Aldehydes, Ketones Question SET

(b) Assuming no temperature change and
atmospheric pressure to be Po, find the Where DP is pressure difference at the two ends of
surface tension of the soap solution. the tube and h is coefficient of viscosity. Assume
Q.23. In the last problem, one of the bubbles supplies Vidyamandir Classes
Vidyamandir Classes that the bubble remains spherical.
its entire air to the other bubble and a film of soap Q.27. Two blocks are floating in water. When they are
solution is formed at the end of the straw which brought sufficiently close they are attracted to
keeps it closed. What is the radius of curvature each other due to surface tension effects. When
of this film if the bigger bubble has grown in size the experiment is repeated after replacing water
and its radius has become R3. with mercury,/ GOAonce /again the two blocks are
MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK BOKARO / PUNE
attracted. Explain the phenomena. It is given that
IIT – JEE: 2022 MathematicsProperties CRASH
Partof COURSE
Matter
Test (ADV)
- 4 |Question
JEE SET
Advanced-2020 2 material of DATE: 29/12/21
een the
LeveL 3 Aldehydes, Ketones Question
water SETthe
wets the block where as
at point TIME: 2 Hr. TOPIC: ALDEHYDE & KETONES mercury does not. MARKS: 120
Matrices & Determinants, Film of soap Probability, Vectors & 3D-Geomatry
Q.1:
Q.24. Consider a rain drop falling at terminal solution
speed. For Q.5:
Q.28. A long thin string has a coat of water on it. The
r2 = r. what radius (R) of the TIME drop can : SINGLE
we disregard
3 hrs CORRECT
the ANSWER TYPE
radius of the water
M.M. : 236cylinder is r. After some time
terface
Thisinfluence
section of gravity on its shape? Surface tension
contains 15 multiple choice questions. Each question
R3 of water are T and r respectively.
it was foundhas that4the string had
options (A),a (B),
series(C)of equally
and
and density spaced identical water drops on it. Find the
(D) for its answer,
Read the out of which ONLY
following ONE option
Instructions can be correct.
very carefully before you proceed.
sts and Q.25. A soap bubble has radius R and thickness of its
Q.2: minimum distance between two successive drops.
Marking
1. scheme:
This question +4 forconsists
paper correct of 3answer,
sections 0 if not
(Section I, attempted
Section and
III). –1 in all other cases.
le find wall is a. Calculate the apparent weight (= true Q.29. A &liquid
Q.6:
II Section
having surface tension T and density r
en that weight - Buoyancy) of the bubble if surface
2. Section I contains 3 types of questions [Type 1, Type 2 & is in contact with a vertical solid wall. The liquid
Type 3]
R and 1. tension
Which statement
of soap is and
solution correct for product
its density ‘X’?
are T and surface gets curved as shown in the figure. At the
Type 1 contains 10 Single Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and (D), V
d respectively. The atmospheric pressure is P0 bottom the liquid surface is flat.
out of which ONLY ONE CHOICE is correct.
and density of atmospheric air is r0. By assuming The atmospheric pressure is Panswer]
 Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong o.
a = 10–6 m, R = 10 cm, P0 = 105 Nm–2, r0 = 1.2
kg m–3, Type
d = 10 3
kg m–3,20T Multiple
2 contains = 0.04 Nm –1
Correct; show that Type Questions. Each question
Answer A has 4 choices (A), (B), (C) and
the weight of the bubble is mainly because
(D), out of which ONE OR MORE CHOICES may be correct. of
h
water inthe skin. What scheme
Marking is weight of the for
[4 Marks bubble?
All Correct answers & –1 NEGATIVE MARKING for wrong answer]
Q.26. A soap Type
Q.3: bubble is blownFIVE
3 contains at the end of aBased
paragraphs. capillary
on these paragraphs, there are TEN questions. Each question has
tube of radius a and length L. When the other end
R1) are (A) 1º alcohol functional group is present of
FOUR options (A), (B), (C) and (D).
is left open, the bubble begins to deflate. Write
ONLY ONE in these
‘X’ four options is correct.
bble to (B)Ethyl group
Marking isscheme
present [3 in ‘X’of
Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
the radius of the bubble as a function time if
mains.
the (C)
3. initial2º-alcohol
radius
Section of functional
the bubble
