NAMA : ARI KADARWATI TUGAS QC DAN VALIDASI

NIM : G1C222056

PENETAPAN KADAR SAMPEL Cr-VI DAN KADAR SAMPEL + SPIKE

MENGGUNAKAN PERSAMAAN GARIS LURUS

 PEMBUATAN KURVA KALIBRASI

Kadar Baku Cr - VI Absorbansi

No.
(mg/l)  
Labu
X Y
1 0.1 0.045
2 0.2 0.080
3 0.4 0.167
4 0.6 0.243
5 0.8 0.290
6 1 0.382

Kurva Kalibrasi Cr-V1

0.45
0.4
0.35 f(x) = 0.367369863013699 x + 0.011358904109589
R² = 0.994214113211151
0.3
Absorbansi

0.25
Absorbansi Y
0.2 Linear (Absorbansi Y)
0.15
0.1
0.05
0
0 0.2 0.4 0.6 0.8 1 1.2
Konsentrasi Standar
  PERHITUNGAN KADAR SAMPEL + SPIKE

Sampel ID Absorbansi

Sampel 0.090
Sampel + Spike 1 0.135
Sampel + Spike 2 0.140
Sampel + Spike 3 0.144
Sampel + Spike 4 0.142
Sampel + Spike 5 0.136
Sampel + Spike 6 0.138

C Sampel( mg/L)
Keterangan Abs Sampel
(A)

Sampel 0.090 1.0696

Abs C Sp + Spike C Spike Target C Spike Target

Keterangan Treatment (mg/L) (mg/L) Treatment (mg/L)
Sp+Spike
(B)   Selisih (B) dan (A)
Sampel + Spike 1 0.135 1.401 0.4 1.401-1.0696=0.3314
Sampel + Spike 2 0.140 1.458 0.4 1.458-1.0696=0.3884
Sampel + Spike 3 0.144 1.503 0.4 1.503-1.0696=0.4334
Sampel + Spike 4 0.142 1.480 0.4 1.480-1.0696=0.4104
Sampel + Spike 5 0.136 1.413 0.4 1.413-1.0696=0.3434
Sampel + Spike 6 0.138 1.435 0.4 1.435-1.0696=0.3654

 PERHITUNGAN KONSENTRASI SAMPEL + SPIKE MENGGUNAKAN PERSAMAAN GARIS

Y = 0.3674X +0.0114
RUMUS PERHITUNGAN
X = (Y-0.0114)/ 0.3674 x PENGENCERAN

KADAR SAMPEL = (0.090-0.0114)/ 0.3674 x 50/10

= 1.0696

KADAR SP +SPIKE 1 = (0.135-0.0114)/0.3674 x 50/12

 = 1.401

KADAR SP +SPIKE 2 = (0.140-0.0114)/0.3674 x 50/12

= 1.458

KADAR SP +SPIKE 3 = (0.144-0.0114)/0.3674 x 50/12

= 1.503

KADAR SP +SPIKE 4 = (0.142-0.0114)/0.3674 x 50/12

= 1.480

KADAR SP +SPIKE 5 = (0.136-0.0114)/0.3674 x 50/12

= 1.413

KADAR SP +SPIKE 6 = (0.138-0.0114)/0.3674 x 50/12

= 1.435

 PENGOLAHAN DATA

No C Spike Target C Sp + Spike %R = (C Spike Treatment/ C Spike

Rn- R rata-rata
. (mg/L) Treatment (mg/L) Target) x 100

1 0.4 0.3314 (0.3314/0.4)x100 = 82.85% 82.85-94.68 = 11.83

2 0.4 0.3884 (0.3884/0.4)x100 = 97.10% 97.10-94.68 = 2.42

3 0.4 0.4334 (0.4334/0.4)x100 = 108.35% 108.35-94.68= 13,67

4 0.4 0.4104 (0.4104/0.4)x100 = 102.6% 102.6-94.68 = 7.92

5 0.4 0.3434 (0.3434/0.4)x100 = 85.85% 85.85-94.68 = 8.83

6 0.4 0.3654 (0.3654/0.4)x100 = 91.35% 91.35-94.68 = 3.33

Jumlah=48/6= 8
R rata-rata =568.1/6= 94.68%

X %R rata-rata 94.68
SD SD   8
X + 3SD UCL 94.68 + (3 x 8) = 118.68
X + 2SD UWL 94.68 + (2 x 8) = 110.68
X + 1SD LCL 94.68 + (1 x 8) = 102.68
X - 3SD LCL 94.68 - (3 x 8) = 70.68
 X - 2SD LWL 94.68 - (2 x 8) = 78.68
X - 1SD LWL 94.68 - (1 x 8) = 86.68

 Grafik dari %R data sampel + spike 1 sampai 6

X % R rata-rata 94.68
SD SD 8
X + 3SD UCL 118.68
X + 2SD UWL 110.68
X + 1SD 102.68
X - 3SD LCL 70.68
X - 2SD LWL 78.68
X - 1SD 86.68

NO %R Keberterimaan
(80%-120%)
1 82.85% Terima
2 97,10% Terima
3 108.35% Terima
4 102.6% Terima
5 85.85% Terima
6 91.35% Terima

Control Chart Cr-V1

140

120

100
% Recovery

80

60

40

20

0
1 2 3 4 5 6
RATA-RATA UWL UCL LCL LWL % RECOVERY