(12) (3).

Chemical species Hybridisation of

(1) (4). % by mole of carbon = central atom
= 20% ICl2– sp3d
(2) (4). No. of molecules in 4.25 g NH3 IF6– sp3d3
ICl4– sp3d2
BrF2– sp3d
= (13) (2). Density of water = 1 g/mL
Mass of 1 cm3 water = density × volume
∴ No. of atoms = =1×1=1g
= 6 × 1023
(3) (3). N2(g) + 3H2(g) → 2NH3(g) No. of mole of water molecule in 1 cm3 =
(1) 0.5 mol 2 mol No. of molecule of H2O in 1 cm3
(LR)
(2) 1 mol 3 mol (completion)
= × NA = × 6 × 1023 = 3.3 × 1022
(3) 2 mol 5 mol (LR)
(14) (1).
(4) 1.25 mol 4 mol
(LR)
(4) (4).

(5) (1). Ionic character ∝

(6) (3).
(15) (1).
(16) (3). ClO– B.O = 1.0
ClO2– B.O = 1.5
ClO3– B.O = 1.66
ClO4– B.O = 1.75
OR
Empirical formula = NO2 and molecular ClO– < ClO2– < ClO3– < ClO4–
formula = N2O4 B.O. 1.0 1.5 1.66 1.75
(7) (2). For isoelectronic species the size is
compared by nuclear charge. (17) (3).
(8) (2). According to (n + ) rule :
3p < 3d < 4p < 4d
(9) (3). Intermolecular forces ↑, a ↑
since NH3 is a polar molecule it will have
greater intermolecular attraction.
(10) (2). Non-reacting gases follow Dalton's law of
partial pressure.
(11) (3). O2 to O2– el– enters in
el– is entered in ABMO orbital.
 = 1.506 = 1.51 mol/kg
(23) (2). CO2 (g) + C (s) → 2CO (g)
Initially 1L Excess 0
After reaction 1–x Excess 2x
Total volume of gases after reaction
= 1 + x = 1.8 L
∴ x = 0.8 L
and volume of CO = 2x = 1.6 L
(18) (4). hν – φ = KE

∴ Moles of CO at STP = = 0.0714

⇒

(24) (4). CxHy + O2 → xCO2 + H2O

⇒

10 10x
...(1)
By given data, .... (1)
⇒ ...(2) 10x = 40 .... (2)
Divide (1) and (2) ∴ x = 4, y = 6 ⇒ C4H6
(25) (4). N–3 → 1s2 2s2 2p6
Li+ → 1s2
(1.5)2 = ⇒
Mg+2 → 1s2 2s2 2p6
(19) (2). Volume strength = 11.2 × molarity = 11.2
Molarity = 1 M O–2 → 1s2 2s2 2p6
Strength = 34 g/L F– → 1s2 2s2 2p6
Na+ → 1s2 2s2 2p6
N–3, O–2, F– and Na+ are isoelectronic.
% w/w = (26) (4). Graph of |ψ2| v/s r, touches r axis at 1
(20) (2). sp3d2 (2Lp + 5σ) point so it has one radial node and since at
OR r = 0, it has some value so it should be for
sp3d3 hybridisation with 2LP. 's' orbital.
(21) (3).
∴ n –  – 1 = 1 where  = 0 ⇒ n – 1 = 1
∴ n = 2 ⇒ '2s' orbital.

(27) (4).
As b ↑ ⇒ slope ↑ For N2, O2, H2
Hence, Xe, will have highest slope.

(22) (3). Vmp of N2 (300K) < Vmp of O2 (400K)

100 gm solution has 20 gm KI
80 gm solvent has 20 gm KI
< Vmp of H2 (300K)
(28) (3). C3H8(g) +5O2(g) → 3 CO2(g) + 4 H2O ()
Each 1g of C3H8 requires 3.63 g of O2.
P4(s) + 5O2(g) → P4O10(s)
Each 1g of P4 requires 1.29 g of O2.
4 Fe(s) + 3 O2(g) → 2Fe2O3(s)

2
 Each 1g of Fe requires 0.428 g of O2.
2 Mg(s) + O2(g) → 2MgO(s)
Each 1g of Mg requires 0.66 g of O2. m/sec
Therefore least amount of O2 is required in = 5.76 × 105 m/s
option (3).

(29) (4). (40) (1).

