Solution Slot - 2 (Chemistry) Page # 6

Exercise - III Subjective Level-I

6. KOH = xg ; Ca(OH)2 = 4.2 - x g Eq. Concept
Eq. of KOH + Eq. of Ca(OH)2 = Eq. of Acid 19.5
x  1 y  1   1   (1)
x 4.2  x   2 1000
1  = 0.1
40 74 When MeOH is used
 x = 1.474 25  1
x  2  y 1     (2)
1.474 1000
% KOH   100  35%
4.2 from eqn (1) & (2)
7. x mole each 5.5 14
 Na2CO3 = 106 x g and NaHCO3 = 84 xg x mole Na2CO3 & y  mole NaOH
1000 1000
1 In 25ml
 106x + 84x = 1  x  mole
190 Na2CO3 = 5.5 x 10-3 x 106 g = 0.583g
eq. of Na2CO3 + eg. of NaHCO3 = eq. of HCl NaOH = 14 x 10-3 x 40g
1 1 V = 0.56 g
2  1 = 0.1 In 1000ml
190 190 1000 Na2CO3 = 23.32 g & NaOH = 22.4 g
3 0.1 V
 =  V = 157.8 ml 12.NaOH = x m.mole and Na2CO3 = y m mole
190 1000
HPh used
8. H2SO4(m.eq.) = 26.7 x 0.4 1
x  1  y  1  17.5 
26.7  0.4 10
 H2SO4 (mole)   5.34  10  3 MeOH is used after HPh
2  1000
 wt. of H2SO4 = 0.523 g All the NaOH will be finished and Na2CO3 con-
 0.5g oleum produces 0.523g H2SO4 verted in NaHCO3 = y m mole
0.523 1
 100g oleum will produce =  100 g H2 SO 4  y  1  2 .5   y = 0.25m mole
0.5 10
= 104.66 g  x = 1.5m mole
% labelling = 104.66 mass of NaOH = 1.5 x 10-3 x 40 = 0.06g
mass of Na2CO3 = 0.25x10-3 x 106 = 0.0265g
104.66  100   80
 Free SO3 (%)  = 20.73%
18 13.Eq. of Ce 4  = Eq. of Sn 2
9. NaH2PO 4  2 NaOH  Na 3PO 4  2 H2 O 40.05 x 1 x nf = 20x1x2
12g  nf of Ce 4  = 1
12 ox. state change Ce 4   Ce 3 
  0.1 mole NaH2PO4
120 for nf = 1
 NaOH required = 0.2 mole
V 14.Eq. of Se = Eq. of Cr
 0.2  1  V = 200 ml 12.53 x 0.05093 x nf = 25.52 x 0.1 x 1
1000 nf = 4
10.When HPh used
SeO 2  Se
Na 2 CO 3  HCl  NaHCO 3  NaC
for nf = 4 : ox. state = zero
4 
nNa 2CO 3  1   1  Equivalent concept 15.K2C2O4. 3H2C2O4. 4H2O : nf = 8 as R.A.
1000  Eq. of oxalate = Eq. of KMnO4
3
 nNa 2CO 3  4  10 mole ...........(1)
1
When MeOH used  8 = V x 0.1 x 5
M.wt.
Na 2CO 3  2HCl  H2 CO 3  2 NaC Mol. wt. (oxalate) = 508
8
NaHCO 3  HCl  H2CO 3  NaC  V  0.03168 L
508  0.1 5
10.5  V = 31.68ml
nNa2CO3  2  nNaHCO3  1 =  1 .......(2)
1000
3
16.Eq. of H2O2 = Eq. of KMnO4
 nNaHCO 3  2.5 10 mole
11.In 25ml x mole Na2CO3 & y mole NaOH  
nf = 2 nf = 5
When HPh used

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 Page # 7 Solution Slot - 2 (Chemistry)


