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Do
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Chemical Sciences
Paper – ii
1. Central atom with sp3, sp3d2 and sp3d 3. Which of the following statement is
hybridization respectively correct ?
−
(A) BeCl2 and NH3, I5 and ReF7, XeF3+ (A) Best electrophiles have LUMO and
2. The bond length and bond order HOMO and best nucleophiles have
(C) 1.128 A° and 3.0 (CO); 1.115 A° and (B) LiCl > NaCl < KCl > RbCl > CsCl
+
3.5 (CO )
(C) LiCl > NaCl > KCl > RbCl > CsCl
(D) 1.015 A° and 3.5 (CO); 1.128 A° and
3.0 (CO+) (D) LiCl < NaCl > KCl > RbCl > CsCl
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5. The statements regarding hydrides of 7. Match the following and choose the
VI group are correct answer
H2O < H2Te < H2Se < H2S ii. Am241 b. α -particles
(C) U238 (0.70%), U235 (99.3%) and (A) one line only
U234 (traces)
(B) two lines with 1 : 1
(D) U238 (99.3%), U235 (traces) and
(C) three lines with 4 : 1 : 1
234
U (0.70%)
(D) three lines with 3 : 2 : 1
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10. What is the number of vibrational degrees 13. Match the following
of freedom in C6H5 – CH2OH ? Column I Column II
(A) 25 i. [Ni(acac)2 (pph3)2] a. Branched
(B) 27 alcohols
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15. The geometrical isomers of the type 19. Which of the following correctly places
[Pt A2X2] are distinguished by the ligands in their order with respect to
(A) Ring test ∆ 0 values
– – − –2
(B) Chromyl chloride test (A) F < Cl < N3 < O
–2
(C) Silver nitrate test
−
(B) S < OH < CN < pph3
−
17. In bacterial rubredoxin, the number I. The oxidation of alcohol with reduction
of iron atoms, sulphur bridges and of dichromate to chromium (III)
cysteine ligands are
II. Complex formation of alcohol and
(A) 4, 4, 4 dichromate.
(B) 2, 2, 4
III. Change in the coordination number
(C) 2, 2, 2 of chromium.
(D) 1, 0 ,4 Which of the following statements given
above is/are correct ?
18. Itai Itai disease is due to
(A) I only
(A) Hg poison
(B) II only
(B) H3CHg poison
(C) III only
(C) Pb poison
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21. In reverse phase chromatography, the 24. Find the symmetry point groups for
stationary phase is made
Ethane in eclipsed and staggered
(A) Hydrophobic non-polar
conformations.
(B) Hydrophilic polar
(C) Either non-polar or polar (A) C3v, D3h
(D) Polar head and non-polar tail
(B) D3h , C3h
22. Which reaction is an example of chain (C) D3h, D3d
reaction ?
231 (D) D3h, D3
U → 2 He +
235 4
(A) 92 90 Th
75
Se → Br + e−1
75
(B) 34 35
25. In gas liquid chromatography, when films
I →
123 123
(C) 53 53 I + energy
142 91 are used in the interior of capillary column,
U + 0n →
1
(D) 235
92 56 Ba + 36 Kr + 3 10 n
then what is the Eddy diffusion ?
23. Given the character table of the point (A) Greater than 1
group C3V
(B) Less than 1
E 2C3 3 σ V
A1 1 1 1 z (C) Zero
A2 1 1 –1
(D) Less than zero
E 2 –1 0 (x, y)
Consider the reducible representation,
Γ 26. The main buffer system of the human
E 2C3 3 σ V blood is
+
Γ 6 3 0 (A) NH2 CONH2 – NH2 CONH
_
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29. Which statement is correct ? 32. Match the objects in Part A with their
a. All tetrahedral complexes are high size in part B
spin, p > ∆t.
Part A Part B
b. Square planar complexes are
usually low spin and ∆sp > p. i. Nanoshell a. 100 nm
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33. Which of the following method is used 36. Which of the following are intrinsic
to make both nano-particles and properties ?
nano-powders ? 1. Specific rotation
4. Pressure
(C) Ball-mill method
(A) 1, 2
(D) Plasma arching
(B) 2, 3, 4
35. The ESR spectrum of Triphenyl methyl 38. Assertion (A) : If (dECell/dT) p > 0 for a
radical consists of cell reaction, then ∆S is + ve.
Reason (R) : ∆S = nFT (dE/dT).