II contains group
16 Single Ris
wasInteger0 . present
Value in
Surface ‘X’Questions.
Type (i) The
Findanswer
the pressure
to eachin of
thethe
liquid at the top
questions is aof the
(D)single-digit
tension Alkene
of functional
soap solution is group isis known
T. Itfrom
integer, ranging 0present in ‘X
that
to 9 (both inclusive). meniscus (i.e. at A)
volumeflow rate through
Marking a tube
scheme of radius
[4 Marks a and answer & NO (ii)
for Correct Calculate
NEGATIVE the difference
MARKING for wronginanswer]
height (h) between
length
2. 4. You L is given
have III
twoby Poiseuille’s
C6 H104OMatch equation-
ketones, I and II.type Bothquestions.
are optically active,
bottom but
thequestion and Itop
is of
racemized by
the meniscus. treatment
Section contains the columns Each contains statements given in
p a 4 DP
Q =with acid andStatements
2 columns. II is not. Wolff kishner
in the first reduction
column have to ofbeboth
Q.7:
Q.30. Isketones
matchedit with gives
possible the same
that
statements in theachiral
water hydrocarbon,
evaporates
second column.from a
h L answers to. What
8The
formula C6 H12 reasonable
these questions have structures may be assigned
to be appropriately intothe
spherical
bubbled Idrop
and II respectively?
of
answer water
sheet.just by means of surface
(A)I is 3-Methyl-4-Penten-2-one energy supplying the necessary latent heat of
Marking scheme [8 Marks if you darken ALL the bubbles corresponding ONLY to the correct
L vaporisation? The drop does not use its internal
II is 4-Methyl-1-Penten-3-one
answer or given 2 MarksReach for correct bubbling of answer in any row. No Negative mark will be
2a
0
thermal energy and does not receive any heat
(B) I is 2-Methyl
given for cyclopentanone
an incorrectly bubbled answer]
from outside. It is known that water drops of
ut ? 5. II is 3-Methyl cyclopentanone
For answering a question, an ANSWER SHEET (OMR SHEET) size less than 10–6separately.
is provided m do not exist.
PleaseLatent heat of
fill your Q.32. A
(C)Test
I isCode,
3-Methyl cyclopentanone
Roll No. and Group Properly in the space given invaporisation
the ANSWER of water is L = 2.3 × 106 Jkg–1 and
SHEET. a
e and i
II is 2-Methyl cyclopentanone surface tension is T = 0.07 Nm–1.
nd the Where DP is pressure difference at the two ends of t
(D) and
the tube I is h
2-Ethyl cyclobutanone
is coefficient of viscosity. Assume Q.31. In the arrangement shown in the figure, A is a jar
Q.8:
t
upplies
II is 3-Ethyl
that the bubble remainscyclobutanone
spherical. half filled with water and half filled with air. It
is fitted with a leak proof cork. A tube connects
of soap Q.4:
Q.27. Two blocks are floating in water. When they are
it to a water vessel B. Another narrow tube
which brought sufficiently close they are attracted to
fitted to A connects it to a narrow tube C via
rvature each other due to surface tension effects. When
a water monometer M. The tip of the tube C is
in size the experiment is repeated after replacing water
just touching the surface of a liquid L. Valve V
with mercury, once again the two blocks are
is opened at time t = 0 and water from vessel B
attracted. Explain the phenomena. It is given that
pours down slowly and uniformly into the jar A.
water wets the material of the block where as
An air bubble develops PartatTest-4
the tip| JEE-2020
of tube C. The
mercury does not.
VMC | Mathematics 1
Q.33. A
cross sectional radius of tube C is r and density of
Q.28. A long thin string has a coat of water on it. The water is r. The difference in height of water (h) in c
VMC radius
| Physics Assignment
of the water cylinder is r. After some time 1
the two arms of the manometer variesPhysiCs with time i
it was found
CENTERS that the/ D
: MUMBAI string
ELHIhad
/AaKOLA
series/K
of OLKATA
equally /NASHIK /'t'PUNE / GHAZIABAD
as shown in the graph./ B
Find / DUBAI
the surface
OKARO #1
tension d
spaced identical water drops on it. Find the of the liquid L. t
minimum distance between two successive drops. t
3. Cannizzaro's reaction can be exemplified by one of the following :
(A)
(B)
(C)
(D)
4.
(A)
O 2N O
(B)
NO 2
(C)
CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI # 2
(D)
5.
Correct statement about compound (D) formed in above reaction sequence is :

