Halides, Alcohols, Ethers Topics Question SET

(b) Assuming no temperature change and
atmospheric pressure to be Po, find the Where DP is pressure difference at the two ends of
surface tension of the soap solution. the tube and h is coefficient of viscosity. Assume
Q.23. In the last problem, one of the bubbles supplies Vidyamandir Classes
Vidyamandir Classes that the bubble remains spherical.
its entire air to the other bubble and a film of soap Q.27. Two blocks are floating in water. When they are
solution is formed at the end of the straw which brought sufficiently close they are attracted to
keeps it closed. What is the radius of curvature each other due to surface tension effects. When
of this film if the bigger bubble has grown in size the experiment is repeated after replacing water
and its radius/ AKOLA
MUMBAI has become / DELHI
R3. / KOLKATA / GHAZIABAD / NASHIK
with mercury,/ GOAonce /again
BOKARO / PUNE
the two blocks are
IIT – JEE: 2022 CRASH COURSE (ADV) DATE: 29/12/21
attracted. Explain the phenomena. It is given that
een the TIME:
LeveL 3 2 Hr.
Mathematics
Halides, Properties
Alcohols,
TOPIC:
Part of
ALKYL Matter
Test
Ethers
&
|Question
- 4ARYL JEEHALLIDE
Topics SETthe
Advanced-2020
Question
water wets 2 SETmaterial of MARKS:
the block 120 where as
at point mercury does not.
Matrices & Determinants, ALCOHOL
Film of soap ETHERS & PHENOLS
Probability, Vectors & 3D-Geomatry
Q.1:
Q.24. Consider a rain drop falling at terminal solution
speed. For Q.5:
Q.28. A long thin string has a coat of water on it. The
r2 = r. what radius (R) of the TIME drop can we disregard the radius of the water
: 236cylinder is r. After some time
terface
SINGLE
: 3 hrs
influence of gravity on its shape? Surface tension
CORRECT ANSWER TYPE
M.M.
it was found that the string had a series of equally
Thisand
section R3 contains
density of water 15
are Tmultiple
and r choice
respectively. questions.
Read the following Instructions very carefully Each question
spacedbefore hasyou
identical 4 options
water (A), on
drops
proceed. (B),it.(C)Find
andthe
sts and (D) for its answer, out of which
Q.25. A soap bubble has radius R and thickness of its
Q.2: ONLY ONE option can be correct.
minimum distance between two successive drops.
le find Marking
wall is scheme:
1. a. Calculate+4
This question thefor
paper
correct
consists
apparent of 3
answer,(= true0 if not
sections
weight (Section I,
attempted
Section
Q.29.
Q.6: A liquid and
II & Section III).
having –1surface
in alltension
other Tcases.
and density r
en that weight - Buoyancy) of the bubble if surface
2. Section I contains 3 types of questions [Type 1, Type 2 & is in contact with a vertical solid wall. The liquid
Type 3]
R and 1. tension
How of soap
many solution
products and its density
are obtained are T and
in the Type
givenQuestions. surface
reaction:Each gets curved as shown in the figure. At the
Type 1 contains 10 Single Correct Answer question has 4 choices (A), (B), (C) and (D), V
d respectively. The atmospheric pressure is P0 bottom the liquid surface is flat.
out of which ONLY ONE CHOICE is correct.
and density of atmospheric air is r0. By assuming The atmospheric pressure is Panswer]
 Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong o.
a = 10–6 m, R = 10 cm, P0 = 105 Nm–2, r0 = 1.2
kg m–3, Type
d = 10 3
kg m–3,20T Multiple
2 contains = 0.04 Nm –1
; show
Correct that Type Questions. Each question
Answer A has 4 choices (A), (B), (C) and
the weight of the bubble is mainly because
(D), out of which ONE OR MORE CHOICES may be correct. of
h
water inthe skin. What scheme
Marking is weight of the for
[4 Marks bubble?
All Correct answers & –1 NEGATIVE MARKING for wrong answer]
Q.26. A soap Type
Q.3: bubble is blown at the end of a capillary
(A) 1 3 contains FIVE paragraphs. Based on these paragraphs, there are TEN questions. Each question has
tube of radius a and length L. When the other end
R1) are (B)open,
2 options
