B A B

7C C7B CA 8E 49C C1F FCB A9 95A 108 8D0

7B CA 8E 49C 1F CB A9 5A 108 D0 FA
C 4
7B A 8E 9C 1F CB A9 5A 108 D0 FA F2
BC CA8 8E4 49C 1FC CBA A95 5A1 108D D0F FAF F2C C1C
9 1 0 3
CA A8E E49 C1F FCB BA9 95A A10 8D 0FA AF2 2C1 1C3 7C7
4 C C 5 1 8 0 F F C C 7

Q.4
Q.3
Q.2
Q.1
A8 8E4 9C 1FC BA A95 A1 08D D0F AF 2C 1C 37C C7B BCA
9 1 A 0 1 3
8E E49C C1F FCB BA9 95A 10 8D0 0FA AF2 2C1 C37 7C7 7BC CA8 8E4
49 1 CB A 5A 10 8 F F C C 3 C B A E 9C
49 C1 FCB A 95A 10 8D A AF2 2C1 1C3 7C 7BC CA8 8E4 49C 1FC
F 9 F2 C1 C37 7C7 7BC A8 E4 9C 1FC BA
9C C1F CB A9 5A 108 8D0 C 9 1
1 C B A 5 A 01 D F

Instructions:
2C C1C 37C C7B BCA A8E E49 C1F FCB BA9 95A
1F FCB A9 95A 108 8D0 0FA 1 3 7 C 8 4 C
1 C1 C3 7C BC A E4 9C 1F CB A95 5A1 108
8 D

i)
7 7 1 C A

ii)
FC CBA A95 5A1 08D D0F FAF
1C C37 C7B BCA A8E E49 9C1 FC BA 95A A10 08D 0FA
BA 95 A1 08D 0F AF
95 A1 08D 0F AF 2C 3 C 7 C 8 4 C C A 5 1 8D F F F B 9 0
37 7C7 BC A8 E49 9C1 1FC BA 95A A10 08D 0F AF 2C1
A1 08 0 A 2C
D F F C B A E B A 2

0.34V.)
08 0 A 2C 1 7C 7B CA 8E 49C C1F FCB A9 95A 108 8D0 0FA F2 C1C C37
D0 FA F2 1 7 C 8 4 1 C A 5 1 D F F C
[Duration : Two Hours]

FA F2 C1 C C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C C7B

F2 C1 C37 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA
C1 C3 BC A8 E4 9C 1FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E
Total No. of Printed Pages: 02

C3 7C 9 1 0 3
7C CA A8E E49 C1F FCB BA9 95A A10 8D 0FA AF2 2C1 1C3 7C7 7BC CA8 8E4 49C
C 8
7 8 4 1 C A 5 1 D 0F F C C3 7C B A E 9C 1F
A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49 1F CB
9 1 1 3

principle of the cell.

A 0 4 C

)
8E E49C C1F FCB BA9 95A 10 8D0 0FA AF2 2C1 C37 7C7 7BC CA8 8E4 9C1 1FC CBA A95
8 C
49 1 CB A 5A 10 D FA F2 C1 3 C BC A8 E4 C FC BA 95 A1 9

of the cell. (Data given :

C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08
FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA
95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2
A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C1
08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1 C3
D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C C 7C
FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C 7B

Nature of corrosion product.

F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA
EACH PART.

C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37 7B CA 8E
C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37 C7 C 8 49
7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C7 BC A8 E49 C1

1
7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7 BC A8 E4 C1 FC
CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 BC A8 E4 9C FC BA
PART-A

8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC A8 E4 9C1 1FC BA 95

c) Explain the mechanism of chemical corrosion.

Chemistry

Position of the metal in the EMF series.

49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C FC BA 95 A1

Part- B
C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08
FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA
95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2
A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C1

cadmium and copper are -0.4V and 0.34V respectively.

08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1 C3
D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C C 7C
EXAMINATION AUGUST 2020

3) Assume additional data, if required.

FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C 7B

2) Draw diagrams wherever necessary.

8D0FAF2C1C37C7BCA8E49C1FCBA95A10
F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA
C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37 7B CA 8E
F. E Semester-I (Revised Course -2019-20)
Paper / Subject Code: FE1905 / Chemistry

C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37 C7 C 8 49

d) Describe ‘pitting corrosion’ with the help of a suitable example.

