M.

Prakash Institute
STD XII
Paper-2

Test-84 Advance All Batches 18/12/2022

Marking Scheme

Sec 1: 6 questions Multiple answer Correct 4, 1, -2 ( 1 for Partial Marking)

Sec 2: 4 questions Single correct 3, -1

Sec 2: 8 questions Numerical Type 4, 0

Syllabus

Physics Chemistry Maths

12th std. Advance Paper 2 Date: 18/12/2022.
Physics
Section I - Multiple Option Correct - 6 questions

1. A plane spiral made of stiff smooth wire is rotated with a constant angular velocity
ω in a horizontal plane about the fixed vertical axis O. A small sleeve M slides along
that spiral without friction. Find its velocity v ′ relative to the spiral as a function
of the distance ρ from the rotation axis O (The initial velocity of the sleeve is equal
to v0 )

s
q (ρ2 ω 2 ) v0 2 + ρ2 ω 2
(A) v02 + ρ2 ω 2 (B) v02 + (C) v0 + ρω (D)
2 2
2. A point object O is at a distance x from a converging lens of focal length 10 cm as
shown. x can be changed:

(A) The minimum distance between O & it’s real image is 40 cm.
(B) The maximum angle of deviation for any ray 0.05rad approx.
(C) The minimum angle of deviation for any ray is 0rad.
(D) The maximum half angle of the cone made by refracted converging beam is
0.05 rad approx.

3. Charge is uniformly distributed on the curved surface of hemisphere. Potential at

P, Q and T is V, V ′ and V” respectively :-

(A) V < V ′ < 2V (B) 0 < V ′′ < V (C) V′ > V > V′′ (D) V′ = V′′ = V

1
4. Charges Q1 and Q2 lie inside and outside respectively of a closed surface S. Let E
be the field at any point on S and ϕ be the total flux of E over S.
(A) If Q1 changes, both E and ϕ may change.
(B) If Q2 changes E may change but ϕ will not change.
(C) If Q1 = 0 and Q2 ̸= 0 then E ̸= 0 but ϕ = 0.
(D) If Q1 ̸= 0 and Q2 = 0 then E ̸= 0 but ϕ = 0.

5. Line BA & BC are intersecting at ’B’ making angle π/3 at ’B’. Point A & C are at
large distance from point B. An infinite wire carrying current ‘i’ is kept perpendicular
to plane containing line BA & BC and intersect the plane at point ‘ P ’. Current in
R→ − → −
the wire is into the plane of paper as shown in figure. Then B · dℓ will be equal
to:

µ0 i µ0 i
(A) − on line ABC (B) on line ABC
6 6
2 5
(C) µ0 i on line AB (D) µ0 i on line AB
3 12
6. Magnetic field exist in a cylindrical region of radius ‘R’ and centre ‘O’ as shown in
figure. A conducting rod P Q of length ‘a’ is kept in the field as shown in figure.
OPQR forms a square of side ‘a’. Magnetic field in the region is dB changing at the
dB
rate = α(α > 0). Then
dt

Z Q
→
− →
− −a2 α
(A) Line integral E ind · dℓ =
p 2
a2 α
(B) Potential difference between P &Q is
2
Z Q 2
(C) Line integral E ⃗ =aα
⃗ ind · dℓ
R 2
a2 α
(D) Potential difference between Q&R is
2

2
 Section II - Single Option correct - 4 questions
7. A current source is connected to the circuit shown in figure in order to charge
the capacitors having equal capacitances. List-I contains terminals across which
connection is made. List-II contains the capacitors which cannot get charge.

