NEET CHAPTER TEST

CHEMISTRY
CHEMISTRY Topic : Solution [SOLUTIONS]

(1) (3). Vapour pressure is not a colligative property. (9) (2). Benzene-methanol are the liquid pairs
(2) (2). V = nRT shows a positive deviation from Raoult’s
500V1 nR  283 V1 1 law.
 ;  so V2 = 5V1 (10) (4). Two sucrose solutions of same molarity
105.3V2 nR  298 V2 5
prepared in different solvent will have
(3) (2). Tf = kf × m  different freezing point.
Tf 0.186 (11) (2).
  m    0.1m
kf 1.86 78 46
nb   1 ; nt   0.5
Tb = kb × m = 0.512 × 0.1 = 0.0512 78 92
K  WB 1 0.5
(4) (2). Tf  f xb  , xt 
M B  WA 1.5 1.5
75  1

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For cane sugar solution, Pb  Pb0 .x b   50 torr
Kf  5 1.5
2.15 K = (12) (4). M1V1 + M2V2 = M3 (V1 + V2)
342  0.095
720  624
(95 g of water = 0.095 kg) M3  = 1.344 M
For glucose solution, 1000
Kf  5 (13) (4). Equimolar solution in the same solvent
Tf 
LA
180  0.095
have same boiling and same freezing point.
Tf Kf  5 P w  MA 18  18
342  0.095 (14) (3).  xB  B =  0.01
  P0 M B  w A 180  178.2
2.15 180  0.095 Kf  5
(P0  P) P
Tf 
342
 2.15 = 4.085 K or  0.01
180 P P
Freezing point of glucose solution P = (1 – 0.01) × P0 = 0.99 × 760
= 273.15 – 4.085 = 269.07 K = 752.4 torr
i 1 (15) (2). Mass of 1000ml solution
(5) (2).  = 0.3. Thus, = 0.3 or i = 1.3 = 1000 × 1.02 = 1020 gm.
2 1
Mass of water = 1020 – 2.05 × 60
A
 Tf = 1.3 × 0.2 × 1.85 = 0.481
= 897gm.
(6) (3). Ba(OH)2 + 2HCl  BaCl2 + 2H2O 2.05  1000
1 mole 2 mole m = 2.285 mole/kg.
897
For HCl, M = N = 0.1 (16) (3). As NaCl is a strong electrolyte, it
N1V1 = N2V2, undergoes dissociation completely. Thus,
B

25 × N1 = 0.1 × 35 van't Hoff factor will be same for all these

0.1  35 0.1  35 solutions, iA = iB = iC.
N1  or M   0.07
25 25  2 (17) (4). Molarity
(7) (1). The concentration of particles is highest in moles of solute 120  1.15
=   1000
0.01M Na2SO4 and so, elevation of boiling volume of sol. ( ) 60  1120
point will be maximum. = 2.05 M
(8) (3). H3PO3  Dibasic acid and it will react (18) (2). Tf = i × Kf × m
with KOH as x
2.8 = 1 × 1.86 ×
H3PO3 + 2KOH ––– K2HPO3 + 2H2O 62  1
20  0.1 V  0.1 2.8  62
  ; V = 20 × 2 = 40ml. x  93gm
1 2 1.86

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 M1V1  M 2 V2 10
(19) (1). M f  (25) (1). No. of moles of glucose =
V1  V2 180
3 1 = 0.0555 mol
0.5   2  90
 4 4  0.875 M No. of moles of water = = 5 mol
1 18
(20) (3). Tf = i Kf m Number of moles of solution = 5.0555 mol
Mole fraction of glucose
For glucose, i = 1
No. of moles of glucose
For MgCl2, i = 3 
No. of moles of solution
Thus, the depression in freezing point
0.0555 mol
(Tf) of a 0.01 M MgCl2 solution is about   0.01
5.0555 mol
three times of that of 0.01 M glucose

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(26) (1). Mixture of methanol and acetone shows
solution.
positive deviation from Raoults law. In
(21) (3). All solutes are non-electrolytes
pure methanol, molecules are hydrogen
wRT 1
 Osmotic pressure, P   P bonded. On adding acetone, its molecules
MV M get in between the host molecules and
Mglucose = 180, Murea = 60, break some of the hydrogen bonds between
Msucrose= 342 them.
LA
10 10 10 (27) (1). Tf i
P1  , P2  , P3 
180 60 342 As C5H10O5 and C12H22O11 are
 The decreasing order is non-ionisable thus i = 1 for them for KI,
urea > glucose > sucrose i = 2 and for Al2(SO4)3, i = 5
P2 > P1 > P3 Thus i is maximum for Al2(SO4)3, thus
(22) (4). M1V1 = M2V2 depression in freezing point is highest for
0.02 M × 4L = M2 × 5 L Al2(SO4)3 thus this will have lowest
0.02  4 freezing point.
M2  = 0.016 M
5 2  1 WB M A 1 1 200
A
(28) (1).     
Here, molality will be equal to molarity as 2 M B WA 2 M B 20
for NaCl, molecular weight is equal to its 200  2
equivalent weight. MB   20
(23) (1). N1V1 + N2V2 + N3V3 = N (V1+ V2 + V3) 20
(29) (3). Higher the value of KH, the lower is the
50 × 10 + 25 × 12 + 40 × 5 = N (1000)
B

500 + 300 + 200 = N (1000) solubility of gas in the liquid.