7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C7 BC A8 E49 C1

b) Discuss the effect of the following factors on the rate of corrosion:

7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7 BC A8 E4 C1 FC
CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 BC A8 E4 9C FC BA
8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC A8 E4 9C1 1FC BA 95

Nernst equation. Also calculate the standard electrode potential. Given

49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C FC BA 95 A1
C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08

b) Explain the various types of polymerization by giving suitable examples.

FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA

a) Give the mechanism and industrial application of Beckmann rearrangement.

95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2
d) Discuss the Wet electrochemical theory of corrosion with a suitable example.

A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C

c) With the help of neat labeled diagram explain fractional distillation of crude oil.
08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1
D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C
FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C
F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 3
C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37
a) Sketch the electrochemical cell and write the cell reactions if Zn electrode is dipped in

c) Explain galvanic corrosion by giving suitable example along with necessary reactions.

reactions and calculate the standard EMF of the cell, if standard electrode potentials of

a) Outline the construction of Glass electrode and illustrate how it can be used to find pH.
C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37
a) Give the representation of a standard Cadmium-Copper cell, write the electrode and cell

b) A Concentration Cell is constructed by dipping copper rods in 0.001M and 0.1M CuSO4
7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C
d) Explain one suitable method for protection against corrosion of an underground pipeline.
b) What is single electrode potential? With neat labeled diagram explain the measurement of

c) A copper rod is placed in 0.1 M CuSO4 solution at 298K. Write the electrode reaction and

7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7

Solutions. Calculate the EMF of the cell at 298K. Explain the working principle of the cell
0.05M Zn2+ Solution and Mg electrode dipped in 0.01M Mg2+ solution. Calculate the EMF

CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 B
electrode potential of copper electrode (Cu2+ /Cu ) (Standard electrode potential of copper is
1) Answer THREE FULL QUESTIONS with ONE QUESTION FROM

8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC

49 1 CB A 5A 10 8D FA F2 C1 C3 C BC

(4)
(6)
(6)
(4)
(4)
(6)
(6)
(4)
(4)
(6)
(6)
(4)
(4)
(6)
(6)

C1 FC A 95 1 8D 0F F C C3 7C 7B A
FE1905

[Total Marks : 60]

FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8
95 A1 08D 0F AF 2C 1C 37C 7B CA 8E
A1 08 0 A 2C 1C 37 7B CA 8E 4
08 D0 FA F2C 1C 37 C7B C 8E 49
D F F 1 3 C A 4
 B A B
7C C7B CA 8E 49C C1F FCB A9 95A 108 8D0
7B CA 8E 49C 1F CB A9 5A 108 D0 FA
C 4
7B A 8E 9C 1F CB A9 5A 108 D0 FA F2
BC CA8 8E4 49C 1FC CBA A95 5A1 108D D0F FAF F2C C1C
9 1 0 3
CA A8E E49 C1F FCB BA9 95A A10 8D 0FA AF2 2C1 1C3 7C7
4 C C 5 1 8 0 F F C C 7

Q.8
Q.7
Q.6
Q.5
A8 8E4 9C 1FC BA A95 A1 08D D0F AF 2C 1C 37C C7B BCA
9 1 A 0 1 3
8E E49C C1F FCB BA9 95A 10 8D0 0FA AF2 2C1 C37 7C7 7BC CA8 8E4
49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C
49 C1 FCB A 95A 10 8D 0FA F2 C1 C3 7C 7BC A8 E4 9C 1FC
F 9 0 7 7
9C C1F CB A9 5A 108 8D0 FA F2C C1C C37 C7 BC A8E E49 9C1 1FC BA
1 C B A 5 A 01 D F F
A 2 1 3 C

c)
a)
c)
a)
7 BC A8 4 C FC BA 95

d)
b)
d)
b)
1F FCB A9 95A 108 8D0 0FA F2 C1C C37 7C7 BC A8 E49 9C1 1FC BA 95 A10
1 C B E A

i)
ii)
FC CBA A95 5A1 08D D0F FAF F2C 1C 37C C7B CA A8E 49C C1F FCB BA9 95A 108 8D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA
95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2
A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C1
08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1 C3

working.
D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C C 7C

chromium.
FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C 7B
temperature.

