ASSERTION

& CORNER
a statement of
REASON Directions: In thefollowing questions,
as :
assertion is followed
reason.Mark the correct choice
reason are true andreason is the correct explanation of
(a) If both assertion and
true but reason is not the correct explanation of as erion
(b) If both assertion and reason are
(c) If assertion is true but
reason is false.
(d) If both assertion and reason are
false.
as erion
Assertion: Amalgam of mercury with sodium is an 9. Assertion : Asolution of
show negative deviations phenol and aniline
Reason :In case of negativefrom
example of solid solutions.
Reason : Mercury is solvent and sodium is solute in Raoul's)slaw.
the solution. law, A- Bforces are stronger
forces.
dethan
viations -Afrom
A
A
2. Assertion : The concentration of pollutants in water
10. Assertion : The solutions which
andB-
or atmosphere is often expressed interms of ppm.
Reason : Concentration in parts per million can be
expressed as mass to mass, volume to volume and
deviations from Raoult's law
azeotropes. formshowmaxim\arumge bolpositet,
mass to volume. Reason : 95% aqueous solution
3. Assertion : One molar aqueous solution is more
maximum boiling azeotrope. ethanol
concentrated than that of 1 molal aqueous solution. 11. Assertion : The vapour
pressure of
solution of sucrose is less than l.013 an
Reason : Molarity is a function of temperature as bar at aqueos
volume depends on temperature. Reason : Vapour pressure of water is 1.013373.bar3K.
373.15 K.
4. Assertion : Pressure does not have any effect on
solubility of solids in liquids. 12. Assertion : Lowering of vapour
Reason :Solids and liquids are highly incompressible. pressure is ng
dependent on the number of species presentin te
solution.
5. Assertion : Aquatic species are more comfortable in
warm waters than cold waters. Reason: Lowering of vapour presure and
Reason : Kå values for both N, and O, decrease relative lowering of vapour pressure are colligatie
with increase of temperature. properties.
13. Assertion : Osmosis does not take place in tw
Assertion : At equilibrium, vapour phase will be
always rich in component which is more volatile. isotonic solutions separated by semipermeahe
Reason: The composition of vapour phase in membrane.
Reason: Isotonic solutions have same osmoti
equilibrium with the solution is determined by the
partial pressures of the components. pressure.
7 Assertion: Decrease in the vapour pressure of water 14. Assertion : 1 Msolution of KCl has greater osmoa
by adding 1 mol of sucrose to one kg of water is pressure than 1M solution of glucose at the Saik
higher to that produced by adding Imol of urea to temperature. Produ:
the same quantity of water at the same Reason: In solution KCI dissociates to
temperature.
Reason : Molecular mass of sugar is less more number of particles.
than that onthe
of urea. 15. Assertion : Molecular mass of KClcalculated
thanthe
8 Assertion: In an ideal solution, A,mHis zero. basis of colligative Properties will belower
Reason : In an ideal solution, A - B interactions are normal molecular mass. massb
Reason : Experimentally determined molar
lower than A- Aand B- Binteractions.
always lower than the true value.
 the following units is useful in relating
of
oNLentrationofsolution with its vapour pressure?
Which
(a) Methanol and acetone
a)Moletraction (b) Parts per million b) Chloroform and acetone
Masspercentage (d) Molality (c) Nitric acid and water
(d) Phenol and aniline
dissolvingsugarin water at room temperature
touch. Under which of the 8. Colligative
sabtion feels cool to
(a)
properties depend on
the nature of the solute particles dissolved in
following
cases dissolution of sugar will be most
rqpid?
solution
crystals in cold water (b) the number of solute particles in
Sugar solution
Sugarcrystalsin cold water
hot water (c) the physical properties of the solute particles
Powdered sugar in dissolved in solution
d)
PowderedIsugarin hot water (d) the nature of solvent
particles
equilibrium the rate of dissolution of a solid 9. Which of the following aqueous solutions should
At solvent is
soluteina volatileliquid have the highest boiling point?
a less than the rate of crystallisation (a) 1.0MNaOH (b) 1.0 M
(0) greater than the rate of crystallisation (c) 1.0 MNH,NO, (d) 1.0 MNa,SO, KNO,
I) equal to the rate of crystallisation 10. The unit of ebulioscopic
(d) zero constant is
(a) Kkg mol' or K(molality)
beaker contains a solution of substance A:
(b) mol kg K' or K'(molality)
Predpitation of substance ´¤' takes place when small (c) kg molr K'or K'(molality)
amount of 'A' is added to the solution. The solution (d) Kmol kg or K(molality)
1S
(e) saturated (b) supersaturated 11. In comparison to a 0.01 M solution of glucose, the
(c) unsaturated (d) concentrated depression in freezing point of a 0.01 M MgCl,
solution is
Maximum amount of a solid solute that can be
(a) the same (b) about twice
disoved in a specified amount of a given liquid (c) about three times (d) about six times.
slvent does not depend upon
a) temperature (b) nature of solute 12. An unripe mango placed in a concentrated
(c) pressure (d) nature of solvent salt solution to prepare pickle, shrivels because
Concentration of Oxygen in the blood and
tissues of people living at high altitude is due to (a) it gains water due to osmosis
(b) it loses water due to reverse osmosis
) low temperature (c) it gains water due to reverse osmosis
B) low (d) it loses water due to osmosis
9 high atm ospheric pressure
0) atm ospheric pressureand high atmospheric
both low temperature 13. At a given temperature, osmotic pressure of a
concentrated solution of a substance
pressure (a) is higher than that at a dilute solution
áCahnysdidroerginegn thebond,formation, breaking and strength (b) is lower than that of a dilute solution
(c) is same as that of a dilute solution
Ttures wil showpredict which
of the
a positive deviationfollowing
from (d) cannot be compared with osmotic pressure of
Raout'slaw? dilute solution
 40
statements is false? (a) Water will move
14. Which of the following same pressure lower than side from
different solutions of sucrose of
(a) Two
molality prepared in different solvents
willhave on piston (B). osmotic
the same depression in freezing point.
(b) The osmotic pressure of a
theequation
solution is given by
= CRT (where Cis themolarity
of the solution).
pressure for
(b) Water will move from