1000 = N (1000) ; N = 1
(24) (3). For 10–4 M NaCl , i = 2
10–4 M Urea , i = 1
10–3 M MgCl2 , i = 3
10–2 M NaCl , i = 2
More the value of i, more will be the
elevation in boiling point hence increasing
order of boiling point is
10–4 M Urea < 10–4 M NaCl
< 10–3M MgCl2 < 10–2 M NaCl
Thus, the order of increasing solubility is
Ar < CO2 < CH4 < HCHO
KH value: 40.39 1.67 0.413 1.83 × 10–5
(30) (2). p = KH x
Higher the value of KH at a given pressure,
the lower is the solubility of the gas in the
liquid.
(31) (4). Tf i
i for C2H5OH = 1 ; i for Ba3(PO4)2 = 5
i for Na2SO4 = 3 ; i for Li3O4 = 4

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 Thus depression in freezing point will be (40) (1). PT  PP0 X P  PQ0 X Q
in order:
3 2
C2H5OH < KCl < Na2SO4 < Li3PO4 PT  80   60 
< Ba3(PO4)2 5 5
PT  48  24  72 torr
Thus freezing point will be in order
Ba3(PO4)2 < Li3PO4 < Na2SO4 (41) (2). As Tf = Kf m ; Tb = Kb m
< KCl < C2H5OH Tf Tb
m= 
(32) (1). Tf = i Kf m = 2 × 1.86 × 0.5 = 1.86°C Kf Kb
Tf = T°f – Tf = 0 – 1.86 = –1.86°C Tf  Tb
Kf
(33) (2). Tb = i Kb m Kb
Tb – T°b = i Kb m Tb = 100.18 – 100 = 0.18°C

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Thus, boiling point of solution (Tb) 1.86
Tf = 0.18 × = 0.654°C
depends on value of van't Hoff factor (i). 0.512
For 1.0 M Na2SO4 solution, i = 3 hence, it As the freezing point of pure water is 0°C,
has highest boiling point.  Tf = 0 – Tf
(34) (1). glycerine = glucose Tf = – 0.654
n1 n
LA (42) (2). One molal solution means one mole solute
RT  2 RT present in 1 kg (1000g) solvent
V1 V2
i.e., mole of solute = 1
10.2 1 2 1000
   Mole of solvent (H2O) =
1000g 1000

M 1 180 100 18g 18
10.2  18
 M  91.8g Mole fraction of solute
2 1 18
(Density of water = 1g/cm3) =  = 0.018
 1000  1018
(35) (1). Higher the value of KH, lower is the 1  
18 
solubility of gas in the liquid.
(43) (4). The ratio of pentane to hexane = 1: 4
A
(36) (1). Depression in freezing point is directly
Mole fraction of pentane = 1/5
proportional to number of ions. Lower the
Mole fraction of hexane = 4/5
number of ions, lower will be the
Vapour pressure = XPPP° + XHPH°
depression in freezing point and higher
will be the freezing point. Thus maximum 1 4 
   440   120 = 184 mm
freezing point is of glucose. 5 5 
B

(37) (2). KCl  K+ + Cl–, thus, i = 2  Vapour pressure of pentane in mixture

NaCl  Na+ + Cl–, thus, i = 2 = Vapour pressure of mixture × Mole
K2SO4  2K+ + SO42– thus, i = 3 fraction of pentane in vapour phase
(38) (2). (iii) and (iv) will form ideal solutions 88 = 184 × Mole fraction of pentane in
hence do not form azeotropes. Azeotropes vapour phase
have same composition in liquid and Mole fraction of pentane in vapour phase
vapour form when distilled. 88
= = 0.478
(39) (4). If solute dissociates in the solution, e.g. 184
NaCl, MgCl2, BaCl2, etc., the number of (44) (1). Osmotic pressure of urea
particles in solution will be more than that nRT 10
V  nRT      0.821  T
actually dissolved and value of colligative V 60
properties will be higher. [1 dm3 = 1 litre]

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5% solution means For isotonic solution, 1 = 2
100ml 5gm ; 1000ml 50g/L 10 50
Osmotic pressure of solution having  0.821  T   0.821  T
60 M
non-volatile solute
M = 300g mol–1
50
2   0.821  T 1 1000
M (45) (3). T  K f m  5.12    0.4 K
250 51.2

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LA
A
B

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