K-1600

Half Yearty Examination (2022- 23)

Subject Chemistry
hrs Class- Xil Marks 70

l instructions-

Al questons are compuisory

questions and camy 1 mark eacn
to 20 very short answer
1
Secton AQ no are

2 mark each
Secton B Q no 21 to 27 are short answer questions and carry
carry 3 marks each
Secton C Q no 28 to 34 are long answer questions and
marks each
Secton D Qno 35 to 37 are also long answer questions and carry 5
e

LSection Al follow
the questions 1 to 5 that
the given passage and
answer
Read and
observed in graphite.
polyacetylene
to well ordered super iattice
when Lthum ion s dopped Similar to
20 foid decrease upon doping.
m e a s u r e m e n t s presented
C h o s t s in situ resistvity
transfer between
compounds This can be explained by charge
wnat s ocserved in
graphite
intercaiation compounds
and C agand anaiogous
to graphite
(1) Which type of cel is used in hearing ads
conductance (K) and resistivity
the eiationship between
specitic
2 hat s

is used in mobile phone

3) Whch type of battery in acidic
coulombs of eiecticity s required to reduce
1 mole of Cr,0.
HOw many

medium 127 and 76 ohm cm eq-1 at

conductance of and Cl are respectively
) T h e equvalent Ba"
dilution
conductance of BaClh at this
nfinte dilution what would be the equivalent
word a n s w e r s
2uestions 6 to 10 are one
tor its rate constant LMol S
order of the reacton trom the following unt
dentity the
what are isotonic solutons

What happens when bromine attacks

CHCH-CH-C -CH
isomer is more volatile
Whch of the toilowing
P-nitrophenol?
O-ntropheno
what are aziotropes

Questions 11 to 15 are multiple choice questions:

reaction
The rate constant of a reacton is k= 328 *10" S Find the order of the
Zero order b) First order
Third order
c)Second order )
of a substance in a solvent depends on
The solubility
(b) Pressure
a) Temperature
Al of the above
Nature of solute & solvent (d)
c) IP TO]
 2 Chemistry-12- 1600
(13) The transition element with lowest atomic number is
(a) Scandium (D) Titanium (c) Zinc (d)Lanthanum
(14) Which among the following is an example of a solid solution?
(a) Copper dissolved in gold (b) Ethanol dissolved in water

(C) Glucose dissolved in water (d) Sodium chloride dissolved in water

(15) Which of the following products are obtained when Na,CO, is added to a solution of copp

sulphate?
(a) Basic copper carbonate, sodium sulphate and CO,
(b) Copper hydroxide, sodium sulphate and CO;
(c) Copper carbonate, sodium sulphate and CO,
(0) Copper carbonate and sodium sulphate

Questions 16 to 20
A
Both Assertion and reason are correct statement and reason is the correct explanation

the assertion
Both assertion and reason are correct statement but reason is not the correct explanatio
B

of the assertion
Assertion is correct but reason is wrong statement

Assertion is wrong but reason is correct statement

(16)
D.
Asertion: Molarity of a solution in liquid state changes with temperature
The volume of a solution changes with change in temperalure.
Reason:
(17) Assertion: If a liquid solute more volatile than the solvent is added to the solvent. the vapour
°
pressure of the solution may increase 1e, P, Po
In the presence of a more volatile liquid solute, only the solute will form the vapoOL
Reason
and solvent will not
observed
Assertion: VWhen NaCl is added to water a depression in freezing point is
J8) The lowering of vapOur pressure of a solution causes depression in the freezing
Reason
point
When a solution is separated from the pure solvent by a seml-permeable
(19) Assertion:
membrane, the solvent molecules pass through it from pure solvent side to the

solution side
eason Diffusion of solvent ocCurs from a region of high concentration solution to a reg

of low concentration solution

is added to water, boiling point of water increases
(20) Assertion: When methyl alcohol

Reason: When a volatile solute is added to a volatile solvent elevalion in boiling point is

observed
[SECTION8]
reduce the-
(21) The rate constant for a first order reaction is 60
s". How much time will it take to

concentration of the reactant to 1/10th of its initial value?