 1
x 

 MnO 2  Mn2
  100 2  x  N  N = 0.588 nf = 2
 34  1000  m. mole of MnO2 = 4/2 = 2
 
   mole of MnO2 = 2 x 10-3
mass = 2 x 10-3 x 87 = 0.174g
17. Sn  Sn C 4 : At. wt. (Sn) = 118.7
0.174
nf  4 %   100  3.48%
Eq. of Sn = Eq. of dichromate 5
1 1 40 22.Total m.eq. of HC  0.5  50  25
 4 = V  V  L m.eq. of NaOH = 0.3 x 20 =
118 .7 10 118.7
6 = m.eq. of remaining after rxn with Ca(OH)2
 V = 336.98 ml m.eq. reacted with Ca(OH)2 = 25 - 6 = 19
 mole of Ca(OH)2 = 19/2 x 10-3
18.Eq. of Hypo = Eq. of I2
m.20 x 0.0327 = m. eq. of I2 = m. eq. of (in 20ml) 19
 mass of Ca(OH)2 =  10 3  74  0.703 g
1000 2
 Cu  in 1L = 20  0.0327  m. eq.
20 Purity = 0.703 x 100 = 1.406%
 Eq. of Cu  = 0.0327 eq. 23.In 50ml solution
 Cu+ = 0.0327 mole = 0.0327 x 63.5 g = 2.07645g Total m.eq. of HCl = 50 x 0.1 = 5
 % = 2.07645/5 x 100 = 41.53% m.eq. of NaOH = 10 x 0.16 = 1.6
= m.eq. of HCl react with NaOH
1 55.2
19. Fe 2 O 3   0.552g  m.eq. of HCl reacted with Na2CO3
100 = 5 - 1.6 = 3.4
Aften Zn dust treatment  m.eq. of Na2CO3 = 3.4
Fe3  
 Fe2  3.4
 m mole of Na2CO3 =
  2
3 .4
0.552 0.552  mass of Na 2CO 3  x10 3 x106  0.1802 g
 2 mole  2 mole  in100 ml 2
160 160   In 250ml
 In 25 ml mass of Na2CO3 = 0.1802 x 5 = 0.901
0.552  2
Fe2  
0 . 901
mole ; (nf = 1) % Purity   100  90 . 1 %
160  4 1
Now eq. of Fe2+ = Eq. of oxidant
0 .552  2 17  0.0167 24.Total m.eq. of Ag NO3 = 25 x 0.1 = 2.5
 160  4  1 =  nf Ag+ m.eq. reacted with NH4SCN = m.eq. of NH4SCN
1000 given 1 ml of NH2SCN = 1.1ml of AgNO3
 nf = 6 for oxidant  Ag NO3 used = 0.1 x 1.1 x 5 = 0.55
 6 mole e- remaining AgNO3 = 2.5 - 0.55 = 1.95
m.eq. of NaCl + m.eq. of KCl = m. eq. of AgNO3
x  m mole of NaCl + m mole of KCl = 1.95
20. Iron = 0.84  g Let the mass = x kg of substance
100
Eq. of dichromate = Eq. of Fe2+  60 1   37 1  1 . 95
 x    x   
 100 5 .85   100 74 .5  1000
 0.84 
x   x = 0.1281g
N 100 
x   25. 2HC   CaCO 3  H 2 CO 3  CaC  2
1000 56
10g CaCO 3  0.1mole CaCO 3
 N  0.84  1000  0.15 mole of HCl required = 0.2
100  56 250
21.Eq. of I2 = Eq. of Hypo total mole of HCl taken   1  0 .25
1000
40 Remaining HCl = 0.25 - 0.2 = 0.05 mole
meq of I2 = =4  KOH required = 0.05 = 2 x (L)
10
 m.eq. of I2 = m.eq. of KI = m.eq. of C 2  V = 0.025L or V = 25 ml
= m.eq. of MnO2
 m.eq. of MnO2 = 4

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