2006

The Bishop's Co-Ed School, Undri

SECOND TERM EXAMINATION
Chemistry
Class: XI (3 hours)
M.M: 70
(Candidates are allowed additional 15 minutes for only reading the paper. They mUSt O
start writing during this
time.)

All questions are compulsory

n epaper is divided into four sections-A, B, Cand D. Answer all questions.

ection
Section A consists of one question having sub-parts of one mark each.
B consists of ten
questions of two marks
eaceacn and
Section C consists of seven questions of three marksS
Section D consists of three
questions of f+ive marks e and
All working including rough work, should be done on the same sheet as,
adjacent to the rest of the answer.
The intended marks for questions parts of questions are given in brackets
[.
or

and diagram where

Balanced equations must be given
they are helpful.
wherever possible
When solving numerical problems, all essential working must be shown.
In working and
problems, use the following data:
Gas Constant R = 1.987 cal mor= deg 8.314 JK mor
= 0.0821 dm3 atm K mol"
1 atm = 1 dnr atm = 101.3 J, I. Faraday = 96400 coulombs
Avogadro's number = 6.023 x 10

SECTION :A-14
Q1.a) Complete the following statements by selection the correct 4
alternative from the choices given.
1) Which ofthe following will have the configuration 25 22p5?
a) Alkali metal b) Oxygen Family c) Halogen d) Nitrogen

(ii) The element with the highest first ionization enthalpy is

a) Boron b) Carbon c) Nitrogen d) Oxygen
ii) Hydrogen exists in:
a) +1 Oxidation state only b)-1 Oxidation state only
c)0 Oxidation state only d) +1,0,1 Oxidation States
iv) Hydrogen peroxide is
a) An oxidizing agent
b) A reducing agent
c)Both on oxidizing and reducing agent.
d) Neither oxidizing agent nor reducing agent.

b) Fill in the blanks by choosing the appropriate words from 4

those given in the brackets.
(Reducing agent, Covalent bonding, +7, Pyramidal, +5,
Intermolecular hydrogen bonds, oxidizing agents, electron gain,
enthalpy, onization energy).

i) The lower density of Ice is due to the formation of .

i) Shape of ammonia molecule is .
ii) The energy released when electron is added to a neutral aasenu
atom is called of the atom.
iv) Oxidation state of Mn in Kmn04 is
 c)Matchthefollowing a) H,0,
Number of moles of solute per
litre of solution. solute per b) Bao 00
n) Number of moles of
1000g of solvent
ii) Bleaching of Hair
c) Molality
)As a neutron moderator in d) Molarity
nuclear reactors

d) Assertion
i)The physical and chemical properties of the elements are the 2
periodic function of their atomic numbers.
Reason Atomic numbers Is the most fundamental property of an
element and is responsible for its physical and chemical behaviour.
a) Both assertion and reason are true and reason is the correct
explanation of assertion.
b) Both assertion and reason are true but reason is not the correct
explanation for assertion.
C) Assertion is true but reason is false.

d) Assertion is false but reason is true.

ii) Assertion
The real gases deviate from the ideal gas behaviour at high
pressure and low temperatures.
Reason : The molecules of real gases do not attract one another
and move independently of each other.
aBoth assertion and reason are true and reason is the correct
explanation of assertion.
b) Both assertion and reason are true but reason is not the correct
explanation for assertion.
c)Assertion is true but reason is false.
d) Assertion is false but reason is true.
SECTION B: 20 MARKS
Q2. d. Answer the following questions. 2
(i) Write the structural formula of compounds having the following
I.U.P.A.C. names.
a) 5- methyl hept - 3- enal
b) 3- hydroxy 6, 6-dimethyl hept-4-ene-1-oic acid.

Q.3. The first ionization enthalpy of Nitrogen (z=7) is greater than that
of Oxygen (z=8) but the reverse is true for the second ionization
enthalpy. Explain why ?

Q4. Two flasks maintained at the same temperature are filled with 2
hydrogen and oxygen gas respectively.
i) Which of the two flasks contain more molecules and how many
more if the volume of the flasks and the pressure of the gases in
them are equal.
ii) If the capacities of the two flasks and the masses of the two gases
are the same, in which flask is the pressure greater and how many
times?

Q5. State the conditions when a real gas behaves like Ideal gas.

Q6. i) Give reasons 1) Electron gain enthalpy of Noble gases are positive.
i) lonisation enthalpy of Nitrogen is greater than Oxygen.
Q7.
Although both NH and
bond angle molecule have
of water is H,O molecule distorted geometries,
have us
less than that of ammonid Disc uss.
Q8 What is the
gas? compressibility factor ?
What is lue for an ideal
its vaue 2

Q9. Complete and

i) PbS+ HO balance the following
equation
i) FeSO4 +
H;0 +
HS0,
Q10. Draw the isomers of the 2
in. following and name tne

i) CaH10 ii) CHO

Q11. GIve the electronic confiquration of C r . Find the numDer

unpaired electrons in the ion.

SECTIONC: 21 MARKS
Q.12. GIve the I.U.P.A.C. name of the following compound
a Br

b)
CHO
c) CH3-C-CH2-CH2- CH;CI

Q.13. Find the molarity and molality of a 15% solution of H,SO (density
of HSO4Solution 1.10 g cm". Molecular mass of H,SO = 98)

Calcuate the oxidation number of the underlined atom in the 3

Q.14.
following species.

a) KCr2O b) Mn04 c) KFe(CN)

Balance the following equation by oxidation number method. 3

Q.15.
Cu+ HNO3 Cu(NO3)2 + NO + HO

Q.16.a) What type of hybridisation do you expect in the following 2

molecules.
(i) BF3 (i) CH4 (ii) CgHG (iv) BeF2

while H;S is explain 1

b) H20 is a liquid a gas,

In potassium the 19 electron enters into 4S subshell instead of 3d

Q.17 a)
subshell. Give reason.

b) A tennis ball of mass 60g is moving

with a velocity of 10ms 2
ball
Calculate the de-Brogile wavelength of this
(h 6.63 x 10" JS)

Q.18.a) 10g of NaOH are dissolved in 200cm of water. Find the molarity of 2
the solution. (Na=23, O=16, H=1).

b) For which of the following species, Bohr's theory does not apply?
i) H ii) H ii) He Li
 SECTIOND: 15 MARKS

9.a) Calculate the weight of methane in a 9.0 Ltres cylinder at 16 atm

and 27°C (C=12, H=1)

b) On what factors will the rate of diffusion of a gas depend?

Q.20 a) Calculate the density of Carbon dioxide at 27°C and 5 atmosphere 3
pressure (C=12, 016)
b) Give reasons for the following.
)The size of a weather balloon increases as its ascends to higher 2
altitudes.
i) There is no change in temperature when an ideal gas expands.

Q.21 Two elements A and B have atomic numbers 16 and 19 5

respectively.
i)Write down the electronic configuration of A and B in the term of s,
P, d, f.
i) Which element belong to the s-block ?
ii) Which element belong to the p-block?
iv) Which element is more powerful reducing agent.
v) Write down the formulae of the compound formed between A and
B.