atmospheric pressure to be Po, find the Where DP is pressure difference at the two ends of

surface tension of the soap solution. the tube and h is coefficient of viscosity. Assume
Vidyamandir
Vidyamandir Classes Classesthat the bubble remains spherical.
Q.23. In the last problem, one of the bubbles supplies
its entire air to the other bubble and a film of soap Q.27. Two blocks are floating in water. When they are
solution is formed at the end of the straw which brought sufficiently close they are attracted to
keeps it closed. What is the radius of curvature each other due to surface tension effects. When
of this film if the bigger bubble has grown in size the experiment is repeated after replacing water
andMUMBAI
its radius /has AKOLA become / DELHI R3. / KOLKATA / GHAZIABAD with / NASHIKmercury, / GOA / BOKARO
once again the / PUNE
two blocks are
IIT – JEE: 2022 CRASH COURSE (MAIN) attracted. Explain the DATE: 29/12/21
phenomena. It is given that
n the
LeveL TIME: 3 1 Hr.
Mathematics
JEE Main Properties JEE
TOPIC:
Part Main
- Halides, of
ALKYL Matter
Test - 4
Practice Question
| JEE
ARYL Test-20
&Alcohols, water
HALLIDE SET
Advanced-2020
Ethers 2
wets theSET materialMARKS:
of the block 120 where as
point mercury does not.
Matrices & Determinants, ALCOHOL
Film of soap Probability,
ETHERS
ALLEN Vectors & 3D-Geomatry
& PHENOLS
Q.1:
Q.24. Consider a rain drop falling at terminal solution
speed.PART 1 - PHYSICS
For Q.5:
Q.28. A long thin string has a coat of water on it. The
= r. what radius (R) of the TIME drop can 3 hrswe disregard
: SINGLE CORRECT the ANSWER radiusTYPE ofM.M.
the water
: 236cylinder is r. After some time
face SECTION–I : (Maximum
influence of gravity on its shape? Surface tension Marks : 80) 2. Velocity
it was found that the of
vector a particle
string had a seriesjust before
of equally
˜ This
This
and section
section contains
R3 of water
density contains 20 multiple
arefollowing
T and TWENTY choice
r respectively. questions.
questions.very carefullyEach question
making
spacedbefore has 4 options
an inelastic
identical (A),
impact
(B), (C)
with
and horizontal
(D) for its Read
answer, the
out of which Instructions
ONLY ONE option can beminimum correct. distance youwater proceed.drops on it. Find the
and ˜ Each question has FOUR
Q.25. A soap bubble has radius R and thickness of its
Q.2: options (A), (B), between two
smooth surface with coefficient of restitution successive drops.
find Marking
1.(C) is
wall and a.scheme:
This (D). ONLY
question
Calculate +4thefor
paper correct
ONE
consists
apparent of of3answer,
weight these
sections (= true 0 if not
four
(Section attempted
I, Section
Q.29.
Q.6: A and
II & Section
liquid –1 insurface
III).
having all othertensioncases.
T and density r
that 2.options is correct.
weight
1.tension For
- Buoyancy)
Section
the
I contains
given
of3
reaction:
the
types bubble
of questions if surface
[Type 1, Type 2 & is
Type (
0.2 is 3i - with
in contact
3] ˆ ˆ)
10 j -a50k ˆ m/ssolid
vertical with wall.z–axis
The liquid being
and of soap solution and its density are T and surface gets curved as shown in the figure. At the
˜ For ea Typech 1 question,
contains 10 Single darken the bubble
 i  AgNO3Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and (D),
d respectively. R  COOH 
The atmospheric R 
pressure Br is P vertically
bottom the upwards.
liquid surface Velocity
is flat. of the particle
corresponding
out of whichto theONE
ONLY correct
ii  Br 2 /CCl
CHOICE
4 option
is correct. in 0the
and density of atmospheric air is r0. By assuming 1s after collision (in m/s)
ORS.The  yieldMarkingof which product
scheme is maximum?
[3 Marks for Correct answer & –1 NEGATIVE The atmospheric
MARKING pressure
for wrong owill
is Panswer]
. be :-
a = 10–6 m, R = 10 cm, P0 = 105 Nm–2, r0 = 1.2
For m–3each
(A) question, –3 marks
=Br0.04 will –1 be awarded
2CH ( ) ( )
3  CH
2TMultiple
˜ kg , Type
d = 10 kg3 m ,20
contains Nm Correct; show Answer that Type Questions. (A)Each3iˆquestion hasˆ 4 choices
A- 10 ˆj + 10k (B)(A), 3iˆ -(C)
- (B), ˆj + 10kˆ
10and
in one
the weight
(B) of out
(D), the
of ofthe following
bubble
which ONEisOR categories
mainly
MORE CHOICES because: of be correct.
may
Full Marks
water inthe skin. :Marking
+4What Ifscheme
is weightonly of the
the bubble? bub ble answers & –1 NEGATIVE MARKING for wrong h

