VIJAYAM JUNIOR COLLEGE : : CHITTOOR

SUB : CHEMISTRY TERMINAL EXAM DATE :04.08.18 Marks:60

I Answer all of the following questions 10x2=20
1) State Henry’s law?

2) Calculate the mole fraction of H2So4 in a solution containing 98% H2So4 by mass?

3) What is an ideal solution? Give an example.

4) What is conductivity of a material? Give its SI units?

5) State Faraday’s second law of Electrolysis?

6) Give the products obtained at the platinum electrodes when aqueous solution of K 2So4 is electroysed ?

7) How is Gibbs energy(G) related to the cell emf(E) mathematically?

8) Define the speed (or) rate of a reaction? What are the units of rate of a reaction.

9) Give the units of rate constants for zero, first and second order reactions ?

10) A reaction has a half-life of 10 minutes. Calculate the rate constant for the first order reaction.

II Answer any six of the following 6x4=24

11) State and explain Raoult’s law?

12) Define molarity? Calculate the molarity of a solution containing 5g of NaOH in 450ml solution?

13) What is osmotic pressure? Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K 2So4 in
two litre of water at 25oc assuming that it is completely dissociated?

14) What is Electrolysis? Give Faraday’s first law of electrolysis?

15) What are fuel cells? How are they different from Galvanic cells? Give the construction of H 2-O2 fuel cell?

16) State and explain Nernst equation with the help of a metallic electrode and a non-metallic Electrode.

17)What is half-life of a reaction? Derive the equations for the half-life value of zero and first order reactions?

18) What is molecularity of a reaction? How is it different from the order of a reaction?

SECTION-C

III Answer any five of the following 2x8=16

19) a. What is Elevation of boiling point of a solution? How is molar mass related to the elevation in boiling poing of a
solution?

b. What are Non-ideal solutions? Explain their deviations from Raoult’s law?

20) a. What are Galvanic cells? Explain the working of a Galvanic cell with a neat sketch taking Daniell cell

as example.

b. State and Explain Kohlrausch’s law of independent migration of ions?

21)a. Define and Explain the order of a reaction. How is it obtained Experimentally?

b. Discuss the effect of catalyst on the Kinetics of a chemical reaction with a suitable diagram.