Model Answer Homework Lesson (5)

Question Answer Question Answer

1 a 7 a
2 c 8 d
3 a 9 c

4 b 10 d
5 d 11 b
6 c

12. 2NaOH+MgCl2→2NaCl+ Mg(OH)2

Molar mass of NaOH= 23+16+1=40 gm
Molar mass of Mg(OH)2 =24+2(16+1) =58 gm
2NaOH → Mg(OH)2
X g → 5g
2(40)g →58 g
𝟓 𝒙 (𝟐𝒙𝟒𝟎)
So, mass of NaOH= =6.8 grams
𝟓𝟖

13. (a)
BaCl2+Na2SO4→BaSO4+2NaCl
Molar mass of BaCl2= 137+2(35.5) =208 g
Molar mass of BaSO4 =137 + 32 + (4 x 16) = 233 g
BaCl2 → BaSO4
X g → 4g
208g→233g
 4 𝑥 208
Mass of BaCl2 = = 3.57 gram
233

14. (c)
BaCl2
+ Na2SO4→BaSO4+2NaCl
NaCl

molar mass of BaCl2=137+(35.5×2) =208g

Molar mass of BaSO4= 137+32+(4×16) =233g
BaCl2 → BaSO4
X g →2.734 g
208 g→233 g
(2.734×208)
So, mass of BaCl2= = 2.44 g
233
2.44
% of barium chloride in mixture = 3.725 x100 = 65.52%

15. (a)
MCl2 + 2AgNO3 → 2AgCl + M(NO3)2
Molar mass of MCl2 = (35.5×2) +mass of M
Molar mass of AgCl=35.5+107.8=143.3 grams
MCl2→2AgCl
1.59 gm →3.6 gm
(71+M) gm→2(143.3) gm
1.59 𝑥 2(143.3)
71+ M = 3.6

71+M =126.58
So, M=55.58 g
16. (d)
NaCl+AgNO3→NaNO3+AgCl
Molar mass of NaCl=35.5+23=58.5g
Molar mass of AgCl=35.5+107.8=143.3 g
NaCl→ AgCl
58.5 g→ 143.5 g
X g → 4.628 g
So, Mass of NaCl=1.88g
1.88
% of NaCl in sample = x100 = 94.4%
2

17. d
2NaOH+FeSO4→Na2SO4+Fe(OH)2
No.of moles
Concentration = Volume in liters

No. of moles of NaOH =conc. × volume in litres

= 0.1 x 0.1 = 0.01 mole
M.m of Fe(OH)2=56+2(16+1)=90g
Molar mass of NaOH= 23+16+1=40 g
For NaOH
1 mole → molar mass (40g)
0.01 moles → x gm
Mass of sodium hydroxide =0.01(40)/1 =0.4 g
2 NaOH → Fe(OH)2
2(40)g→90g
 0.4→X g
Mass of Fe(OH)2=0.45g
18.(a)
3AgNO3+Na3PO4→Ag3PO4+3NaNO3
Molar mass of AgNO3 =170g
Molar mass of Ag3PO4 = 419g
3AgNO3→Ag3PO4
3(170) g→419 g
X g →2.25 g
(3𝑥170)𝑥 2.25
Mass of silver nitrate = = 2.7 grams
419

19. a (Phosphate anion)

3BaCl2+2Na3PO4→Ba3(PO4)2+6NaCl
Molar mass of BaCl2= 137 + (35.5 x 2) = 208 g
Molar mass of Ba3(PO4)2 = 137(3) +2(31 + (4 x 16)) = 601g
3 BaCl2 → Ba3(PO4)2
3(208) g → 601g
Xg → 1.21g
Mass of barium chloride in soluble=1.256g
20.
KCl+AgNO3→AgCl+KNO3
Molar mass of KCl = 39 + 35.5 = 74.5 g
Molar mass of AgCl = 108 + 35.5 =143.5 g
 KCl → AgCl
74.5g → 143.5g
Xg→2g
2 𝑥 74.5
Mass of KCl= =1.03 g
143.5