(A) It is a chiral compound.
(B) It has 3 chiral center.
(C) It can be classified as ketal
(D) It can reduce fehling solution
6. Predict the major product of the given reaction.
Product (A) is :
(A)
(B)
(C)
(D)
7. Identify the major product,
(A)
(B)
(C)
(D)
8. Acid catalyzed Aldol condensation of 1-phenyl-1,2-propanedione  C6 H5COCOCH3  gives which of

the following?
(A)
(B)
(C)
(D)
9.
The product ‘P’ is :
(A)
(B)
(C)
(D)
 X  
CH  O  excess  conc.NaOHsolution
 Y   Z  

CrO3 /H /H 2 O
10. 2
 
 CH 3COOH  3CO 2
C5H12O4
The compound (X) is:
(A) CH 3CH  O
(B) CH 3  C CH 3
||
O
(C) CH 2  O
(D) CH 3  CH 2  CH 
O
11. Product X is:
(A)
(B)
(C)
(D)
12. Possible structure of F is :
(A)
(B)
(C)
(D)
13. Identify the product (C) of the given sequence of reaction
(A)
(B)
(C)
(D)
14. Identify product :
(A)
(B)
(C)
(D)
15.
(A)
(B)
(C)
(D)
MULTIPLE CORRECT ANSWER(S) TYPE

This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO
incorrect option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C)and (D)are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A)and (D)will result in +2marks; and
darkening (A)and (B)will result in –2 marks, as a wrong option is also darkened.
16. In which of the following reaction Keq. > 1 :
(A)
(B)
(C)
O
(D) ||
H 2O
CF3  C H  
17. Correct statement regarding following reaction sequence:

(X, Y, Z all are organic products)
(A)
(B)
(C) Formation of X is bimolecular nucleophilic substitution reaction
(D)
18. In which reaction the product will react with 2, 4 dinitrophenylhydrazine.
(A)
(B)
(C)
HgSO4
(D) CH 3  C  C  CH 3 
H 2SO 4

19. Identify reactions give ketone product?
(A)
(B)

H3O
(C) PhMgBr  Me  C  N  
(D)
20. If ester (A) contain five carbon atom and product B & C gives positive iodoform test than structure
of ester 'A' is :
(A)
(B)
O
(C) ||
H 3C  CH 2  C  O  CH 2  CH 3
O
(D) ||
H 3C  C O  CH 2  CH 2  CH 3
21. Consider following reaction sequence
P1 undergoes aldol condensation while P2 can not.

Which of the following statement(s) is/are INCORRECT?
(A) NaHSO3 can be used to distinguish P1 and P2 .
(B) P2 reduces tollens reagent but can not reduce Fehling’s solution.
(C) P1 and P2 can undergo iodoform test.
(D) Compound P2 can give positive 2,4-DNP test but can not undergo Cannizzaro reaction.
22. Which statement is/are false about ‘X’?
(A) It undergoes dehydration in the presence of conc. H 2SO 4 & give cyclopropyl ethane as a major
product.
(B) It give Haloform reaction in the presence of NaOH  I 2
(C) It gives instant turbidity with Lucas reagent
(D) It converts into acid in the presence of cold KMnO 4 .
23. Which of the following reagents can convert benzene carbaldehyde to benzyl alcohol?
(A) LiAlH 4 ; H 2 O
(B) H 2 , Ni
(C) B2 H 6 ; H 2 O
(D) HCHO / NaOH
24.
Identify the unknowns:
(A)
(B)
(C)
(D)
PhH/HF H 2 /Pt NBS H 2 Oacetone MnO2