Here, n1 = 3, n2 = 4

(41) (3). r ∝ n2

(42) (4). All are symmetrical molecule.

(43) (2). EN ∝ % s-character.
(44) (2). Bond angle for multiple bond > bond
(30) (3). 5 [MA + 2 MB] = 125
angle for single bond.
MA + 2MB = 25 ....(1)
OR
2MA + 2MB = 30 ....(2)
Multiple bond exert more repulsion.
From eq. (1) & (2)
MA = 5, MB = 10
(31) (1). Only one electron can have a definite set (45) (1). Molarity =
of four quantum numbers.
(32) (2). NH2–, NH3 NH4+
sp3 sp3 sp3
wt (C12H22O11) = 68.4 gram
I.P. 2 1 0
(33) (1). (I.E)He+ = ((I.E.)H × Z2 = 13.6 × 4
= 54.4 eV
(46) (1). = [M1T–2]
(34) (2). PI3 > PBr3 > PCl3 > PF3
If C.A. = same Hybridisation same
L.P. = same
(47) (3).
Bond angle ∝ Size of side atom
(35) (1). Stability ∝ B.order If B.order is same

Stability ∝
(36) (1). BeCl4–2 – sp3 – 109° 28'
BeCl3– –– sp2 – 120°
BeCl2 – sp – 180° (48) (3). ....... (1)
(37) (3). X = polar and v = g t ....... (2)
Y = Non-polar

(38) (1). (49) (1). Percentage error

(39) (2).
3
(50) (3). From the figure for the equilibrium of the
system T = mg
Also,

u = 5/3 m/s

(54) (4).

⇒
(51) (4). For swimmer to cross the river straight
4 sin θ = 2 ⇒ sin θ = 1/2 ⇒ θ = 30°
So, angle with direction of river flow
= 90° + θ = 120°
(55) (1). The situation is shown in figure.

50m/s2
(52) (1).

When the car moves towards right with

acceleration a the rope carrying the mass
makes an angle θ.

Applying equilibrium conditions, Acceleration,

Σ Fx = 0
⇒ F1 + 1 sin 45º – 2 sin 45º = 0 ⇒
or F1 = 2 sin 45º – 1 sin 45º (56) (2). Because volume, length and area are
defined by same fundamental quantity.
= 1 sin 45° = (57) (2). Initial velocity of food packet
Σ Fy = 0 u = 4 m/s (upward)
it a acceleration = – g downwards
v = +4 – 9.8 × 3 = –25.4 ms–1
⇒ F2 = 1 cos 45º + 2 cos 45º –ve means downwards
(53) (1). Equation of trajectory is given as (58) (3). Range will be same for time t1 & t2, so
y = 2x – 9x2 ........ (1) angles of projection will be θ & 90º – θ.
Comparing with equation :

y = x tan θ – ........ (2)

We get; tan θ = 2 ∴

4
 and

(65) (4). m = 20 g , u = 1 m/s, v = ?

(59) (2). Time of flight for each ball = 1s S = 20 × 10–2 m

(60) (2). p = k saIbhc

v2 = u2 + 2as
where k is dimensionless constant
MLT–1 = (MT–2)a (ML2)b (ML2T–1)c
a+b+c=1
2b + 2c = 1
–2a – c = –1
a = 1/2, b = 1/2, c = 0 = 0.7 m/s
s1/2I1/2h0
(61) (1). Momentum p = mv .....(1) (66) (4).
and for motion under gravity Tension in the string, T = m(g – a)

......(2)

(62) (3). Speed of the child w.r.t. moving belt=

9km/h. (67) (3).
As the belt is moving with a speed of 4
km/h, hence w.r.t. observer on the
Average speed =
platform, speed of child in the direction of
motion of the belt = 9 + 4 = 13 km/h
(63) (3).