 3 Chernistry-12-1600

(22) What are the transition elements ? Write two characteristics of the transtion elements

How will you convert the tollowing

(23)
2,4,6-
)
(9 propan -2-ol to propanone (i) phenol to tribromopheno
How Is vapour pressure of solvent affected when a non-volatile solute is dis5olved in t ?

OR
State Henry's law what is the effect of temperature on the solubilty of a gas in a liquid 7

(25 Zinc rod is dpped in 0 1M soluton of Zn$O. The salt is 95% dissociated at this dilution at 256 K

Calculate the electrode potential

(26) Why do transition elements show variable oxidation State ? In 3d series, which elerment show ue

maximum number of oxidation state and why?

(27) Write the name of the cell which is generally used in inverters write the reactions taking place at

the enode and the cathode of this cell

LSECTION-C]
Complete the tollowing equations
(28) ?
2 MnO, 16 H' (0 C, O + 2 0OH 7
0 +
5S Ph sC.
(i) 8 MnO +3S,0, H,0?
2
29) How do you convert
) chlorobenzene to bipheny! ( propene to 1- lodopropane

( 2- Bromobutane to but -2-ene

(30) What happens when
4 Ethanol is treated with Cu at 573 K
C
Phenol is trealed with CH,COCI/ anhydrous
(t) AlC C-C

(11) Ethyl chloride is treated with NaOCH,

(31) For a first order reaction, show that time required for 99% completion is twice the time required
for the completion of 90h of reaction
OR
In a first order reaction, the concentralion of the reactant is reduced from 0.6 mol L" to 0.2 mol L
in 5 minutes.calculate the rate constant of the reaction T

(32) Although chlorine is an electron withdrawing group. yet it is Ortho-para directing in electrophilic
aromatic substitution reactions. Explain why it is so7
33) How do you convert the following- '/2
(0 aniline to phenol Sx
prop-1-ene to propanol
)Anisole to 2- Methoxytoluene
The molar conductivity of 1.5 M solution
34) a

Calculate the çonductivity of the solution.

of an electrolyte is found to be 138.9 S Cm mot".

LSECTION-D]
35) (a) A first order reaction take 40 minules for 30% decomposition. calculate tin for this reaction
(Given: log 1.428 0.1548)
 Chemistry-12-1600
Defne he toiliowng temm

ATvatiom energy o' a reacton

raes amost reactons doubie when their temperature is rised from 298 Kto S08 K
a i a t e atvarOn energy of Such a reaction
R 3 1 4J mo K og 3010)

Ea v e reasons for the tollowing9

Sertychioride is hghly reactve towards the SN1 reaction

) 2-Sromabutane is opticaly active but 1- Bromobutane is opticdiy
Nucleopnilic reactions in haloarenes occur slowly
"au

Wne the main products when

methy chioride is treated with AgCN
chionde s with AgNO;
ehy treated
OR

a Write he structures of the major product in each of the following reactons

CR-CH CH - H-0

CCH:
CH CHBCH, KOH-
m) 2CH-CH(CT-CH;
Account or the tolowing
Chiorotorm s stored in a ciosed dark brown botles
) The C-Ci bond length in chiorobenzene is shorter than that in CH,-C

the toliowing-
for boling
AccountThe point ot aicohols decrease with increase in branching of the alkyl chain.

Phenol does not give protonation reaction readily

ether reacts wth Hl to give Phenol and methyl iodide and not
Phenyl methyl
OdObenzene and methyl aicohol

ustrate the tollowing reactions gving a chemical equation for each.

)
Kolbe's reaction

wiliamson synthesis
PR
How do you convet the tollbwing
(a)
Phenol to 2- Hydroxyacetophenone C
Ethyl chionide to methoxy ethane
methyipropan-2- ol
(m)Acetone to 2-
)Arange the following compound in the increasing order of their property indicated
(9 -nitrophenol ethanol. phenol (acidic character)
propanol. propane. propanal ( boiling point )
Cn:CCG