FOUR (A), (B), (C) and (D). ONLY ONE of these four options is correct.
is left the bubble begins to deflate. Write
bble to (C)3 of the Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
the radius bubble as a function of time if
mains.
(D)Section
the initial
3. 4 radius of the bubble
II contains wasInteger
16 Single R0. Surface
Value Type Questions. (i) The
Findanswer
the pressure
to eachin of
thethe
liquid at the top
questions is aof the
tensionsingle-digit
of soap solution is T. Itfrom
integer, ranging is known that inclusive).
0 to 9 (both meniscus (i.e. at A)
volumeflow rate through
Marking a tube
scheme of radius
[4 Marks a and answer & NO (ii)
for Correct Calculate
NEGATIVE the difference
MARKING for wronginanswer]
height (h) between
length L is given by Poiseuille’s equation- thequestion
bottom and top ofstatements
the meniscus.
4. Section III contains 4 Match the columns type questions. Each contains given in
p a 4 DP
Q = 2 columns. Statements in the first column have to Q.7:
Q.30. Is it with
be matched possible that water
statements evaporates
in the second column.from a
h L answers to these questions have to be appropriately bubbled
8The spherical
in thedrop of water
answer sheet.just by means of surface
energy supplying the necessary latent heat of
2. TheClaisen rearrangement
Marking scheme [8ofMarks if you darken ALL the bubblesgives
corresponding ONLY to the correct
vaporisation? The drop does not use its internal
L
answer or given 2 MarksReach for correct bubbling of answer in any row. No Negative mark will be
2a
0
thermal energy and does not receive any heat
given for an incorrectly bubbled answer]
from outside. It is known that water drops of
ut ? 5. For answering a question, an ANSWER SHEET (OMR SHEET) size less than 10–6separately.
is provided m do not exist.
PleaseLatent heat of
fill your Q.32. A
Test Code, Roll No. and Group Properly in the space given invaporisation
the ANSWER of water is L = 2.3 × 106 Jkg–1 and
SHEET. a
e and i
surface tension is T = 0.07 Nm–1.
nd the Where DP is pressure difference at the two ends of t
(A) and h is coefficient of viscosity. Assume
the tube Q.31. In the arrangement shown in the figure, A is a jar
Q.8:
t
that the bubble remains spherical. half filled with water and half filled with air. It
upplies
is fitted with a leak proof cork. A tube connects
of soap Q.4:
Q.27. Two blocks are floating in water. When they are
it to a water vessel B. Another narrow tube
which brought sufficiently close they are attracted to
fitted to A connects it to a narrow tube C via
rvature each other due to surface tension effects. When
a water monometer M. The tip of the tube C is
in size the experiment is repeated after replacing water
just touching the surface of a liquid L. Valve V
with mercury, once again the two blocks are
is opened at time t = 0 and water from vessel B
attracted. Explain the phenomena. It is given that
pours down slowly and uniformly into the jar A.
water wets the material of the block where as
An air bubble develops PartatTest-4
the tip| JEE-2020
of tube C. The
mercury does not.
VMC | Mathematics 1
Q.33. A
cross sectional radius of tube C is r and density of
Q.28. A long thin string has a coat of water on it. The water is r. The difference in height of water (h) in c
VMC radius
| Physics Assignment
of the water cylinder is r. After some time 1
the two arms of the manometer variesPhysiCs with time i
CENTERS : M UMBAI / DELHI /A KOLA /K OLKATA
it was found that the string had a series of equally /N ASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI # 1 d
't' as shown in the graph. Find the surface tension
spaced identical water drops on it. Find the of the liquid L. t
minimum distance between two successive drops. t
(B)
(C)
(D)
3. The reaction of RCHO with 2 eq. of PhOH in acidic medium gives
(A)
(B)
(C)
CENTERS: MUMBAI / DELHI /AKOLA /KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI # 2
(D)
4. In the given reaction,
The product ‘Y’ is