OR

Average speed for A to B =

2T cos θ = mθ ; = 30 km/hr
cos θ less or θ more tension more.
(64) (3). Time for 5m fall = 1 s Average speed for C to D =
= 30km/hr
Average speed for A to D

It means each drop will released after

every (1/2) s. (68) (2). Given, u = 0

5
 ⇒ S2 = 4S1 (79) (3).
(69) (3). Total Area = A1 + A2 + ...... A7 (80) (4). x = at + bt2 – ct3
= A + A + ......... 7 times = 37.03 m2. v = = a + 2bt – 3ct2
Addition of 7 terms all having 2 terms a = = 2b – 6ct = 0 ⇒ t =
beyond decimal, so final answer must have v(at t = b/3c) = a + 2b – 3c
2 terms beyond decimal (as per rules of (81) (4). µmg = ma ⇒ µg = a
significant digits.)
(70) (3). During the first 5 seconds of the motion,
the acceleration is –ve and during the next
5 seconds it becomes positive. (Example: a
stone thrown upwards, coming to
momentary rest at the highest point.) The This equation is free from mass m.
distance covered remains same during the So this is true for all values of m.
two intervals of time. (82) (4). Net force applied by block on the inclined
(71) (2). 10 g = µ (m + 20)g plane is equal to the weight of the body.
⇒ 10 = 0.25 (m + 20) ⇒ m = 20 kg
(72) (4). Relative velocity of policeman w.r.t. the
thief is 10 – 9 = 1 m/s. Since, the
separation between them is 100 m, hence
the time taken will be 100 s.
(73) (1). vrel = 45 + 36 = 81 km/h
N = mg cos θ
S = vrel × t = 81 × = 6.75 km fs = mg sin θ

(74) (2).

S = 2 cos15° × t – g sin 30° t2 (83) (2).

Put values and solve, S = 20 cm As acceleration depending on time so its
(75) (3). It is only possible when particle goes upto not a case of constant acceleration hence
maximum height in 5th and come back in
6th. So, v = u – gt ⇒ 0 = u – 9.8 × 5
⇒ u = 49 m/s

(76) (2).
(77) (3). The fourth coin is under the weight of six
coins above it. Hence, Reaction of the 4th (84) (1).
coin on 5th coin = Force on the 4th coin
due to 5th coin = 6 mg
(78) (3). ΔP = Area under F – t graph
aAmax = µ g = 2 m/s2
= × 8 × 2 – 2 × 1 = 6 kg-m/sec

6
 (90) (1). Velocity of paratrooper after bailing out
= 0 after falling 50m,
v2 = 2ah = 2 × 9.8 × 50 = 980
Let he cover distance h, with retardation of
F–8=4×2
2m/s2 then 32 = v2 – 2 × 2 × h1
F = 16 N
9 = 980 – 4h1
(85) (4). sin θ = 3/5
or h1 = 242.75 m
∴ Total height = 242.75 + 50 ≈ 293 m
(91) (3) (92) (2) (93) (3)
(94) (2) (95) (2) (96) (4)
(97) (4) (98) (4) (99) (4)
(100) (1) (101) (2) (102) (2)
Clearly, base of the triangle is 4 units (103) (3) (104) (1) (105) (3)
µ = tan θ = 3/4 = 0.75 (106) (3) (107) (2) (108) (4)
(86) (3). (109) (4) (110) (3) (111) (2)
(112) (2) (113) (3) (114) (3)
(115) (1) (116) (3) (117) (1)
(118) (2) (119) (4) (120) (3)
Acceleration (121) (1) (122) (1) (123) (3)
(124) (3) (125) (3) (126) (4)
(127) (1) (128) (1) (129) (3)
Applying NLM on half portion of rope (130) (2) (131) (1) (132) (1)
T = (m1 + m2) a (133) (3) (134) (3) (135) (4)
T = (2 + 0.5) × 2 = 5 N (136) (4) (137) (2) (138) (2)
(87) (1). (139) (3) (140) (2) (141) (2)
(142) (3) (143) (3) (144) (1)
(145) (3) (146) (3) (147) (1)
(148) (2) (149) (3) (150) (2)
= 10 × 103 N = 10 kN (151) (2) (152) (3) (153) (2)
(88) (3). All blocks will move with same (154) (1) (155) (2) (156) (2)
acceleration (157) (4) (158) (2) (159) (4)
(160) (1) (161) (3) (162) (3)
(163) (3) (164) (1) (165) (3)
F cos 60° = total mass × acc. (166) (1) (167) (4) (168) (3)
F cos 60° = (8 + 6 + 4 + 2) × 1 (169) (3) (170) (2) (171) (3)
F × (1/2) = 20 ⇒ F = 40 N (172) (2) (173) (2) (174) (3)
(89) (2). (175) (3) (176) (1) (177) (2)
(178) (2) (179) (4) (180) (3)