List-I List-II
(P) A and C (1) Capacitor 1
(Q) B and C (2) Capacitor 2
(R) C and D (3) Capacitor 3
(S) B and D (4) Capacitor 4
(5) Capacitor 5
(6) Capacitor 6
(A) P → 6; Q → 4; R → 1; S → 3 (B) P → 6; Q → 2; R → 1; S → 3
(C) P → 6; Q → 2; R → 4; S → 3 (D) P → 5; Q → 1; R → 2; S → 3

8. In a vessel, radioactive material A is placed at t = 0, which disintegrate into B and

which further disintegrate into C which is stable. In another vessel a radioactive
material D (at t = 0, D is zero) is produced at a constant rate which dissociate
into E. List-I shows variation of quantity with time where as List-II gives some
quantities. Match the following.

(A) P → 3; Q → 5; R → 4; S → 2 (B) P → 3; Q → 5; R → 1, 5; S → 1
(C) P → 3; Q → 4; R → 1; S → 2 (D) P → 3; Q → 4; R → 1, 5; S → 2

3
9. In a YDSE setup, light of wavelength of light 4000Å is used. Distance of screen from
the slits is 2 m and distance between the slits is 1 mm. There are four slabs, slab
1 (thickness 2 mm, refractive index 2), slab 2 (thickness 1 mm, refractive index 3),
slab 3 (thickness 4 mm, refractive index 3/2 ) and slab 4 (thickness 3 mm, refractive
index 5/3)

List-I List-II
(P) If slab 1 is placed in front of slit S1 . (1) Central maxima is at C.
(Q) If slab 2 is placed in front of slit S2 along (2) Central maxima is above C.
with condition (P).
(R) If slab 3 is placed behind slit S2 along with (3) Central maxima is below C
condition (Q).
(S) If slab 4 is placed begind slit S1 along with (4) Fringe width remains unchanged
condition ( R).
(5) No. of fringes crossing the central
max as a result of slab
placing is 5000
(A) P → 3, 4, 5; Q → 1, 4; R → 4, 5; S → 1, 4, 5
(B) P → 2, 4, 5; Q → 1, 4, 5; R → 3, 4, 5; S → 1, 4, 5
(C) P → 2, 4, 5; Q → 3, 4; R → 1, 4, 5; S → 2, 4, 5
(D) P → 1, 4, 5; Q → 1, 5; R → 3, 5; S → 2, 4, 5

4
10. In each situation of List-I a process ABC is given for an ideal gas. Match each
situation of List-I with correct option in List-II

(A) P → 1, 2; Q → 3, 4; R → 1, 2; S → 2, 5
(B) P → 2, 4; Q → 1, 4; R → 3, 4; S → 1, 5
(C) P → 1, 2, 5; Q → 3, 5; R → 1, 2; S → 2, 5
(D) P → 4, 5; Q → 1, 5; R → 3, 5; S → 1, 4

5
 Section III - Numerical - 8 questions
11. A rod of mass 1gm lies on smooth parallel rails which are connected by a charged
capacitor at the end. Uniform magnetic field of 4 T is perpendicular to the plane
of the rails everywhere. The initial velocity of rod is 0 . What is the velocity (in
m/s ) of rod in steady state? Take C = 10µF & initial voltage = 100 V. There is
no resistance anywhere.

12. When nuclear motion is considered, the Rydberg’s constant of Hydrogen atom (RH )
is different from the Rydberg’s constant for Bohr atom (R∞ ).
R∞ − RH
What is the value of × 104 (in nearest integer). Take mass of electron =
R∞
mass of proton /1800.

13. An object is hanged from ceiling with help of two light strings A & B. Object stays
in equilibrium with tension in string A & B equal to 40 N and 30 N respectively.
Now the object is pulled by a constant horizontal force F = 120 N perpendicular to
initial plane of object and two strings. If object stays at rest in equilibrium then
tension in string B (in newton) (g = 10 m/s2 )

14. A real cell of emf 20 V is connected across a resistor of resistance R. A voltmeter of

varying resistance (rv ) is connected across resistance to measure the potential drop
across the resistor. Variation of potential drop against rv is as shown in figure. Thus
value of R will be (in ohm)

15. A travelling microscope is used to measure the refractive index of a glass slab.
The microscope is focused on a spot on the table and the reading of microscope is
10.08 cm. Now the glass slab is put on the spot & microscope is raised to focus
on the apparent position of spot. The reading is 12.48 cm. Now the microscope is
raised further to focus on the top of the slab. The reading is 14.88 cm. If the least
count of scale is 0.01 cm, what is the % error in refractive index?

