FALCON GROUP OF INSTITUTIONS

QUEENS ROAD
BANGALORE
NEET/JEE/KCET
Date : 28/11/2022 TEST ID: 6211
Time : CHEMISTRY
Marks : 36
8.REDOX REACTIONS

Single Correct Answer Type This section contain(s) 1 question(s) numbered 20

11. Of the following reactions, only one is a redox to 20. Each question contains STATEMENT
reaction. Identify this reaction. 1(Assertion) and STATEMENT 2(Reason). Each
a) Ca (OH )2 +2 HCl ⟶ CaCl2+ 2 H 2 O question has the 4 choices (a), (b), (c) and (d) out
b) 2 S 2 O 7
2−¿+4 H +¿ ¿ ¿
2−¿+2 H 2 O ⟶ 2 SO4 ¿ of which ONLY ONE is correct.
a) Statement 1 is True, Statement 2 is True;
c) BaCl2 + MgSO4 ⟶ BaSO 4 + MgCl 2
Statement 2 is correct explanation for Statement
d) Cu 2 S+2 FeO ⟶ 2 Cu+ 2 Fe+ SO 2 1
12. What is the oxidation state of P in b) Statement 1 is True, Statement 2 is True;
Ba ( H 2 PO2 )2 ? Statement 2 is not correct explanation for
a) +1 b) +2 c) +3 d) −1 Statement 1
13. Oxidation number of ‘N’ in N 3 H (hydrazoic c) Statement 1 is True, Statement 2 is False
acid) is d) Statement 1 is False, Statement 2 is True
a) −1 b) c) d) 20
+3 0 −3
3 Statement 1: Nitrous acid may acts as an
14. The number of moles of KMnO 4 reduced by oxidizing agent as well as
one mole of KI in alkaline medium is reducing agnet.
a) 1 b) 5 c) ½ d) 1/5 Statement 2: The oxidation number of
15. What is the oxidation number of chlorine in nitrogen remains same in all
ClO−¿ ¿
3 ? the compounds.
a) +5 b) +3 c) +4 d) +2
16. Oxidation state of chromium

a) +10 b) +6 c) +3 d) +2
17. The oxidation number of Xe in XeF 4 and
XeO 2 is
a) +6 b) +4 c) +1 d) +3
18. Oxidation number of S in SO 2−¿ ¿
4
a) +6 b) +3 c) +2 d) −2
19. When K 2 Cr2 O 7 is converted into K 2 CrO 4 ,
the change in oxidation number of chromium
is
a) 0 b) 5 c) 7 d) 9

Assertion - Reasoning Type

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 FALCON GROUP OF INSTITUTIONS
QUEENS ROAD
BANGALORE
NEET/JEE/KCET
Date : 28/11/2022 TEST ID: 6211
Time : CHEMISTRY
Marks : 36
8.REDOX REACTIONS

: ANSWER KEY :

11) d 12) a
13) a 14) a 15) a 16) b
17) b 18) a 19) a 20) c

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 FALCON GROUP OF INSTITUTIONS
QUEENS ROAD
BANGALORE
NEET/JEE/KCET
Date : 28/11/2022 TEST ID: 6211
Time : CHEMISTRY
Marks : 36
8.REDOX REACTIONS

: HINTS AND SOLUTIONS :

Single Correct Answer Type = 1
11 (d) Hence, moles of KI = moles of KMnO 4 .
Oxidation
15 (a)
−¿ .¿
Oxidation number of Cl in ClO 3
+1 -2 +2 0 0 +4
Cu2S + 2FeO 2Cu + 2Fe +SO2 Cl O3=−¿1
x +3 (−2 )=−1
Reduction x=+6−1
Reduction x=+5
In this reaction Cu and Fe undergo reduction
16 (b)
while sulphur undergoes oxidation. Hence, this is
a redox reaction.

12 (a)
Let oxidation state of P in Ba ( H 2 PO 2 ) 2 is x , then
2 (+ 1 )+ 2 [ 2 ( +1 ) + x+ 2 (−2 ) ]=0 It is chromium peroxide.
2+2 ( 2+ x−4 )=0 Let the oxidation number of Cr is ' ' x '' .
2+ 4+2 x−8=0
−¿ − CrO ¿
5
2− ¿ +O ¿
−¿+O 2
¿
x+ ¿+O 2 ¿
Cr
2+2 x−4=0
x + (−1 ) 2+ (−1 ) 2+ (−2 ) 1=0
2 x=2
x−6=0
x=+1
x=+6
13 (a) Hence, the oxidation state of Cr is +6.
N 3 H ( hydrazoic acid )
17 (b)
+3 ( x )+ 1=0 The oxidation state of Xe in both
3 x+ 1=0 Xe O2∧ XeF4 is 4.
−1 XeO 2 XeF 4
x=
3
x +2 (−2 )=0 x +4 (−1 )=0
14 (a) x=4 x=4
In alkaline medium
18 (a)
+7 +6
−¿⟶ K 2 MnO 4 ¿ The sum of oxidation states of all elements in an
KMnO 4 +OH
ion is equal to charge on it.
Change in oxidation number 2−¿=x ¿
Let the oxidation state of S in SO 4
= 7−6

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 ∴ x+(−2 ×4 )=−2 ∴ Change in oxidation state of Cr is zero when it
Or x=+6 changes from
K 2 Cr2 O7 ¿ K 2 CrO 4.
19 (a)
Let oxidation state of Cr in K 2 Cr2 O 7=x Assertion - Reasoning Type
(+1 ×2)+ 2 x + (−2 ×7 )=0 20 (c)
or +2+2 x−14=0 Oxidation number of N is changed according to
∴ x=+6 compounds
Let oxidation state of Cr in K 2 CrO 4=x (-1 to +5) N has five types of oxides as
+1 ×2+ x + (−2 ×4 )=0 NO 2 , NO , N 2 O3 , N 2 O4 ∧N 2 O5 . All have different
2+ x−8=0 oxidation states in different compounds.
x=6

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