elements. 32. Explain : postulates of Werner’s theory.
33. (a) [Ti(H2O)6]3+ is coloured compound,
state the effect on colour of substance on
heating.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.
BHAGYESH LIMBACHIYA BOARD QUESTION BANK-2024 Page 9 of 9

(b) State IUPAC name : 53. What is vitamin ? State names, source
and diseases occurred with their
(NH4)2[Cr(OH)3] deficiency of vitamin.
54. Which reactions of glucose cannot be
34. [Fe(CN)6]3- is weak paramagnetic, where explained by linear structure ? explain
[Fe(CN)6]4- is diamagnetic – Explain. cyclic structure of glucose.
35. Which type of isomerism is seen in
[Fe(H2O)4(NO2)2]Cl ? Draw its isomers.
36. State any four applications of co-
ordination compounds.
37. State only chemical equations of
preparation of alcohol from alkene by acid
catalyzed hydration and by hydroboration
oxidation.
38. Explain : prepration of phenol.
39. Explain : physical properties of phenol.
40. Explain : oxidation of alcohol.
41. Give conversion :
(i) phenol → o-hydroxy benzaldehyde
(ii) phenol → acetyl salicylic acid.
42. Explain : chemical reactions of ether.
43. Give conversion : (in two steps)
(i) Acetic acid → ethanol
(ii) Ethanol → bromo ethane.
44. Explain : chemical reacitons of aldehyde
compounds with derivatives of ammonia.
45. Explain : Cross aldol condensation.
46. Explain : reduction of –CHO AND –CO-.
47. Explain : oxidation of ketone.
48. Explain : prepration of derivatives of
carboxylic acids.
49. Give organic conversion :
(i)benzyl alcohol → phenyl acetic acid.
(ii) benzene → methyl benzoate.
50. An organic compound contains 69.77 %
carbon, 11.63% hydrogen and rest
oxygen. The molecular mass of the
compound is 86. It does not reduce
Tollens’ reagent but forms an addition
compound with sodium hydrogen sulphite
and give positive iodoform test. On
vigorous oxidation it gives ethanoic and
propanoic aicd. Write the possible
structure of the compound.
51. Give conversion : 4-nitro toluene → 2-
bromo benzoic acid.
52. State chemical equations of preparation of
halobenzene from BDC.
SAI INSTITUTE OF CHEMISTRY, BHAGYESH LIMBACHIYA. (M.Sc. B.Ed.) (M : 9824340952)
U-13, VASUKANAN COMPLEX, NEAR NIRNAYNAGAR UNDERBRIDGE, CHANDLODIYA
ROAD,AHMEDABAD-382481.