6
16. A rod of mass m and length L(= 50/3 m) is hinged in plank of same mass m. The
plank is kept at the corner of a smooth table and rod makes θ with the vertical.
The system is released from the θ = 0◦ . Find the velocity ( in m/s) of plank when
the rod makes the θ = 180◦ · (g = 10 m/s2 )

17. Assume that sun radiates like a black body with surface temperature at Ts = 6000 K
and earth absorbs radiations coming from sun only. Both earth and sun are consid-
ered as perfect sphere with distance between centre of earth and centre of sun to be
200 times the radius of sun. Find the temperature (in Kelvin) of surface of earth in
steady state (assume, radiations incident on earth to be almost parallel)

18. A homogeneous aluminium ball of radius r = 0.5 cm is suspended on a weightless

thread from an end of a homogeneous rod of mass M = 4.4 g. The rod is placed on
the edge of a container with water so that half of the ball is submerged in water when
the system is in equilibrium as shown. The densities ρal and ρw of aluminium and
water are 2.7 × 103 kg/m3 and 1 × 103 kg/m3 respectively. Determine the ratio y/x
of the parts of the rod to the brim, neglecting the surface tension on the boundaries
between the ball and water.

7
12th std. Advance Paper 2 Date: 18/12/2022.
Chemistry
Section I - Multiple Option correct - 6 questions
19. Which of the following statement(s) is(are) true about transition metal alkene ?
(A) Back bonding weakens the double bond of alkene
(B) σ-bonding and back-bonding synergistically strengthen metal-alkene interac-
tions
(C) Electron withdrawing substituent on alkene increases metal-alkene interaction
(D) π - acidic CO ligands on metal strengthen metal alkene back-bonding

20. During a negative β-decay

(A) An atomic electron is ejected.
N
 
(B) After β-emission ratio decreases
P
(C) A neutron in the nucleus decays emitting an electron.
(D) A part of the binding energy of the nucleus is converted into an electron.

21. Both compartments in the above diagram are large and contain ideal gas. The
initial conditions are mentioned in the diagram. Select the correct statement(s) for
the whole system.

(A) ∆S > 0 if TA > TB

(B) ∆S > 0 if TA < TB
(C) ∆S > 0 if TA = TB
(D) For overall system ∆U = 0 no matter that what is the relationship between TA
and TB

22. Consider the following reaction.

Among the following, the compound(s) whose osazone derivative(s) will have same
melting point as that of X is (are)

1
23. In which of the below pairs the first compound reacts faster than second towards
the reaction as mentioned in parenthesis

24. A nonvolatile solute ‘ X ’ completely dimerises in water, if the temperature is below

−3.72◦ C and the solute completely dissociates as X −→ Y + Z, if the temperature
is above 100.26◦ C. In between these temperatures, (including both temperatures) ‘
X ’ neither dissociates nor associates. One mole of ‘ X ’ is dissolved in 1Kg water.
(Given: Kb of water = 0.52 K Kg mol−1 , Kf of water = 1.86 K Kg mol−1 ) Which
of the following statement(s) is/are correct regarding the solution?
(A) The freezing point of the solution is −1.86◦ C.
(B) The boiling point of the solution is 101.04◦ C.
(C) When the solution is cooled to −7.44◦ C, 75% of water present initially will sep-
arate as ice.
(D) When the solution is heated to 102.08◦ C, 50% of water present initially will
escape out as vapors.