21.(d)
NaCl+AgNO3→NaNO3+AgCl
Molar mass of NaCl=35.5+23=58.5g
Molar mass of AgCl=35.5+107.8=143.3 g
NaCl→ AgCl
58.5 g → 143.5 g
X g → 4.628 g
So, Mass of NaCl=1.88 g
1.88
% of NaCl in sample = x100 = 94.4%
2

22. (a) (The main component is carbohydrates)

𝑀𝑎𝑠𝑠 𝑜𝑓 𝑐𝑎𝑟𝑏𝑜ℎ𝑦𝑑𝑟𝑎𝑡𝑒𝑠
Mass of carbohydrates = x100
𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠
44
Mass of carbohydrates = 50 x100 = 88%

23. (c)
KCl + AgNO3 → AgCl + KNO3
Molar mass of AgCl = 108 + 35.5 =143.5 g
AgCl → Cl
143.5 g → 35.5 g
 6.7 g →X g
Mass of cl= 1.657g
Total mass of sample (KCl)=3.4g
1.657
% of Cl= x100 = 48.7%
3.4

24.(d)
molar mass of BaCl2=137+(35.5×2)=208 g
Molar mass of H2SO4 = 2(1) + 32 + 4(16) =98 g
BaCl2 → H2SO4
208 g → 1 mol
0.5g → X mol
So, no. of moles of sulphuric acid=2.4×10-3 mol
For H2SO4
𝑁𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
Concentration=𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑒𝑠

volume=2.4×10-3 L. =2.4 mL
25.(c)
𝑀𝑎𝑠𝑠 𝑜𝑓 𝑔𝑜𝑙𝑑 23
%of gold= x100 = 313 x100 = 7.34%
𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠

% of impurity =100-%of purity (Gold)=100- 7.34=92.65%

26. (b)
Na2CO3.10H2O → Na2CO3 + 10H2O
10H2O → 20H
Molar Mass (H2O) = 10 x 18 = 180g
Molar Mass (H) = 20 x 1 = 20g
20
Mass percentage of hydrogen =180 x100 = 11.11%

Or
H2O → 2H
Molar Mass (H2O) = 18 g
Molar Mass (H) = 2 x 1 = 2 g
2
Mass percentage of hydrogen =18 x100 = 11.11%

27.(c)
NaOH
+HCl→NaCl+H2O
NaCl

𝑀𝑎 ×𝑉𝑎
= Acid
𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑏𝑎𝑠𝑒
Base
𝑛𝑎 𝑛𝑏
Va=0.01L Vb= x
No. of moles of base=1 ×10 mol
-3
Ma=0.1 Mb = x
Molar mass of NaOH= 23+16+1=40 g na=1 nb=1

For NaOH:
1 mole → 40 g (molar mass)
1X10-3 mole → = x g
Mass of sodium hydroxide = 1×10-3 × 40 = 0.04 g
𝑀𝑎𝑠𝑠 𝑜𝑓 𝑁𝑎𝑂𝐻 0.04
%of NaOH in mixture= x100 = x100 = 40%
𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠 0.1
28) (b)
NaOH+HCl→NaCl+H2O
𝑀𝑎 ×𝑉𝑎 𝑀𝑏 ×𝑉𝑏
=
𝑛𝑎 𝑛𝑏 Acid Base
Mb=0.06M Va=0.015L Vb=0.025L
𝑁𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
Ma=0.1M Mb= x
Concentration= 𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑒𝑟𝑠 na=1 nb=1
No. Of moles= 0.06 x 0.025=1.5×10-3 mol
Molar mass of NaOH= 23+16+1=40 g
For NaOH:
1 mole → 40 g (molar mass)
1X10-3 mole → = x g
Mass of substance=1.5×10-3 x 40= 0.06g
29) (b)
KOH+HCl→KCl+H2O
𝑀𝑎 ×𝑉𝑎 𝑀𝑏 ×𝑉𝑏
= Acid Base
𝑛𝑎 𝑛𝑏
Va=0.015L Vb=0.01L
So Mb=0.3M
Ma=0.2M Mb=?
For KOH: na=1 nb=1
𝑁𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
Concentration=𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑒𝑟𝑠