(A) 25 lines
(A) Both A and R are true and R is the
(B) 75 lines correct explanation of A
(C) 196 lines (B) Both A and R are true and R is not
the correct explanation of A
(D) 27 lines (C) A is true but R is false
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39. Only one signal is present in the PMR 42. At what angles for the first order diffraction,
or NMR spectra of spacing between two planes respectively
(A) C3H4, C3H6 λ
are λ and ?
2
(B) C4H6, C5H12
(A) 0° , 90°
(C) C3H8, C2H6O
(D) C4H6, C3H18 (B) 30° , 90°
(C) 90° , 0°
40. Rotational Raman Spectrum is not
possible for (D) 90° , 30°
(A) CCl4
(B) CO 43. The X-rays of wavelength equal to
(C) HCl 0.134 nm give a first order diffraction
(D) N2 from the surface of a crystal when the
value of θ is 10.5°. Then the distance
41. Which is true among the following
about collids ? between the adjacent planes in the
1. Smaller the gold number greater the crystal is (sin 10.5° = 0.1822)
protective power.
(A) 367 nm
2. Lesser the valency of the coagulating
ion, the greater the coagulation (B) 3.67 nm
power.
(C) 0.0367 nm
3. Charge on the colloidal solution is
due to preferential adsorption of (D) 0.367 nm
either positive or negative ion which
is common and present in excess.
44. Number average molecular mass
4. Emulsion is dispersion of one liquid
into another which are completely of polymers can be determined by
miscible. following method
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51. The average position of a particle in 55. Average distance for 2s orbital of
one dimensional box of length L is He+ is
(A) L (A) 1A°
(B) L /2
(B) 2A°
(C) 2L
(C) 3A°
(D) 12L
(D) 4A°
52. For a two component system the
reduced phase rule equation is 56. The radial function ‘R’ depends on
(A) F = 4 – P 1. n
(B) F = 3 – P 2. l
(C) F = 2 – P 3. m
(D) F = 1 – P 4. s
(A) 1, 2
53. Identify the correct energy order of
equivalent ionic conductance of the (B) 1, 4
following
(C) 2, 3
(A) Li+ < Na+ < K+ < Rb+
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58. Which of the following transition require 61. The entropy of all perfect crystalline
the least energy ? substances is zero at T = 0°C
∗
(A) n → π represents
∗
(B) π → π (A) First law of thermodynamics
∗
(C) σ → σ (B) Zeroth law of thermodynamics
∗
(D) n → σ (C) Second law of thermodynamics
in solution is 4. Heat
(A) 1, 2
(A) Ag
(B) 2, 3
(B) Cu
(C) 3, 4
(C) Co
(D) 1, 4
(D) Zn
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64. What is the indicator electrode used 67. The IUPAC name of the following
in the potentiometric titration of AgNO3
compound is
Vs KCl ?
(A) Hydrogen electrode
(B) Platinum electrode
(C) Silver electrode (A) (R) – 3 – (prop – 2 – enyl) hex – 5 –
(D) Calomel electrode ynoic acid
List – I List – II
a. D3h i. PCl3
b. C2h ii. Cis 1,2 dichloro ethylene
(A) (2E, 4E) – 3 – chlorohexa – 2,4 –
c. C3v iii. BF3
diene – 1,6 – diol
d. C2v iv. Trans-N2F2
(B) (2Z, 4E) – 3 – chlorohexa – 2,4 –
Codes :
diene – 1,6 – diol
a b c d
(C) (2Z, 4Z) – 3 – chlorohexa – 2,4 –
(A) i ii iii iv
diene – 1,6 – diol
(B) i iii ii iv
(D) (2E, 4Z) – 3 – chlorohexa – 2,4 –
(C) ii i iv iii
diene – 1,6 – diol
(D) iii iv i ii
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69. Identify the following : 72. Among the following the aromatic
compounds are
I.
I II III
II.
(A) I, II and III
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a. Beckmann i. Oxetane
Rearrangement Y
b. Paterno Buchi ii. Olefin a. is form is more reactive
b. trans form is more reactive
Reaction
c. anti group migration favors as such
c. Wittig reaction iii. Enamine is form is more reactive
d. Stork reaction iv. Caprolactum d. syn group migration favors as such
trans form is more reactive
(A) a – iv; b – i; c – iii; d – ii (A) a, d
(B) a – ii; b – iii; c – iv; d – i (B) b, c
(C) ‘a’ is correct but ‘d’ is not the correct
(C) a – iv; b – i; c – ii; d – iii explanation
(D) a – ii; b – iii; c – i; d – iv (D) ‘b’ is correct but ‘c’ is not the correct
explanation
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79. Identify the catalyst in the following 82. Identify the intermediate (X) and target
reaction. molecule (Y) in the following reaction.