25. CH
 2 CH  CH 2  OH I
A  II
 B 
III
 C  IV
 D 
V
E
Which of the following statement(s) is/are correct?
(A) ‘B’ gives total 5 monochloro products on photochemical chlorination.
(B) ‘E’ gives positive test with NaOI.
(C) ‘D’ don’t give any turbidity even on heating with HCl  ZnCl 2
(D) Ist step is an electrophilic substitution reaction.
26.
(A)
(B)
(C)
(D)
14
27. Ba C O3  H 2SO 4 
 X  H 2 O  BaSO 4
gas
(A)
(B)
(C)
(D)
28.
(A)
(B)
(C)
(D)
29. x = no. of dianion intermediates which are better hydride donor than
(A)
(B)
(C)
(D)
30. In the following reaction
O
Br

C2 H 5 O Na 
 3
i H O

C 2 H 5 OH
A 
ii Soda lim e/   B
Product A and B are:

O
OC 2H5
(A)
O OC 2 H 5
C
(B)
(C)
(D)
NUMERICAL VALUE TYPE

This section contains 10 questions. Each question is numerical value type. For each question,
enter the correct numerical value (in decimal notation, truncated/rounded-off to second
decimal place. (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
31. Ninhydrin when undergoes hydration, which carbonyl carbon is first
attacked by H 2 O ?
32. The total number of compounds (shown below) that form phenyl hydrozone derivatives under acidic
conditions is :
33. If (X) is molecular weight of major organic product produced in following reaction then find the
 x  12 
value of  ?
 15 
34. How many of the following can be reduced by NaBH4?
35. Number of reagents by which can be converted in to followed
by acidification.
(i)  Ag  NH 3 2  OH (ii) Benedict’s Reagent
(iii) K 2 Cr2O 7 / H  ,  (iv) Conc. OH 
(v) KMnO 4 , HO  ,  (vi) CuSO 4  NH 4 OH
(vii) Zn–Hg/HCl (viii) Red P/HI
(ix) Alcoholic KCN (x)
36. Among the following how many can reduce tollen’s reagent:
HCOOH,CH 3COCH3 , PhCOOH, CH 3CHO, PhCOCH 3 ,
37. Of the following carbonyl compounds, how many would give self aldol condensation reaction?
38. Among
How many compounds give silver-white precipitate on reaction with Tollen’s Reagent?
39. Consider the following reaction sequence
How many carbons are present in the final product Z?
40. Identify the total number of compounds that give positive test with Tollen’s reagent

Aldehydes, Ketones Question SET

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(b) Assuming no temperature change and

Correct statement about compound (D) formed in above reaction sequence is :

6. Predict the major product of the given reaction.

7. Identify the major product,

8. Acid catalyzed Aldol condensation of 1-phenyl-1,2-propanedione  C6 H5COCOCH3  gives which of

The product ‘P’ is :

12. Possible structure of F is :

13. Identify the product (C) of the given sequence of reaction

MULTIPLE CORRECT ANSWER(S) TYPE

16. In which of the following reaction Keq. > 1 :

17. Correct statement regarding following reaction sequence:

(C) Formation of X is bimolecular nucleophilic substitution reaction

19. Identify reactions give ketone product?

21. Consider following reaction sequence

P1 undergoes aldol condensation while P2 can not.

22. Which statement is/are false about ‘X’?

Identify the unknowns:

PhH/HF H 2 /Pt NBS H 2 Oacetone MnO2

Product A and B are:

NUMERICAL VALUE TYPE

31. Ninhydrin when undergoes hydration, which carbonyl carbon is first

34. How many of the following can be reduced by NaBH4?

35. Number of reagents by which can be converted in to followed

(ix) Alcoholic KCN (x)

39. Consider the following reaction sequence

How many carbons are present in the final product Z?

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