F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA

C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37 7B CA 8E
C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37 C7 C 8 49
7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C7 BC A8 E49 C1
7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7 BC A8 E4 C1 FC
CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 BC A8 E4 9C FC BA
8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC A8 E4 9C1 1FC BA 95
49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C FC BA 95 A1
C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08
FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
Chemical properties
Electrical properties

BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA

95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2
A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C1
08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1 C3
D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C C 7C
FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C 7B
F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA
C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37 7B CA 8E
C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37 C7 C 8 49
7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C7 BC A8 E49 C1

2
7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7 BC A8 E4 C1 FC
CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 BC A8 E4 9C FC BA
8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC A8 E4 9C1 1FC BA 95
Part-C

49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C FC BA 95 A1
C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08
FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA
Explain any two polymerization methods you know.

95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2 Differentiate between enantiomers and Distereomers.
A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C1
How will you find the optical activity of an enantiomer?

08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1 C3

c) Distinguish between Octane number and Cetane number.

D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C C 7C
d) Classify Polymers based on response to heat and structure.

FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C 37C 7B

8D0FAF2C1C37C7BCA8E49C1FCBA95A10
F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 37C 7B CA
C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37 7B CA 8E
Paper / Subject Code: FE1905 / Chemistry

C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37 C7 C 8 49
7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C7 BC A8 E49 C1
7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7 BC A8 E4 C1 FC
b) Discuss the following structure –property relationship in polymers.

CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 BC A8 E4 9C FC BA
What is the principle of Gas chromatography? Explain the working.

8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC A8 E4 9C1 1FC BA 95

Explain how nature of oxide layer affects the further rate of corrosion.

49 1 CB A 5A 10 8D FA F2 C1 C3 C BC A8 E4 9C FC BA 95 A1
C1 FC A 95 1 8D 0F F C C3 7C 7B A E 9C 1F B 9 A 08
How is mechanical strength of polymer related to the structure? Explain.

d) With the help of neat labeled diagram explain the working of Zn-air cell.
FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA 8E 49C 1F CB A9 5A 108 D0
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 10 D0 FA
a) Give the mechanism and industrial applications of Riemer-Tiemann reaction.

95 A1 08D 0F AF 2C 1C 37C 7B CA 8E 49C 1F CB A9 5A 108 8D0 FA F2

A1 08 0 A 2C 1C 37 7B CA 8E 49 1 CB A 5A 10 D FA F2 C
08 D0 FA F2C 1C 37 C7B C 8E 49 C1 FC A 95A 10 8D 0FA F2 C1
What is the principle of FTIR? Explain its working and mention the applications.

D0 FA F2 1 37 C7 C A8 4 C1 FC BA 95 1 8D 0F F C
c) State and explain measures for corrosion control by modification of environment.
FA F2 C1 C37 C7 BC A8 E4 9C1 FC BA 95 A1 08D 0F AF 2C 1C
F2 C1 C37 C7 BC A8 E4 9C FC BA 95 A1 08D 0F AF 2C 1C 3
d) Explain the process of degradation of polymers due to oxidation and exposure to high

C1 C3 C BC A E4 9C 1F B 95 A1 08 0 A 2C 1C 37
C3 7C 7B A 8E 9C 1F CB A9 A 08 D0 FA F2C 1C 37
What do you understand by Weathering and Environmental stress cracking of polymers?

7C 7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 1C 37 C
7B CA 8E 49C 1F CB A9 5A 108 D0 FA F2 C1 37 C7
CA 8E 49 1F CB A9 5A 10 D FA F2 C1 C3 C7 B
8E 49C C1F CB A9 5A 10 8D0 0FA F2 C1 C37 7C7 BC
49 1 CB A 5A 10 8D FA F2 C1 C3 C BC
(5)
(5)
b) With the help of neat labeled diagram explain the process of Electroplating of an article with (5)
a) States the basic principle involved in the working of Uv-visible spectroscopy and explain its (5)
(5)
(5)
(5)
(5)
(4)
(4)
(6)
(6)
(4)
(4)
(6)
(6)
(4)

C1 FC A 95 1 8D 0F F C C3 7C 7B A
FE1905

FC BA 95 A1 08D 0F AF 2C 1C 7C 7B CA
BA 95 A1 08D 0F AF 2C 1C 37C 7B CA 8
95 A1 08D 0F AF 2C 1C 37C 7B CA 8E
A1 08 0 A 2C 1C 37 7B CA 8E 4
08 D0 FA F2C 1C 37 C7B C 8E 49
D F F 1 3 C A 4