( ) ( )
[4 Marks for All Correct answer]
ˆ
(C) 3i - 10 j ˆ (D) - 3iˆ - 10 ˆj
corresponding
Q.26. A soap Type
Q.3: bubble to
is blownFIVE the
at the correct
end of aBased option
capillary is
3 contains paragraphs. on these paragraphs, there are TEN questions. Each question has
darkened.
tube of radius a and length L. When the other end
) are
What will the ideal ammeter read for the
FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
Zero
is Marks
left open, the: bubble
0 If none beginsoftothe deflate.bubbles Write is 3.
le to  Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
ains. darkened.
the radius
(C) of the bubble as a function of time if circuit shown here?
the
3. initial radius of the
Negative Marks : –1 In all other 0cases
Section II contains bubble
16 Single was R
Integer . Surface
Value Type Questions. (i) TheFindanswer
the pressure
to eachin ofthetheliquid at the top
questions is aof the
tensionsingle-digit
of soap solution is T. Itfrom
integer, ranging is known
0 to 9 (both that inclusive). meniscus (i.e. at A)
1. In theflow
volume circuitrate shown
through in
a tube figure,of radiusinitially a andthe 90Winanswer]
(D) Marking scheme [4 Marks for Correct answer & NO (ii) Calculate
NEGATIVE MARKINGthe difference
for wrong height (h) between
terminals
length L is given A and P are connected
by Poiseuille’s equation- together the bottom and top of the meniscus.
10W A given in
to charge
p a 4 DP 4µF capacitor. Then battery is
4. Section III contains 4 Match the columns type questions. Each question contains statements
Q = 2 columns. Statements in the first column have to Q.7:
Q.30. Is it with
be matched 45V
possible that water
statements evaporates
in the second column. from a
disconnected,
h L answers
8The and the terminals P and B are spherical drop of water
to these questions have to be appropriately bubbled in the answer sheet.just by means of surface
10W
2. connected
Inthe given together. reaction Then sequence the (Q) ratio and of
(R)final
respectively energy supplying the necessary
are: latent heat of
charge and initial charge on 4 µF capacitor
Marking scheme [8 Marks if you darken ALL the bubbles corresponding ONLY to the correct
L  vaporisation? The drop 20Wdoes not use its internal
2ais :
C 6 H 5  CH
answer
2  NH 
or given
2
CHCl
alc
2 3Marks
KOH
0
 PReach
 H 2for
O/OH