(A) A positional isomer of X
(B) Identical to X
(C) Chain isomer of X
(D) An oxidation product of X.
5.
(A)
(B)
(C)
(D)
6. The insecticide chlordane is warmed with dilute NaOH solution for some time. The expected product
would be:
(A)
(B)
(C)
(D)

H
7. CH 3  CH 2OH  CH
2 C
 O  ?
(A) CH 3  O  CH 2  C  CH 3
||
O
(B) CH 3  CH 2  C O  CH3
||
O
(C) CH3  O  CH 2  CH 2  C  H
||
O
(D) CH 3  CH 2  O  C  CH 3
||
O
8. Dehydrohalogenation by a strong base is slowest in.
(A)
(B)
(C)
(D)
9. Which of the following statements is not correct?

(A) Phenol reacts with CCl4 in the presence of NaOH solution at 70 C to give salicyclic acid.
(B) Phenol reacts with phthalic anhydride in the presence of concentrated H 2SO 4 forming
Phenolphthalein which is used as acid-base indicator.
(C) Phenol on exposure to air produces a red coloured product known as phenoquinone.
(D) The treatment of concentrated H 2SO 4 at 15  20 C with phenol produces p  phenolsulphonic
acid whereas at 100 C , o- phenolsulphonic acid is produced.
10.
(A)
(B)
(C)
(D)
11. The major product of the following reaction is
(A)
(B)
(C)
(D)
12. In the given reaction:

 *
HOH
CH 3  CH 2  S C H 2  CH 2 Br  X

[X] will be:

*
(A) CH 3  CH 2  S  C H 2  CH 2  OH
*
(B) CH 3  CH 2  S  CH 2  C H 2  OH
(C) 1:1 mixture of (A) and (B)
(D) 2:1 mixture of (A) and (B)
13. In the given reaction
(A)
(B)
(C)
(D)
14. What is product of the following reaction?
(A)
(B)
(C)
(D) None of these
15. Major product of the following reaction is ……..
(B)
(C)
(D)
MULTIPLE CORRECT ANSWER(S) TYPE

This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO
incorrect option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C)and (D)are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A)and (D)will result in +2marks; and
darkening (A)and (B)will result in –2 marks, as a wrong option is also darkened.
16. Which order is correct:
(A) Nuecleophilicity  In DMSO 
(B) Leaving group tendency:
(C) Rate of reaction (Electrophilic addition reaction):
(D) Rate of reaction(Dehydration):
17. Which of the following statements are not correct?

(A) Sulphonation of phenol at low temperature is rate-controlled to give o  HOC6 H 4SO3H
(B) Sulphonation of phenol at higher temperaures is thermodynamically controlled to give
o  HOC6 H 4SO3 H .
(C) The  OH is more activating than O towards aromatic electrophilic substitution reactions.
(D)Bromination of phenol in aqueous medium gives monobrominated phenol while in nonaqueous
medium, tribrominated phenol is formed.
18. Consider the structure of given alcohol:
The alcohol can be prepared from:

O
||
(A) C6 H 5  C  CH 3 andC 2 H 5 MgBr
O
||
(B) CH3  CH 2  C  CH 3 andC 6 H5 MgBr
(C)
(D)
19.
(A)
(B)
(C)
(D)
20.
(A) E is CH 3CH 2 CH 2OH
(B) D is CH 3  CH 
CH 2
(C) B is CH 3CH 2  Cl
(D)
21. Which of following will give syn- elimination

(A) CH 3CH 2 CH 2  OCOCH 3
(B)
(C)
(D)
22. An optically active compound(A) reacts with NaBr  H 2SO 4 Solution & gives an optically inactive
compound(B). A on reaction with CrO3 / aq . Acetone gives a chiral compound C  C9 H10O 2  . C on
reaction with moist Ag 2O followed by treatment with Br2 / CCl4 solution gives D, a lower
homologue of B. A on heating with alkaline KMnO 4 produces E  C7 H 6O2  .A,C & E all liberate a
Colourless & odoulrless gas with Na metal. A does not respond to iodoform test. A on controlled
oxidation with CrO3  pyridine produces a chiral compound F. Identify the correct options.
(A)
(B)
(C) E is C6 H 5  CHO
(D)
23. An organic compound x C5 H12O gives effervescence with NaH. X on treatment with acidic CrO 3
solution turns solution to blue – green forming C5H10 O2 . Also X can be resolved into enantiomers.
The correct statement regarding X is
(A) It is 2-pentanol
(B) It is 3- pentanol
(C) With HBr, it gives achiral alkylbromide
(D) The oxidation product C5H10O 2 is achiral
24. Consider the following solvolysis reaction.
The expected product(s) is/are
(A)
(B)
(C)
(D)
25. In which of the following reactions D-exchange will take place?
(A)
(B)
(C)
(D)
26. CH
 2
PhH/HF
CH  CH 2  OH I
H 2 / Pt
A  II
B
NBS H 2 O,acetone MnO2

