CHM1102 Worksheet 6 2021

1. The vapor pressure of pure hexane and pentane at 25°C are 149.1 mmHg and 508.5
mmHg, respectively. If a hexane pentane solution has a mole fraction of hexane of 0.750,
what are the vapor pressures of hexane and pentane above the solution? What is the total
vapor pressure?
2. A benzene toluene solution with Xben = 0.300 has a normal boiling point of 98.6°C.
The pure vapor pressure of pure toluene at 98.6 °C is 533 mmHg. What must be the
vapor pressure of pure benzene at 98.6 °C? (Assume ideal solution behaviour)

3. Assuming ideal solution behaviour, what is the freezing point of a solution of 9.04 g of I 2
in 75.5 g of benzene? Freezing point of benzene is 5.5°C and Kf = 5.12 °C kg/mol 4.

4. Assuming ideal solution behaviour, what is the freezing temperature of a solution of

115.0 g of sucrose, C12H22O11, in 350.0 g of water? Freezing point of water is 0°C and Kf
=1.853 K·kg/mol
5. Assuming ideal solution behaviour, what is the boiling point of a solution of 115.0 g of
non-volatile sucrose, C12H22O11, in 350.0 g of water? Boiling point of water is 100°C and
Kb = 0.51 °C kg/mol.
6. Assuming ideal solution behavior, what is the osmotic pressure (atm) a solution with a
volume of 0.750 L that contains 5.0 g of methanol, CH3OH, in water at 37 °C?

7. The edge length of the unit cell of alpha polonium is 336 pm.
(a) Determine the radius of a polonium atom.
(b) Determine the density of alpha polonium.

8. Classify the following systems as open, closed or isolated

a. A stoppered plastic bottle containing water
b. The human body
c. A closed thermos flask with hot tea
d. The Universe
9. When 20 g of a fuel is burnt, the heat released raises the temperature of 200 g of water by
5 0C, what is the enthalpy of combustion of the fuel in kJ/g? (cwater = 4.184 Jg-1K-1)

10. Calculate the enthalpy of solution of sodium hydroxide if 5 g produces a temperature

increase of 12.5 0C in a 100 cm3sample of water. (cwater = 4.184 /Jg0C; ℓwater = 1.00 g/cm3)

11. Find the ΔH for the reaction below, given the following reactions and
subsequent ΔH values:
PCl5(g) → PCl3(g) + Cl2(g)

1) P4(s) + 6Cl2(g) → 4PCl3(g) ΔH = -2439 kJ

2) 4PCl5(g) → P4(s) + 10Cl 2(g) ΔH = 3438 kJ

12. Find the ΔH for the reaction below, given the following data
2CO2(g) + H2O(g) → C2H2(g) + 5/2O2(g)

1)…..C2H2(g) + 2H2(g) → C2H6(g) ΔH =-94.5 kJ

2)…..H2O(g) → H2(g) + 1/2O2 (g) ΔH =71.2 kJ
3)…...C2H6(g) + 7/2O2(g) → 2CO2(g) + 3H2O(g) ΔH =-283 kJ

13. Write an expression for the ΔH of the reaction below, given the following
data: N2H4(l) + H2(g) → 2NH3(g) ΔH = x kJ

Data

N2H4(l) + CH4O(l) → CH2O(g) + N2(g) + 3H2 (g) ΔH = a kJ

N2(g) + 3H2(g) → 2NH 3(g) ΔH = b kJ CH4O(l) → CH2O(g) + H 2(g) ΔH = c
kJ