 
correct Q    R
bubbling  of answer in any row. No Negative mark will be
thermal energy and does not receive any heat
given for an incorrectly bubbled answer]
(A) C6 H 5  NH 2 and CH 3COOH from outside. It is known that water drops of
? 5. A B
For answering a question, an ANSWER SHEET (OMR SHEET) size less than 10–6separately.
is provided m do not exist.
PleaseLatentfill your heat of Q.32
(B) C6 H 5  CH 2  NH 2 and HCOOH 6 –1
and Test Code, Roll No. P and Group Properly in the space given invaporisation the ANSWER of water is L = 2.345
SHEET. × 10 Jkg and
(C) V C6 H 5  CH 2 4µF NH 2 and 2µF CH 3COOH (A) 0.5A
surface tension is T = 0.07 (B) Nm–1. A
the Where DP is pressure difference at the two ends of 130
(D)
the tube and 6h isC H  CH
5 coefficient
2  OH and C
of viscosity. H 
6 5 Assume CH 2  NH  CHQ.31.
Q.8: 3 In the arrangement shown in the figure, A is a jar
that the bubble remains spherical. half filled
45 with water and half filled 9 with air. It
plies (A) 1/3 (B) 3/4 (C)fitted A
is with a leak proof (D)
cork. A A connects
tube
soap Q.4: 94 23
Q.27. Two(C) 4/5
blocks are floating in(D) water. 5/6When they are it to a water vessel B. Another narrow tube
hich brought sufficiently close they are attracted to
fitted to A connects it to a narrow tube C via
ature each other due to surface tension effects. When
a water monometer M. The tip of the tube C is
size the experiment is repeated after replacing water
just touching the surface of a liquid L. Valve V
All India
withOpen Test/Leader
mercury, once& againEnthusiast the Course/JEE(Main)
two blocks are 0000CJA102119031
Page 2/19 SPACE
is opened at time t = 0 and water from vessel B
attracted. Explain the phenomena. It is given thatFOR ROUGH WORK 29032020
pours down slowly and uniformly into the jar A.
water wets the material of the block where as
An air bubble develops atTest-4 the tip| JEE-2020
of tube C. The
Cmercury : MUMBAI
does
VMC | Mathematics
ENTERS not. /DELHI /AKOLA /LUCKNOW1/ NASHIK /PUNE /NAGPUR / Part
cross sectional radius B tube C is/ D
ofOKARO UBAI
r and # 1 of
density Q.33
Q.28. A long thin string has a coat of water on it. The water is r. The difference in height of water (h) in
VMC radius| Physics
of the waterAssignment cylinder is r. After some time 1
the two arms of the manometer variesPhysiCs with time
VMCit |was JEE found Main that the string had a series of equally 1
't' as shown in the graph. Find the surface TESTS
PRACTICE tension
spaced identical water drops on it. Find the of the liquid L.
minimum distance between two successive drops.
3. Which one of the following gives (E) alkene when treated with alc KOH /  ?

(A)

(B)

(C) (A) and (B)

(D)

4. Which one of these is least reactive for ArSN reactions:

(A)

(B)

Cl
NO2 NO2
(C)

NO2
Cl

(D)
NO2
NO2

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5. Dichloromethane on treatment with alc KOH /  will give:
(A) H 2 C  CH 2
(B) HC  CH
(C) HCHO

(D) C HCl

6. Product (P) of the reaction is:

CH3
Ph Br Zn / 

C 2 H 5 OH

Ph Br

CH3
C6H 5 C 6 H5

(A) C C
CH
3 CH3
C6H 5 CH3
(B) C C
C6H 5 CH3
C 6H 5 CH3
(C) C C
CH
3 C6 H 5
(D) All of these

7. In the reaction sequence:

Cl2 /hv
C6 H5  CH 3    X HOH/ NaOH
 Y
 Small  monochlorinated
compound

[X] and  Y  will respectively be:

(A) C6 H 5  CH 2 Cl and C6 H 5  CH 2 OH
(B) C6 H 5  CHCl2 and C6 H 5  CHO
(C) C6 H 5  CCl3 and C6 H 5 COOH
(D) C6 H5 CCl3 and C6 H 5 COONa

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8. In the given reaction:
CH2OH
COOH 110o C [Intermediate compound]
 CHOH  
COOH (P)
CH2OH