No.of moles = 0.3× 0.5=0.15mol

Molar mass of KOH= 39+16+1=56 g
1 mole → 56 g (molar mass)
0.15 mole → x g
Mass of substance =8.4g
8.4
%of KOH= 10 x100 = 84 %

30) (a)
CaCO3+2HCl→CaCl2+H2O+CO2
𝑀𝑎 ×𝑉𝑎 𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑏𝑎𝑠𝑒
= Acid Salt of base
𝑛𝑎 𝑛𝑏

No.of moles =6×10-³ mol Va=0.015L V=?

Ma=0.8M M=?
Molar mass of CaCO3= 40 + 12 + na=2 nb=1
3(16) = 100 g
1 mole → 100 g (molar mass)
6 x 10-3 mole → = x g
Mass of substance=6×10-3 x100=0.6g
0.6
%of CaCO3=1.5 x100 = 40%

31) (a)
2KOH +H2SO4→K2SO4+2H2O
Molar mass of KOH= 39+16+1=56 g Acid Base
Va=? Vb=0.03L
1 mole → 56 g (molar mass) Ma=0.5M Mb=?
X mole → 5.6 g na=1 nb=2
No.of moles (base)= =5.6/56=0.1mol
Concentration of base (Mb)
No.of moles 0.1 Acid Base
=Volume in liters =100 x 10−3 = 1M Va=? Vb=0.03L
𝑀𝑎 ×𝑉𝑎 𝑀𝑏 ×𝑉𝑏 Ma=0.5M Mb=1
𝑛𝑎
= 𝑛𝑏 na=1 nb=2
So, Va=0.03L=30mL
32) (b)
2HCl+Na2CO3→2NaCl+H2O+CO2
Acid Base
𝑀𝑏 ×𝑉𝑏 𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑎𝑐𝑖𝑑
= Va=? V=0.022L
𝑛𝑏 𝑛𝑎
Ma=? M=0.11M
So, No. of moles of acid = 4.84x10-3mol na=2 nb=1
Molar mass of HCl= 1 + 35.5 = 36.5 g
1 mole → 36.5 g (molar mass)
4.84 x 10-3 mole → = x g
X = 0.17666 g
So, mass = no. of moles x molar mass
= 36.5x 4.84x10-3 = 0.177g
33) (b)
Mg(OH)2+2HCl→MgCl2+2H2O
𝑀𝑎 ×𝑉𝑎 𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑏𝑎𝑠𝑒
= Acid Base
𝑛𝑎 𝑛𝑏
Va=0.125L Vb=?
125×10−3 x0.136
No. of moles of base= Ma=0.136 Mb=?
2
=8.5x10-3 mol na=2 nb=1
Molar mass of Mg(OH)2= 24+ 2(16+1)=58 g
1 mole → 58 g (molar mass)
8.5 x 10-3 mole → = x g
X = 8.5 x 10-3 x 58 = 0.493 g
Mass =no. of moles x molar mass=8.5x10-3 x 58=0.493g
34) (d)
Mg(OH)2+2HCl→MgCl2+2H2O
𝑀𝑎 ×𝑉𝑎 𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑏𝑎𝑠𝑒
= Acid Base
𝑛𝑎 𝑛𝑏
125×10−3 x0.136
Va=0.125L Vb=?
No. of moles of base = Ma=0.136 Mb=?
2
= 8.5x10-3 mol na=2 nb=1
Molar mass of Mg(OH)2= 24+ 2(16+1)=58 g
1 mole → 58 g (molar mass)
8.5 x 10-3 mole → = x g
X = 8.5 x 10-3 x 58 = 0.493 g
Mass =no.of moles x molar mass=8.5x10-3 x 58=0.493g
35) (d)
H2SO4+2NaHCO3→Na2SO4+2H2O+2CO2
𝑀𝑎 ×𝑉𝑎 𝑛𝑜 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑏𝑎𝑠𝑒
=
𝑛𝑎 𝑛𝑏

