RUBBER AND PLASTICS TESTIN9

AsSIGNMENT

STUDy ON CURE (HARE CTERISTmes OF STyRENE-BUTADIENE RUBBER

Vulconuatun isOne o th dd est x most (mpextant pros U

ouDDE
pocaJa v tt laads to the toonssomedtin o a
plastt uDna
COmpound Uto a hiah alastic fn tshod product te) a vuleonizote.

Aith apeche Hunduonal propertiza

Mony difoont ouuung Astema has an deueloped& tha most unpetort
beuhg usng of sulphuu, peonides metol onids.The tholde a
Poope tuuung dyptem Tesults maunly frn tRe chomieol notuwe f
aubbete presenca of functorol obupa
suitabt fox cCoss hrt ve
eadunz
Tho mogt Dmmonly Ued g na Uhtie nubbe ndustay aTe

elomanctal sulu hor ubbeus uirth &ome deqpe0 tungotuuatun

peonioos fet 3atuuatd topokymets
SBR Rubbol tonpounds orse ul eansed at 160°C wth a q0
Uncceose in forqus. Optumal Vulcon usotton fuine c foo) s
found
usuig Movuig Die Rhe ometer 2 san
SBR Vul eanuatu
tatpe atues 0d the efe dt
Tampe atuunes
oentfolpy on the
provcoks wel
studud wungo Diffeantial Sconnung
oloometer
 ofpnrnouy
Ouug ats
(om tte type
th charedtexs
The unfuenco of ontent o ZnD, on thu uuu

tu
wed usq
be estunated
accelorator
Con
ubbe tompbunds
t t o s f SBR
bheomap@160°C lo (roole/cm
Nn)foa(mir) tqo(minYt
(dNm)AS (d
ACTIVATOPSmin
CormPoUNDS
I T H CB >MBT
RUBBER
D 8
6 16
2 S
sphs Zn0 1-2
CoMFOUNDS w rTH CB 2 DPG
RUBBER
32 64
S pha 2nD11 24 44
ComPOUNRI TH SIUCA ADPG
RUBBER
3-1
Sphs 2nD 11 o-0
04-8 s3
Smin Mnunum Tosque AS -ncoemert o Torque dung
VulcansoatuoD
to Scos ch ftme, Tqo- Dptumum cuse turte
Thae roununurn tosqu duroug tho zhe omotolc meaAuemnu
CoobOsporded to the vB tocdy ot uhcuted aubber Compburd
Tt con be concluded tot the type of uwug sytem hod
no unfuence on the sUo dg f tre uncued SeR Comptunds

flled wrth cB
TOe uncued silica filled SPR 0Ubber tompounds enhibited
Considoab highu usuoctty AThaus bighe Svin than the
SBR compounds ftled wrth ce
 Ths dAt to he apph otuon of
fumed nanod1od silt co ufth
quto 1aae sro suufaco sco uhtch unuea/eol The
esoib
the stirfnes of frs
aubber topounds compaued to (olbon
blatk NSso
Ve toogue tncuoment (A) ciueng ohgomehic measuue vofl 4
CooDspend to it deqvee of Cooss lunbog of tho
ru bhe
Among 3BR COMpaunds ied wrlh (B MBT ano (B
DP), Theu
ony e vey los O:1 deuiet ton tho torque naermot
sean dhile these SER Comfounds fld wrth silio DPG)
accalaiatos, the 8S vaues ose iq hy deuiated compaued t
SBR UOtth CBAled
As Rnouwn Prooy, ET poovides meduum cuue Tat uhewos
a

DPG vesutb n a sutfher Souo Cuug gate ba u

6ofe in tems
foubbes Dmpound pcesUg.
1hdlefvse SBR CDMpounds
Jrff tqesT eaibttod a couidorabg shovte
opfumal vol eanuat on
me than Df) contayi ugBR. Too eachool af
bmns
se of tre SBR Compourd iled wth (BMBT
occolar atua
hi(o that wrih DiG a( Coletafvo,
(Ailed LBR mpOund
achad Tro @ 32 mus n the Ofh! hand torth iica
ft(ed
sR D a accolorafos it fook S3 mus (to seach 1go
 SPR nubba compound med orth Dlo a an accolpa ator

eahibitod slqnitt eant4 onge 3tor ch fune hon the B

on Tha
Comtaunung SBR Compbunds. Cuuug Jysteo has an Unpact
CoDssunb danab f SBR Compouncls The CB-flled
(B-Allad
Vulcantbata Cuad srth MBt shouwed htqha csogsg Une

densit thon th oge cotaun un9 DP ace lpratos

CURINO CHARACTERISTICS Of SBR NBR BENDS.

he
ft bland vottos uplo ts pho, SBR/ NBR bords ghou?ed hig
ta andt10 CompaAgd to SBRCUe
TEMPERATURE AND ENTHALPY OF BR VULCANISATION DETERMINED Fy
DSC

ActtUeTOR TEmP OF UULCANISATON TErOP Of PEAM Hvol3a)

SBR CB FIUED ITH MBT
sphro 2n0 S8-203 °C L18 4
SBR CB FlLED W rH
DPG
spho 2n0D T1-21
214 -2
SBR Silicati Lud uoTH DP
Spha 2nb 82-238 209 13.8

Cuuung sysloro otedis "Tua bong oVuleohL6otun tenmp asd

the erttolpy opovco D SBR tompounda The vuleonstun
of8BR cortaunug inBT 06 pomauy accolbi atva Degan at o
tR 20- 30°c (oue thon SBR 0otauung DPG accaluano
 EFFECT of CURIN s9TEm ON
OF SBR WLCerZATES M6HArltCAL FRPERTIES AND
HARDNEC

AtruamDR SEac6 (f) Ts(mfoy EB(7) H (3hA)

Yul cantztas usth CB MEST
sph6 2nD
6
453
Vulcanf2ortes urh CB ADPG
Spho 2nb
S6

Vulcanizotes usitti slt co

DPs
Spha 2nD
29
modulMs oelctwe
elongrofuon o3o0
ensile Strenqth EB elorgnatuon Br2ok,
h: Haudnes
Chonges n SEseo mbdulus o SBR Vul
coni2atos undu tha
uflueno tho cuuug systom orse tosut ert with the
changes in
Csosslnk densry CB ilod
alcan2ates wed sh oMBT emhi bited
Afe hig hesf SEs0o Value
he tuung 6ptom & OA tD
ofect the teniCa sregth of SBR
Ueuleartzorhes ogt of tf CB ulcani2oles contaunu
DPe ehibrfed app qmPa ahu TS vau Aan those
Jtth tqpBT Med
CuAungsooha a
siqnifhcant mpatt on the EB vau
Arnona cB sERilled SER, fe EB Uauz of Drh accelusted
Ddtoi2 ote u highe than tht ef toer Onthe othe handl
St lhou ftlkd SBR uth DP accaluator has the htghest
elonanato) buok vaur Lndicafung tls Impact of uuU
stum
&rril aby hardrum valus chonge au du to thu Tse in th
Coots une densty of the ul tani20otes wrth the CuuUg

ustomsHeve "to ths Same 1end as thot of ¬B ú seon

siltex fllocd SBR uwtR PPS b much houdu than (B tlled
SEBR dhlle among CB tlled SBR Compounda, Met accupiotod

bapsthe hiohest haudns value) Ualtes bu g

Drolszho DPS) S2ND

Silico flad
2 CB illed

D-4
jo
o 2

20 -&O -30 20
-$O 30

Termp- Femp