III
 C  IV
D 
v
E
Which of the following statements is/are correct
(A) ‘B’ gives total 5 monochloro products on photochemical chlorination
(B) ‘E’ gives positive test with NaOI
(C) ‘D’ gives instant turbility with HC  ZnCl 2
(D) Ist step is electrophilic substitution reaction.
27.
Which of the following statements is/are correct about the above reaction?
(A) Product shows geometrical isomerism
(B) Product shows colour due to extended conjugation
(C) Electrophile attack at para position due to large size
(D) Carbocation form as intermediate
28.
(A)
(B) CH3  O  H
(C)
(D) HO
29. An optically active compound A  C8 H17 Br  on heating with alcoholic KOH produces B  C8 H16  as
the major product. B reacts with NBS (N- Bromo succinimide) and produces C  C8 H15 Br  , another
optically active compound. Further dehydrobromination of C produces D  C8 H14  . When D is
treated with one mole of Bromine at 40  50 C , it forms an optically inactive dibromide
E  C8 H14 Br2  as the major product (80%). When E is added to an ethereal solution containing
magnesium F  C8 H14 Mg 2 Br2  is obtained. To this solution 1 mole of Ethyl acetate is added slowly
and finally the product is hydrolysed and identified as given below. Identify correct option(s).
(A)
(B)
(C)
(D)
30. Compound A  C7 H11Br  reacts with Mg in ether to give B. To this solution acetaone (propanone) is
added slowly. When this solution is added to water a product C  C10 H18O  is obtained. C on heating
with conc. H 2SO 4 gives D  C10 H 16  . D on catalytic hydrogenation gives 2-
methylpropylcyclohexane (isobutylcyclohexane). If B is treated with water the product is E  C7 H12 
which on ozonolysis produces 6-oxoheptanal. Identify the correct options.
(A)
(B)
(C)
(D)
NUMERICAL VALUE TYPE

This section contains 10 questions. Each question is numerical value type. For each question, enter
the correct numerical value (in decimal notation, truncated/rounded-off to second decimal
place. (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
31. Total possible elimination products are
32. How many of following reaction gives Hoffmann product as a major product?
33. How many of the following compounds given below have faster aromatic nucleophilic substitution
rate than
34. Number of moles of HIO4 that will react with following compound is x and y moles of HCOOH are
xy
formed then value is________
2
35. How many of the following produces a characterstic coloration/ ppt with neutral FeCl3 ?
36. In Zeisel’s method for the determination of methoxyl groups a sample of 2.68 gm of a compound (A)
gave 14.08 gm of AgI. If the molecular weight of compound (A) is 134, the number of  OCH 3 
group(s) in the compound (A) is:
37.
Total number of organic products formed(major, minor all)
38.
x HI
 value of x is
Cl 2

hv
7 39. Consider only monochloro product. Find no. of enantiomeric pair.
Cl2 / h Zn/ 
40. Cycloalkane 
excess
 C5Cl10   Polychlocyclopentadiene
 end product 
Write the number of chlorine (Cl) atom present in the end product.

Halides, Alcohols, Ethers Topics Question SET

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Halides, Alcohols, Ethers Topics Question SET

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(b) Assuming no temperature change and

3. The reaction of RCHO with 2 eq. of PhOH in acidic medium gives

4. In the given reaction,

The product ‘Y’ is

8. Dehydrohalogenation by a strong base is slowest in.

9. Which of the following statements is not correct?

11. The major product of the following reaction is

12. In the given reaction:

[X] will be:

13. In the given reaction

14. What is product of the following reaction?

(D) None of these

15. Major product of the following reaction is ……..

MULTIPLE CORRECT ANSWER(S) TYPE

16. Which order is correct:

(A) Nuecleophilicity  In DMSO 

(B) Leaving group tendency:

(C) Rate of reaction (Electrophilic addition reaction):

17. Which of the following statements are not correct?

18. Consider the structure of given alcohol:

The alcohol can be prepared from:

21. Which of following will give syn- elimination

24. Consider the following solvolysis reaction.

The expected product(s) is/are

25. In which of the following reactions D-exchange will take place?

NUMERICAL VALUE TYPE

31. Total possible elimination products are

7 39. Consider only monochloro product. Find no. of enantiomeric pair.

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