!

~ Rea d the given pas sag e and ans wer the

questions
/ tha t follow:
Sol uti on play a very imp ort ant role in our daily
life.
Alloys, hon1ogeneous mix tur e of metal are solution
of solid in solid. 1 ppm (parts per million) of fluorid
e
ions pre ven t tooth decay. All intravenous injection
s
mu st be iso ton ic wit h our bod y fluids, i.e. sho
uld
hav e sam e con cen tra tion as blo od pla sm a. Dia bet
ic
pat ien ts are mo re like ly to hav e hea rt att ack
and
high blo od pre ssu re due to hig her glu cos e lev
el in
blo od.
Co mm on s_a lt inc rea ses blo od pre ssu re bec
aus e
Na+ mix es up wit h blo od. Aq uat ic spe cie s are mo
re
com for tab le in col d wa ter tha n wa rm water.
In the se que stio ns, a sta tem ent of ass ert ion fol low
ed
by a sta tem ent of rea son is giv en. Ch oos e the cor rec
t
ans we r out of the fol low ing cho ice s.
(a) Assertion and reason both are correct statem
ents
and reason is correct explanation for assertion.
(b) Assertion and reason both are correct statement
s
but reason is not correct explanation for assertion.
(c) Assertion is correct statement but reason is wro
ng
statement.
(d) As ser tion is wrong statement but reason is correc
t
statement.
(1) Assertion: 0.1 M glu cos e is not iso ton ic wit
h
0.1 M KC l solution.
Reason: Th ey do not hav e sam e osmotic pre ssu re
due to dif fer ent num ber of particles.
(i,) As ser tio n: If blo od ce lls are pla ce d
in sa lin e
wa ter, it wi ll shr ink .
Reason: Sa lin e wa ter is on sol uti on sid e hy pe rto nic
sol uti on , the ref ore , cel l flu id wi ll co me ou t.
(iii) Assertion: If pressure applied on solution side is
equal to 'n' ( osmotic pressure), osmosis will stop.
Reason: If applied pressure on solution side is
greater than '1t ', then reverse osmosis will take
place.
(a) E xplain whv a solution of chloroform and
""
acetone shows negative deviation from Raoult's
law.
(b) Phenol ass·o ciates in benzene to certain extent
t o form a dimer. A solution containing 20 g of
phenol in 1.0 kg of benzene has its freezing
point low.e red by 0.69 K. Calculate the fraction
o f phenol that has dimerised.
IGiv en Kf for benzene= 5.1 Km~1] (HOTS)
 Compound 'A' with molecular formula C 4 H9Br is treated with aq. KOH solution. The rate of this reaction depends
upon the concentration of the compound 'A' only. When another optically active isomer 'B' of this compound was
treated with aq. KOH solution, the rate of reaction was found to be dependent on concentration of compound
and KOH both.
(z) Write down the structural formula of both compounds 'A' and 'B'.
(u) Out of these two compounds, which one will be converted to the product with inverted configuration.