HCOOH  CO 2  glycerol
The intermediate compound (P) is:
(A) CH 2 CH  CH 2OH
CH2 O C O
(B) CH O C O
CH2OH
O O
(C) CH2 O C C OH
CHOH
CHOH
(D) Both (B) and (C)

9. In the given reaction:

Moist Ag 2 O
CH 3  CH 2  Br    X
[X] will be:
(A) Ethanol
(B) Diethyl ether
(C) Propane
(D) Propyne

10. In which reaction, the major product is primary–alcohol?

(A)

(B)

(C)

(D) All of these

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11. Propanal can be converted into 1–propanol by:
(A) KMnO 4 / H  / 

(B) KMnO 4 / O H / 

(C) NH 2  NH 2 / O H / 
(D) NaBH 4 , H 2O

12. Which of the following alcohols will give carboxylic acid and iodoform on oxidation with NaOI?
(A) 2–Propanol
(B) 3–Hexnol
(C) Cyclopentanol
(D) Cyclohexanol

13. In the given reaction;

HF/BF3 / 
C6 H5 N 2Cl   X
[X] will be:
 
(A) C 6 H 5  N  N BF4
(B) C6 H 5  F
(C) C6 H 5  Cl
(D) C6 H5  H

14. Which of the following gem diols is stable?

(A)

OH
(B) C2H 5 C H
OH

(C)

(D)

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15. In the given reaction

[P] is:

(A)

(B)

(C) H3C O CH2 CH3

(D) H3 C S CH2 CH3

16. Which of the following gives colour with phenolic compounds?

(A) Alcoholic FeCl3
(B) Cerric ammonium nitrate
(C) HgCl2
(D) Hg  OCOCH3  2

17. Phenolphthalein is obtained by condensation between:

(A) Phenol and succinic acid
(B) Phenol and phthalic anhydride
(C) Phenol and succinic anhydride
(D) Phenol and benzaldehyde

18. In the reaction sequence,

[X] will be:

(A) CH 3  CHOH  CH 3
(B) CH 3  CH 2  CHOH  CH 3

(C)

(D) CH 3  CH 2  CH 2  OH

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19. Glycerol forms Acrolein on heating with:
(A) Anhy. ZnCl2
(B) Conc.H 2SO 4
(C) Anhy. AlCl3
(D) H 3 PO 4

20. The given reaction,

OH O

K2S2O8/OH

O
is known as:
(A) Elbs persulfate oxidation
(B) Elbe reduction
(C) Houben–Hoesch reaction
(D) Air oxidation

NUMERICAL VALUE TYPE

This section contains 10 questions. Attempt any 5 questions out of 10. Each question is
numerical value type. For each question, enter the correct numerical value (in decimal notation
(e.g. 6.25, 7.00, 7, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.

21. Number of moles of periodate consumed by the glycerol in periodate reaction is:

22. Consider the following

CH3COCl
Hydroxy compound 
Py
 Acetyl derivative
MW  152 MW  362
Number of hydroxyl groups in the reactant is:

23. Number of alkenes formed in the given reaction is:

CH3 OH
Conc.H2SO4
CH3 C CH CH2 CH3
CH3

24. Number of nitro groups present in RDX is

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25. Number of compounds which can give SN2 reaction in the presence of polar aproetic solvents is:

(I)
(II) CH3  I
(III)

(IV)

(V)

(VI) C6 H 5  CH 2  Br

26. Number of possible cupling products in given reaction are:

Na
CH 3  CH 2  Br  CH 3  CH 2  CH 2  Br 
dnyether

27. How many moles of ‘HI’ will react with

28. Total number of atoms in 18–crown–6 is:

29. ?
R  CH 2  OH   R  CH 2  Cl
Find out number of reagents that can be used for above conversion, from following.
HCl ZnCl 2 , PCl3 , PCl5 , POCl3 ,SOCl2 , NaCl, TsCl

30. How many compounds A through G are enol tautomers of 2–butanone.

OH
OH
(A) (B)

OH OH
(C) (D)

OH
(E) OH (F)

(G) OH

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