2
 Section II - Single Option Correct - 4 questions
25. Match the type of crystals given in list I with the appropriate relation involving
edge length (a), radius of cation (r+ ), radius of anion ( r− ) and arrangement given
in list II
List-I (Type of Crystal) √ List-II
(A) NaCl type crystal (P) √3a = 4 (r+ + r− )
(B) ZnS type crystal (Q) 3a = 2 (r+ + r− )
(C) CsCl type crystal (R) cation in tetrahedral void
(D) Na2 O type crystal (S) a = 2 (r+ + r− )
(A) A → S; B → P, R; C → Q; D → P, R
(B) A → P; B → P, R; C → S; D → Q, R
(C) A → Q; B → S, R; C → S; D → Q, R
(D) A → Q; B → S, R; C → S; D → P, R

26. Match the following

List-I (Electrolyte

which is electrolysed) List-II (Characteristics)
Naq
(A) NaCl (P) H2 liberates
(B) AgNO3 (aq) (Q) O2 liberates
(C) CuSO4 (aq) (R) pH increases
(D) H2 SO4 (aq) (S) pH decreases
(A) A → Q, S; B → P, R; C → P, R; D → Q, S
(B) A → P, R; B → Q, S; C → P, R; D → Q, S
(C) A → Q, S; B → P, R; C → Q, S; D → P, R
(D) A → P, R; B → Q, S; C → Q, S; D → P, Q

27. .

(A) A → T; B → T; C → S, T; D → P, Q (B) A → R; B → T; C → S; D → P
(C) A → S; B → T; C → S; D → P; Q (D) A → P; B → T; C → S, Q; D → P

3
28. Match the following

(A) A → T; B → T; C → S, T; D → P, Q
(B) A → R, S, T; B → T; C → R, S; D → P, Q
(C) A → R, T; B → P, R; C → Q; D → R, S, T
(D) A → T; B → P, R; C → Q, R, S; D → R, S, T

4
 Section III - Numerical - 8 questions
29. In 80% ethanol at 55◦ C, isopropyl bromide reacts with hydroxide)ion according to the
d[RX] n  h i
following kinetics − = 4.7 × 10−5 M−1 s−1 [RX] OH− +{2.4 × 10−6 s−1 [RX]}
dt
What percentage of isopropyl bromide reacts by the SN 2 mechanim when
[OH] = 0.01 M. Give answer as the closest integer.

30. Solid AgNO3 is slowly added to a solution that is 0.02 M in Cl− ions and
−
0.02 Min Br ions. What % percent of Br− remains in the solution when AgCl starts
precipitating ?
Given Ksp AgCl = 1.6 × 10−10 , Ksp of AgBr = 8 × 10−13

31. The percentage void space per unit volume of unit cell in zinc blende structure is
(Give answer as the closest integer.):

32. One gram of commercial AgNO3 is dissolved in 50 mL of water. It is treated with

50 mL of a KI solution. The silver iodide thus precipitated is filtered off. Excess
of KI in the filtrate is titrated with M/10KIO3 solution in presence of 6 MHCl till
all Γ ions are converted into ICl. It requires 50 mL of M/10KIO3 solution. Twenty
millilitres of the same stock solution of KI requires 30 mL of M/10KIO3 under sim-
ilar conditions. Calculate the percentage of AgNO3 in the sample.
(Reaction: KIO3 + 2KI + 6HCl → 3ICl + 3KCl + 3H2 O )

33. The coagulation of 10 cm3 of Gold solution by 1ml10%NaCl solution is completely

prevented by addition of 0.25 g of starch to it. The gold number of starch is

34. An undergraduate student heated 1-cyclopentylethyl ethanoate at 300◦ C to obtain

an unsaturated hydrocarbon ‘ K ’ which was then treated with mercuric acetate
followed by water then sodium borohydride to give ‘ L ’ which is dehydrated by
conc. H2 SO4 at 180◦ C to give ‘ M ’ as one of products. What is the molecular mass
of compound ‘M’ ?

35. 3-Amino-2,3-dimethyl butan-2-ol when treated with NaNO2 /HCl gives product (x).
(x) on treatment with LiAlH4 forms (Y). ’Y’ on heating with conc. H2 SO4 forms
M.M · z
(z). Give your answer as Where M.M. z is Molar mass of z, M.M. x is
M.M · x
molar mass of x.

