Solution Slot - 2 (Chemistry) Page # 10

Exercise - V JEE-Problems
1. Eq. of H2O2 = Eq. of I2 3. nf. of FeC2O4 = 3
Equivalent of KMnO4 = Eq. of FeC2O4
nf of H2O2 = 2 and nf. of I2 = 2
nKMnO4  5  1 3
 M  2  5 = 0.508  2 3
1000 254  nKMnO 4 
5
 M = 0.4
 Volume strength = 0.4 x 11.2 = 4.48
4. SO 32   SO 24
2. Let the Fe3O4 = xg and Fe2O3 = yg nf = 2
Fe 3 O 4  Fe 2  and Fe 2 O 3  Fe 2  nKMnO4  5  1 2
nf = 2 nf =2/3 nf = 2 nf=2/3
2
x y  nKMnO 4 
mole of Fe 3O 4  mole of Fe 2O 3  5
232 232
3x 2y
mole of total Fe2+ produced  
5. O3  2KI  H2O  2 KOH  I2  O 2
232 160
In 20 ml of diluted solution nf  2 nf  1 nf  2

 3x 2y  1
mole of Fe 2      I2  2Na 2S 2 O 5  Na 2S 4 O 6  2Na I
 232 160  5
nf  1
Eq. of I2 produced in 100 ml diluted solution
= eq. of Fe3O4 + eq. of Fe2O3 Let the mole of O 3  nO3 STP
x y eq. of O3 = eq. of I2 = eq. of Na2S2O3
 2   2  2 x  2y
232 160 232 160  1 1 
 nO  2 = eq. of I2 =  40     1  nf. of Na2S2O3
 2x 2y  1
3
 10 1000 
Eq. of I2 in 20ml    
 232 160  5 1 1
In 20ml solution  n O 3  40    2  10  3  0.002
10000 2
Eq. of I2 = Eq. of Hypo
 Let the total mole of O2 + O3 are ntotal
 2x 2y  1 0 .5  11  2
    2  nf. of Hypo 1
 232 160  5 1000 at NTP : ntotal =  0.0446
22.4
nf of I2
 nO2  0.0446  0.002  0.0426
x y
 232  160  0 .01375    (1) mass of O2 = 0.0426 x 32 = 1.3632g
mass of O3 = 0.002 x 48 = 0.096g
In 50ml solution
0.096
% by mass of O 3   100
mole of Fe 2    3 x  2y   1 1.3632  0.096
 232 160  2
2+ 0.096
eq. of Fe = Eq. of KMnO4   100  6.58%
1.459
 3x 2y  1 12.80  0.25 One photon consumed by one O3 moleule
    1   5  nf of KMnO 4
 232 160  2 1000  no. of photon = no. of O3 moleule = 0.002 x NA
= 1.2 x 1021 photons
3x 2y
   0.032    ( 2)
232 160 0.10
from eqn (1) & (2) 6. KIO 3  KI  I2 mole of KIO3 =
y = 1.48g x = 1.044g 214
nf  5 nf  1 nf  5 3
1.044 Eq. of KIO3 = Eq. of I2 produced
% of Fe 3 O 4   100  34.8%
3 0.10
 5  nI2  5 3
1.48 214
% of Fe 2 O 3   100  49.33%
3

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 Page # 11 Solution Slot - 2 (Chemistry)

0.10  3 0.3 2KMnO 4  3MnSO 4  2H2O  5MnSO 4  K 2SO 4  2H2 O

 nI2  
214 214 nf  3 nf  2 (ppt ) nf  6 / 5

I2  Na 2 S 2 O 3  I  Na 2 S 4 O 6 MnO 2  Na 2 C 2O 4  2H2 SO 4  MnSO 4  CO 2  Na 2 SO 4  2H2 O

nf  2 nf  1 (ppt )
nf  2 nf  2
Eq. of I2 = Eq. of Na2S2O3
: Different nf of MnO2 in these reaction
45
nI2  2  M 1
1000 m.eq. of H2O2 = m. eq. of KMnO4 -----(1)
0 .3 45 MH2O2  20  2 = MKMnO4  20  5
 2  M
214 1000 m.eq. of MnSO4 = m.eq. of KMnO4
300  2 nMnSO4  2  20  MKMnO4  3
 M  0.0623 M
45  214
10 × MMnSO4  2  20  MKMnO4  3
0 .5
7. CuCO 3  0.5g  mole = meq. of MnO2 = nMnO2 × 6/5
123.5
CuCO 3  H2SO 4  CuSO 4  H2 CO 3  nMnO 2  MKMnO 4  20  3  5 6 m. mole  
mole of CuCO3 = mole of H2SO4 m.eq. of MnO2 = m.eq. of Na2C2O4
0 .5
 0.5  V
 MKMnO 4  20  3  5  2  10  0.2  2
 6
123 .5
46 4
1  MKMnO  
4
 V L  8.097 ml 20  6  5 100
123.5
8. N = M x nf ; nf = 2= 0.3 x 2 = 0.6 4
 from eqn (1) MH2O 2  20  2   20  5
100
4  20  5 10
MH2O 2   MH2O2  0.1
100  20  2 100

13. Mohr salt : (NH4)2 Fe(SO4)2. 6H2O

Fe is in +2 state
9. Ca 3P2  6 H2 O  3 Ca(OH)2  2PH3
nf of Mohr salt = 1 nf of K 2 Cr2 O 7  6
2 mole phosphine produced and 3 mole caluim
hydroxide produced Ans. (C) Eq. of Mohr Salt = Eq. of K 2Cr2 O 7
6.3 nx1 = 1x6
10. H2 C 2O 4 . 2H2 O  6.3g  mole  0.05 mole n = 6 Ans. (D)
126
0.05 mole oxalic acid present in 250ml
14.
 In 10ml
Eq. of H2C2O4. 2H2O = Eq. of NaOH (A) O 2  O 2  O 22  disproportionation (s)
10 Redox reaction (p)
  V
 0.05   2  0. 1 
 250  1000 (B) CrO24  H  Cr2O 72 Ans. : R

0.05  10  2  1000
Ans. (A) (C) MnO 4  NO 2  H   Mn 2   NO 3  H2O (P, Q)
 V  40ml
250  0.1 trigonal planer

11. n factor of K2Cr2O7 = 6 (D) NO 3  H2SO 4  Fe 2  Fe 3   NO  SO 24  H2O (p)

M. mass (Re dox Re action )
 Eq. mass of K2Cr2O7 = Ans. (B)
6 O
15. P4  NaOH  H2 O  PH3  NaH 2PO 2 Ans. : (B)
12. given reactions are ( disproport ionation Rxn)
2KMnO 4  5H2 O 2  3H2 SO 4  2MnSO 4  K 2 SO 4  8H2 O  SO 2
nf  5 nf  2

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IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, email-info@motioniitjee.com