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Since these are aqueous solutions, the solvent is water. The solute is urea, CO(NH2)2.
Molar mass of urea: (12.01) + 16.00 + 2(14.01 + 2(1.008)) = 60.06 g/mol.
a. 2.577 m indicates that there are 2.577 mol. of solute per 1000 g of solvent and the
calculations are based on that ratio.
60.06 g urea
2.577 mol. x = 154.8 g urea
1 mol. urea
1000 g 1 mol. H 2 O
1 kg x x = 55.49 mol. H 2 O
1 kg 18.02 g H 2 O
1000 g 1000 g
mass % = x 100% = = 86.58%
(1000 g + 154.8 g) 1155 g
154.8 g
ppm solute = x 10 6 = 1.340 x 10 5
(1000 g + 154.8 g)
55.49 mol.
X H 2O = = 0.9556
(55.49 mol. + 2.577 mol.)
b. 45.0 mass % of solvent means that 45.0 g of solvent are present for each 100.0 g of
solution. Calculations are then based on this ratio.
1 mol. H 2 O
45.0 g x = 2.50 mol. H 2 O
18.02 g
mass of solute = 100.0 g (total) – 45.0 g (water) = 55.0 g CO(NH2)2
1 mol. urea
55.0 g urea x = 0.916 mol. urea
60.06 g urea
0.916 mol. urea
molality = = 20.4 m (remember to convert mass of solvent to kg)
0.0450 kg H 2 O
55.0 g urea
ppm solute = x 106 = 5.50 x 105
100 g
2.50 mol.
X H 2O = = 0.731
(2.50 mol. + 0.916 mol.)
mass of solute
c. ppm = x 10 6 = 4768 g
mass of solution
If we assume a total mass of 106 g, then the mass of solute = 4768 g by definition. Any
assumption for mass is valid here, this one was chosen for simplicity.
1 mol. urea
4768 g urea x = 79.39 mol. urea
60.06 g urea
1 mol.
10 6 g - 4768 g = 995232 g; 995232 g H 2 O x = 55244.0 mol. H 2 O
18.0152 g
55244.0 mol.
X H 2O = = 0.9986
(55244.0 mol. + 79.39 mol.)
9.95232 x 10 5 g
mass % = x 100% = 99.5232%
10 6 g
79.39 mol.
molality = = 0.07977 m
995.232 kg
d. Xsolvent = 0.815 indicates that there are 0.815 moles H2O per 1 mole of solvent and solute
combined. Consequently, there must be 0.185 mol. (1-0.815) urea.
60.06 g urea
0.185 mol. urea x = 11.1 g urea
1 mol. urea
18.02 g
0.815 mol. H 2 O x = 14.7 g H 2 O
1 mol.
0.185 mol. urea
= 12.6 m (remember to convert mass of solvent to kg)
0.0147 kg H 2 O
mass of solvent 14.7 g
Mass % = x 100% = x 100% = 57.0%
total mass (11.1 g + 14.7 g)
mass of solute 11.1 g urea
ppm = x 10 6 = x 10 6 = 4.30 x 10 5
mass of solution (11.1 g + 14.7 g)
The compound which exhibits intermolecular forces most similar to water will be the more
soluble in water (like dissolves like). Recall that water has dispersion, dipole, and H-bonding
forces.
c. LiCl: ionic
C2H5Cl: dispersion and dipole forces
LiCl would be more soluble because it is ionic and ionic compounds generally exhibit
high solubility in water.
X H 2C 2O 4 = 0.018
Assuming 1 mole total, this means we have 0.018 mol. H2C2O4 and 0.982 mol. water
(1.00 - 0.018 = 0.982). The next step is to calculate the masses associated with these
quantities, and from that the mass of solution and volume of solution.
18.02 g H 2 O
0.982 mol. H 2 O x = 17.7 g H 2 O
1 mol. H 2 O
90.04 g H 2 C 2 O 4
0.018 mol. H 2 C 2 O 4 x = 1.6 g H 2 C 2 O 4
1 mol. H 2 C 2 O 4
1 mL 1L
(17.7 + 1.6) g solution x x = 0.0184 L
1.05 g 1000 mL
Now one can either:
1. Calculate molarity (mol./L) and convert mol./L to grams/L (using molecular mass) or
2. Directly calculate grams of H2C2O4 in one liter (as shown below)
1.6 g H 2 C 2 O 4
1.00 L solution x = 87 g H 2 C 2 O 4
0.0184 L solution
Thus, to prepare the prescribed solution, one must dissolve 87 g H2C2O4 in enough water to
make 1.00 L of solution.
40. Refer to Sections 10.3 and 3.3, and Example 10.7.
Use the freezing point depression to calculate molality, and from that, moles of the compound
and the compound's molecular mass.