36. Find sum of the unpaired electrons in S2 , atomic Phosphorus, FeSO4 ·7H2 O, NO, B2 , CaC2 ,
[Ni (NH3 )6 ] SO4

5
12th std. Advance Paper 2 Date: 18/12/2022.
Maths
Section I - Multiple Option Correct - 6 questions
Z 1  
37. Let f (x) = x + x − tx2 f (t)dt. Then which of the following alternative(s)
−1
is/are correct?
−1
 
(A) lim f (x) = 2 (B) f 0 =1
x→0 3
(C) f is continuous and derivable on R. (D) maximum value of f (x) does not exist.

38. Let u : ax2 + bx + c = 0

v : dx2 + ex + f = 0
w : gx2 + hx + i = 0
are the quadratic equations in x.
Consider a quadratic equation in y as
E : uy 2 + vy + w = 0
Which of the following alternative(s) is/are correct?
(A) If for some value of x say x = x1 , the equation E = 0 has one root infinite and
other root a non zero finite quantity then u = 0 and v = 0 will have a common root.
(B) If for some value of x say x = x2 , the equation E = 0 has both root infinite
then u = 0 and v = 0 will have a common root.
(C) If for some value of x say x = x3 , the equation E = 0 becomes an identity in y
then u = 0, v = 0 and w = 0 must have a root, common to all of them.
(D) If for some value of x say x = x4 , the equation E = 0 has both roots real and
distinct then v = 0 and w = 0 must have a common root.

d2 y
!
39. For the curve ax2 + by 2 = c, y 3 + 4 = 0, then the equation ax2 + 4bx + c = 0
dx2
will have
(A) imaginary roots (B) real and unequal roots
(C) real and equal roots (D) both roots infinite

40. Let f(x) = sin x + ax + b. Then f(x) = 0 has

(A) only one real root which is positive if a > 1, b < 0
(B) only one real root which is negative if a > 1, b > 0
(C) only one real root which is negative if a < −1, b < 0
(D) only one real root which is positive if a < −1, b < 0

41. Let f : R → [−1, 1] be defined as f(x) = cos(sin x) then which of the following is(are)
correct?
(A) f is periodic with fundamental period 2π
(B) Range of f = [cos 1, 1]
π π
    
(C) limπ f −x +f +x =2
x→ 2 2 2
(D) f is neither even nor odd function

1
 2 2
42. The area of the region in the
√ first quadrant enclosed by the circle x + y = 4, the
x-axis and the line y = x/ 3 is :
π π π
(A) (B) (C) (D) 1
2 3 4

Section II - Single Option correct - 4 questions

43. .

List-I List-II
(P) There are n distinct white and n
distinct black balls. If the number of ways (1) 2
of arranging them in a row so that neighbouring
balls are of different
colours is 1152 then ‘ n ’ equals (2) 3
(Q) If a, b ∈ R such that a + b = 1 and (1 − 2 ab) (a3 + b3 ) = 12. (3) 4
The value of (a2 + b2 ) is equal to
(R) Suppose that z is a complex number that
satisfies |z − 2 − 2i| ≤ 1. (4) 5
The maximum value of |2iz + 4| is equal to
(S) Number of solutions of the equation (5) 6
log2 (sin x) + log3 (tan x) = log4 (cos2 x) + log5 (cot x) in (−2π, 2π), is Which of the
following is true?
(A) P → 3; Q → 5; R → 2; S → 1 (B) P → 3; Q → 2; R → 5; S → 1
(C) P → 3; Q → 2; R → 5; S → 3 (D) P → 3; Q → 2; R → 1; S → 3