No.of moles of base =1.43 x10-3mol

Molar mass of NaHCO3= 84 g
Acid Salt of base
1 mole → 84 g (molar mass) Va=7.15X10-3L Vb ?
1.43 x 10-3 mole → = x g Ma=0.1M Mb ?
na=1 nb=2
X = 1.43 x 10-3 x 84 = 0.12012 g
Mass =no.of moles x molar mass = 0.12g
0.12
%of NaHCO3= x100 = 12%
1

36.(a)
% of impurities=100 -18=82%
 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑖𝑚𝑝𝑢𝑟𝑖𝑡𝑖𝑒𝑠
% of impurities= x100 =
𝑡𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑖𝑚𝑝𝑢𝑟𝑖𝑡𝑖𝑒𝑠
82% = x100
3

So, mass of impurities=2.46Kg

37)C
38) C (Mass of D = 111 g)
Answer is C) B only
A) NaCl + AgNO3 → AgCl + NaNO3
Molar mass of NaCl= 23+35.5 =58.5 g
Molar mass of AgCl= 108 + 35.5=143.5 g
NaCl → AgCl
58.5 143.5 g
Xg 116 g
X = (58.5 x 116) / 143.5 = 47.2 g
% of sodium chloride = (47.2 / 50) x 100 = 94.5%
More than 90% so it will be packaged

B) NaCl + AgNO3 → AgCl + NaNO3

Molar mass of NaCl= 23+35.5 =58.5 g
Molar mass of AgCl= 108 + 35.5=143.5 g
NaCl → AgCl
58.5 143.5 g
Xg 105 g
X = (58.5 x 105) / 143.5 = 42.8 g
% of sodium chloride = (42.8 / 50) x 100 = 85.6%
Less than 90% so it will not be packaged

C)NaCl + AgNO3 → AgCl + NaNO3

Molar mass of NaCl= 23+35.5 =58.5 g
Molar mass of AgCl= 108 + 35.5=143.5 g
NaCl → AgCl
58.5 143.5 g
Xg 122 g
X = (58.5 x 122) / 143.5 = 49.7 g
% of sodium chloride = (49.7 / 50) x 100 = 99.4%
More than 90% so it will be packaged

D)NaCl + AgNO3 → AgCl + NaNO3

Molar mass of NaCl= 23+35.5 =58.5 g
Molar mass of AgCl= 108 + 35.5=143.5 g
NaCl → AgCl
58.5 143.5 g
Xg 111 g
X = (58.5 x 111) / 143.5 = 45.2 g
% of sodium chloride = (45.2 / 50) x 100 = 90.4%
More than 90% so it will be packaged
39) (a)
Na2CO3+2HCl→2NaCl+H2O+CO2
𝑀𝑎 ×𝑉𝑎 𝑀𝑏 ×𝑉𝑏
= 𝑛𝑏
𝑛𝑎
Acid Salt of base
So, Mb=0.05M Va=0.025L Vb=0.025L
Concentration of base (Mb)=no. Ma=0.1M Mb?
na=2 nb=1
moles/total volume
so, no. of moles =0.05 x 1=0.05mol
Molar mass of Na2CO3= 2(23)+12 + 3(16) = 106 g
1 mole → 106 g (molar mass)
0.05 mole → = x g
X = 106 x 0.05 = 5.3 g
Mass =no. of moles x molar mass=
=0.05 ×((23x2)+12+(16x3))=5.3g
Na2CO3.XH2O→Na2CO3+XH2O
14.3g. 5.3g
So, mass of water =14.3- 5.3=9g
% of Water= 62.93%