(c)
a pressure greater
than
applied on piston (B).
Water will move from
pressure equal to
pres ureSa.
side (B)
OSmotic
side (B) to side
(c) Decreasing order of osmotic
0.01 M aqueous solutions of
barium chloride,
is
on piston (B). Osmotic pressure
potassium chloride, acetic acid and sucrose (d) Water will move fromn
side (A)
BaCl, > KCI > CH,COOH > sucrose.
(d) According to Raoult's law, the vapour pressure
pressure equal to
on piston (A). osmotic to side lB
pressure
exerted by a volatile component of a solution is 20. We have three aqueous
directly proportional to its mole fraction in
the solutions. of
solution.
'AB'and 'C with
concentrations NaCll
0.001 M, respectively. The value of
15. The values of van't Hoff factors for KCI, NaCl and for these solutions willbe in the ordervant Hof fac
K,SO, respectively, are (a) i, <ig <ic (b) ia>is> ic
(a) 2, 2 and 2 (b) 2, 2 and 3
(c) 1, 1and 2 (d) 1,1and 1
(d) i<i_> iç
On the basis of
16. Which of the following statements is false?
21.
correct option.
information given below martk t:
(a) Units of atmospheric pressure and osmotic
Information:
pressure are the same.
() In bromoethane and
(b) In reverse osmosis, solvent molecules move chloroethane
intermolecular interactions of A-A and A.:
miutur.
through a semipermeable membrane from
a region of lower concentration of solute to a type are nearly same as A-B type interactions
(I) In ethanol and acetone mixture A-A or R
region of higher concentration.
(c) The value of molal depression constant depends type intermolecular interactions are stronge
on nature of solvent. than A-B type interactions.
(d) Relative lowering of vapour pressure, is a (III) Inchloroform and acetone mixture A-A or B
dimensionless quantity. type intermolecular interactions are weake
17. Value of Henry's constant Ky. than A-B type interactions.
(a) Solution (II) and (III) will follow Raout's la
(a) increases with increase in temperature
(b) decreases with increase in temperature (b) Solution (1) will follow Raoult's law.
(c) remnains constant (c) Solution (II) will show negative deviation tr
Raoult's law.
(d) first increases then decreases
(d) Solution (II) will show positive deviation tr
18. The value of Henry's constant Ky is Raoult's law.
(a) greater for gases with higher solubility taken. (n
(b) greater for gases with lower solubility 22.. Two beakers of capacity 500 mL were filledwt
was
(c) constant for all gases of these beakers, labelled as "A labelled 'N
(d) not related to the solubility of gases 400 mL water whereas the beaker NaC.Atk
of
19. Consider the figure and mark the correct option. filled with 400 mL of 2 Msolution plad
both the beakers were sat
Piston (4) same termperature material and
Piston (B)
SPM in closed containers of same
capacity as shown in figure.

Concentrated
Fresh water sodium chloride
(4) solution in
water
NaCl solution
Water
 Solutions

temperature, which of the following 25. On the basis of information given below mark the
given
correct about the vapour pressure of correct option.
Ala is
stateiments
solution.
andthat of) NaCl Information :
water
pure pressurein container (A) is more than On adding acetone to methanol some of the
Vapour
(a) container(B). hydrogen bonds between methanol molecules break.
thatin pressure in container (A) is less than (a) At specific composition methanol-acetone
Vapour
container(B), mixture will form minimum boiling azeotrope
the. containers.
thatin pressureis equal in both the and will show positive deviation from Raoult's
Vapour container (B) is twice the law.
c pressure in
Vapour (b) At specific composition methanol-a
pressure in container (A).
vapour mixture forms maximum boiling azeotrope
B form minimum boiling will show positive deviation fro
liquids A and and
two at some specific composition then
azeotrope Raoult's law.
(c) At specific composition methanol- acetone
those azeotrope
mixture will form minimum boiling
interactions are stronger than from
(a) A-B
betweenA-Aor B-B and will show negative deviation
because Raoult's law.
pressure of solution increases methanol-acete
vapour andB (d) At specific composition
(b) number of molecules of liquids A
more mixture will form maximum
boiling azeo
the solution deviation from
can escape from
because trope and will show negative
pressure of solution decreases Raoult's law.
(c) vapour molecules of only one of the
less number of
26. Ky values for Arig» CO21gy
HCHO and CH4)
from the solution respectively.
liquids escape those are 40.39, 1.67, 1.83 x10 and 0.413
interactions are weaker than their increasing
(d) A-B Arrange these gases in the order of
between A-A or B-B
solubility.
aqueous solution of NaClwas diluted (a) HCHO <CH, CH, <Ar
< CO,< Ar
4 4L of 0.02M The molality of the
litre of water. (b) HCHO < CO, < HCHO
by adding one CH, <
(c) Ar< CO,<
resultant solution is CO, <HCHO
(a) 0.004
(b) 0.008 (d) Ar< CH, <
(d) 0.016
(c) 0.012