44. .
List-I List-II
+
(P) Let f : R → {−1, 0, 1} defined by (1) Into
f(x) = sgn (x − x4 + x7 − x8 − 1)
where sgn denotes signum function,
then f(x) is
(Q) Let f : R → R and satisfies (2) One-one
f (x) + xf (−x) = x + 1, then f (x) √is
(R) Let f : [0, 4] → [0, 9] defined by f (x) = 6x − x2 , (3) Many-one
then f (x) is
(S) Let f : [0, 3] → [2, 8] defined by (4) Even then f (x) is
f (x) = 2|x−1|+|x−2| ,
(5) Onto
Which of the following can be true ?
(A) P → 1; Q → 1; R → 3; S → 5 (B) P → 1; Q → 2; R → 3; S → 5
(C) P → 3; Q → 2; R → 4; S → 5 (D) P → 3; Q → 3; R → 1; S → 2

2
45. .
List-I List-II
(A) A is a real skew symmetric matrix such that (p)
2
A + I = 0.BA − AB Then
(B) A is a matrix such that (q) A is of even order then
2 n
A = A. If (I + A) = I + λA,
λ equals (n ∈ N )
(C) If for a matrix A, A2 = A, (r) A
and B = I − A,
then AB + BA + I − (I − A)2 equals
(D) A is a matrix with complex entries (s) 2n − 1
and A∗ stands for transpose of
complex conjugate of A If A∗ = A.
B ∗ = B, then (AB − BA)∗ equals
(t) n C1 + n C2 . . . . + n Cn
Which of the following can be true ?
(A)A − q, B − r, C − p, B − s
(B)A − q, B − s, C − r, D − p
(C)A − s, B − r, C − p, D − q
(D)A − p, B−, C − s, D − q

46. .
List-I List-II
(A) The area of the triangle whose vertices (p) 0
are the points with ractangular cartesian
coordinates (1, 2, 3), (−2, 1, −4), (3, 4, −2) is
(B) The value of (q) 28
~ ~ ~
(~a × b) · (~c × d) + (b × ~c) · (~a × d)~ + (~c × ~a) · (~b × d)
~ is
(C) A square PQRS of side length P is folded along the (r) 2
diagonal P R so that the point Q reaches at Q0 and
planes PRQ0 and PRS are perpendicular
to one another, the shortest distance between PQ0 and PS
kP
is √ 6
, then k =
√
(D) ~a = 2î + 3ĵ − k̂, ~b = −î + 2ĵ − 4k̂, ~c = î + ĵ + k̂ and (s) 1218
2
d~ = 3î + 2ĵ + k̂ then (~a × ~b) · (~c × d)
~ =
(t) 21
Which of the following can be true ?
(A) A − p, B − q, C − r, D − S
(B)A − r, B − s, C − q, D − p
(C) A − r, B − p, C − r, D − s
(D) A − q, B − p, C − s, D − r

3
 Section III - Numerical - 8 questions
47. Find the length of the shortest path that begins at the point (2, 5), touches the
x-axis and then ends at a point on the circle x2 + y 2 + 12x − 20y + 120 = 0.
√
48. Suppose in a tetrahedron ABCD, AB = 1; CD = 3 the distance and angle be-
tween the skew lines AB and CD are 2 and π3 respectively. If the volume of the
tetrahedron is V then find the value of (60 V).
" # " #
1 −1 a b
49. Let A = ;B = . If (A + B)2 = A2 + 2AB+ B 2 , find the value
2 3 1 −2
of a2 + 4b2 .
100
a (2100 ) + b
!
X k 100
50. If Ck = where a, b, c ∈ N , then find the least value of
k=0 k + 1 c
(a + b + c).

x+1 y−p z+2 x y−7 z+7

51. Find the value of p so that the lines = = and = =
−3 2 1 1 −3 2
are in the same plane.
Z 1/n
52. lim n2 (2010 sin x + 2012 cos x)|x|dx =
n→∞ −1/n

dy
53. Given y(0) = 2000 and = 32000 − 20y 2 , then find the value of lim y(x).
dx x→∞

54. N fair coins are flipped once. The probability that at most 2 of the coins show up
as heads is 12 . Find the value of N .