Self-Assessment Quiz QL. Achemical system produces 185 WJ of heat and does 22 8} ‘of work, Whats AF for the suraundings? QT b)-W7K g) 133K) a) 1338) 2, Which samples most lke to undergo the smallest ‘change in temperature upon the absorption of 100 Kj of heat? a) 1S gwater by 1Sglead ©) Sogwater 4) sO gtead 93, How much heat must be absorbed by a 18.0.gsample of ‘water to alse ls temperature from 28.0°Cta 8.0°C? or water,C, = 4.18)/8°C) a) 17K) 185K) 345K a) 107) 92, 4125-g sample of granite initially at 2.0°C is immersed into 25.0 g of water initially a 2.0°C, Whatis the inal temperature of bath substances when they seach thermal ‘equilibrium? (For water, = 4.18}/g"Cand for granite, = 0790) /8°C) 8) 520°C by 185 x 10% 9 187°C 272°C 5. Acylinder with a moving piston expands from an initial ‘volume of 0.250 L against an external pressure of 2.00 at. ‘The expansion does 288 j of work on the sucroundings.. What isthe final volame of the cjlinder? 8) 142L W)LITL MAL) 1671 6. When 43.804 sample of liquid octane (C4H,.)is bumed in bomb calorimeter, the temperature ofthe calorimeter rises bby27.3°C. The heat capacity ofthe calorimeter, measured ina separate experiment, Is6.18/°C. Determine the AE for octane combustion in units of kj/mol octane. 3) 8.07 » 10°KI/mot by 8.07 x 107k} mot ©) #44 x 10°kj/mol 1d) “16.7 10kI/mol 7. Hydrogen gas eacts with oxygen to form wate: 2X9) + OXs) — 21,019) AH = ~48351) Determine the minimum mass of hydrogen gas esquize to produce 220 kj of heat. 3) 863g b) 188g 0) 0.982g a) 0.935g 8. Manganese reacts with hydrochloric acid to produce ‘manganese(l) chloride and hydeogen gas Man(s) + 2HCKiag) — Maclay) + Hs) ‘When 0.625 g Mn i combined with enough hydrochloric cid to make 100.0 ml. of solution in acoffe-cup calorim- ‘te, al of the Ma react, raising the temperature of the so lution ftom 23.5°C to 28.8°C. Find AF forthe reaction as written (Assume thatthe specific heat capacity ofthe solution i418 ]/g°Cand the density is 1.00 g/ml.) b) 358) ) 220) (@10, Use standard enthalpiesof formation to determine AH, SeltAssessment Quiz 285 98. Consider the eactions: A—20 aK A—3C Ath ‘Whats A#fforthereaction 2B —> 3? a) Ath + Sth ) AM ~ AH © Aih— aH a) 2x (aH = SH) forthe reaction: Fe,0y.) + 3CO(g) — 2Fe(s) + 3 COM) a -4128) 9 se b) 23364) ) 248K) QA. ‘wo substances, A and By of equal mass butat diffrent temperatures come into theemal contact. The specific heat capacity of substance Ais twice the specific heat ‘capacity of substance B, Which statementis truco the temperature ofthe two substances when they reach thermal equilibrium? (Assume no heat foss other than the thermal transfer between the substances.) 4) The final temperature ofboth substances is closer to the initial temperature of substance Athan the inital {temperature of substance B. 1) The inal temperature ofboth substances is closer to the initial temperature of substance B than the intial temperature of substance A, (©) Thetinal temperature ofboth substances is exactly ‘midway between the initial temperatures of substance and substance B. 4) The final temperature of substance B s greater than the final temperature of substance A. 12. Which process s endothermic? 4) the evapozaton of water from the skin 1) the burning of candle wax ©) the oxidation of iron ina chemical hand warmer 4) the combustion of natural gas in a stove (@13. Which fuel ismota fossil fue? 2) coal ) hydrogen ©) natural gas 4) potcoleum (Q14. The standard enthalpy of formation for glucose [CgHaO4(o] 1273.3 9j/mol. Whats the corzect formation equation corresponding to this AH? 4) 64s graphite) + 6 HOC) —> CoH 2O4(, glucose) 1) 6Cls, graphite) + 6 HOU) —> CaHy204s, glucose) ©) GCIs, graphite) + 6HAD + 30,1) —> GH Oa, cose) caphite) + 6HG{s) + 3019) — CaH2Oal, glucose) &) 60%, {@45._ Natural gas bucnsinairto form carbon dioxide and water, releasing heat. CHA) + 0x19) — COA) = HO1s) Ming = 802.3 K} ‘What minimum mass of CH is sequized to heat 58 got ‘water by 25°C? (Assume 10096 heating efficiency.) a) OulIS by 225 x 10, 9 Sg @ 870g OSE OL OEE OZ OL MOL O6 OR WL (9 1's PF] OZ (T SIMsUY