Catalyst
+ → 1. Li NH3 BuOH
→
2.m − CPBA
X →Y
(A) Na in C2H5OH
(B) Pd (OAc)2
(A) X =
(C) Zn in AcOH
(D) n-BuLi
Y =
80. Predict the stereochemistry of the
product in the following reaction
OsO4 product.
R – CH = CH –R →
(B) X =
(A) Syn Diol
(D) Epoxide
(C) X =
81. In the below sequence ‘X’ can be
X
C6H5 – CH = CH – CHO → Y =
C6H5 – CH = CH – CH2OH
(A) H2 | Ni
(D) X =
(B) Sn | HCl
(C) NaBH4
+ Y =
(D) K2Cr2O7 | H
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83. For the following three step conversion 85. The number of π electrons participating
of ‘X’ to ‘Y’, the appropriate sequence and the mode of cyclization in the
of reactions is following reaction are
heat
→
X
(A) 4 and CON rotatory
(B) 4 and DIS rotatory
(C) 6 and CON rotatory
(D) 6 and DIS rotatory
Y
86. Predict the stereochemistry of the product
(A) MnO2; (CH2OH)2/P – TSA; PCC in 1, 3 – sigmatropic rearrangement
(B) PCC; MnO2; (CH2OH)2/P – TSA of ‘carbon’ substituent under thermal
conditions.
(C) Jones reagent; (CH2OH)2/p – TSA;
MnO2 (A) inversion of configuration
(A) Synthesis of optically active 87. Amongst the following which will
compound from inactive one without undergo Diel’s Alder reaction ?
using optically active reagent
(A)
(B) Synthesis of optically active
compound from inactive one using
optically active reagent (B)
II 18 A-02-18
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88. What is the preferable site for electrophilic 90. Papaverine on oxidation with potassium
substitution reaction in isoxazole ? permanganate gives a ketone, which on
fusion with potassium hydroxide gives
(A) C – 3
(B) C – 4
(C) C – 3 and C – 5
(D) C – 3 and C – 4
(A) (A)
(B) (B)
(C) (C)
(D)
(D)
II 19 A-02-18
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91. Consider the following reaction 93. How many stereogenic centers are
sequence starting with α -pinene, present in cholesterol ?
identify the correct statement
alk. KMnO4
→ pinonic acid
α -pinene
A B
NaOH / Br
2→ pinic acid
C
(A) ‘A’ has a disubstituted double bond; (A) Seven
‘B’ and ‘C’ are dicarboxylic aicds (B) Six
(B) ‘A’ has a trisubstituted double bond; (C) Eight
‘B’ has a ketone and carboxylic acid (D) Nine
‘C’ is a dicarboxylic acid
(C) ‘A’ has a trisubstituted double bond; ‘B’ 94. In the IR spectrum, carbonyl absorption
band for the following compound
is a diketone and ‘C’ is a dicarboxylic
appears at
acid
(D) ‘A’ has a disubstituted double bond; ‘B’
is a diketone and ‘C’ is a dicarboxylic
acid
(A) 1770 cm–1 (B) 1690 cm–1
92. For estrone amongst the following (C) 1810 cm–1 (D) 1660 cm–1
statements which is true ?
95. Predict the appropriate 1H NMR
a. It has an aromatic ring chemical shifts for the protons A – D for
b. It has two hydroxyl groups the following compound.
d. It is a steroidal harmone
(A) b, c, d
(A) A 5.7; B 6.8; C 3.9; D 2.1 ppm
(B) a, b, d
(B) A 6.8; B 5.7; C 2.1; D 3.9 ppm
(C) a, c, d
(C) A 6.8; B 5.7; C 3.9; D 2.1 ppm
(D) a, b, c
(D) A 5.7; B 6.8; C 2.1; D 3.9 ppm
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96. An organic compound having the 97. Match the following drugs with their
molecular formula C10H14 exhibited two medicinal activity.
singlets in 1H NMR spectrum and three a. 5-fluorouracil i. Anticancer
signals in 13C NMR spectrum. The
compound is b. Amoxicillin ii. Anti-
inflammatory
iii. Antibacterial
iv. Cholesterol
(A)
lowering
(A) a – iii, b – iv (B) a – i, b – iii
(C) a – ii, b – iii (D) a – i, b – ii
_________________
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