DATA TABLE:(exp 4)

Data table for solubility measurement at different temperatures:

Titration
Mass Data(mL) Conc. Solubi
Mass
of 5mL of Mass lity
1/T of
Temp saturated succinic of (S)
(1/K) solven lnS
(ºC) succinic Acid solute
10-3 I F D t
acid (g) (solute) (g) (g/
(g)
N 100g)

16 3.34 5.112 19.0 31.8 12.8 1.22 0.72 4.392 16.44 2.80
31 3.30 5.234 20.7 34.3 13.6 1.295 0.764 4.466 17.11 2.84
36 3.20 5.32 2.0 16.4 14.4 1.37 0.808 4.512 17.92 2.89
41 3.18 5.44 16.5 31.4 14.9 1.42 0.84 4.6 18.21 2.92

GRAPH:

We can determine the heat of solution from lnS vs (1/T) graph.

f(x) = NaN x + NaN

R² = 0 lnS vs 1/T
12

10

6
lnS

0
0 2 4 6 8 10 12
1/T(1/K)
CALCULATION:

We know, Van’t Hoff equation is, lnS = -ΔH/R (1/T) + constant. If we compare the equation
with y = mx + c, we will find the slope, m = -ΔH/R in a lnS vs 1/T graph.

From the graph, we can get the value of slope, m = -678.77

Now, -ΔH/R = -678.77

ΔH = (678.778.314) [ R=8.314 J/molK]

= 5643.29 J/mol

= 5.64 kJ/mol
DATA TABLE:(exp 5)

Data table to determine the concentration of I2 solution:

Burette Reading Required

Volume
Conc. of (mL) Volume Conc. of
Of I2
Layer Na2S2O3 Of I2
Solution
(N) Initial Final Na2S2O3 (N)
(mL)
(mL)
CCl4 20 0.1 5.1 26.2 21.1 0.1055
Water(aq KI) 50 0.1 7.8 35.6 27.8 0.0556
CCl4 10 0.1 2.0 7.5 5.5 0.055
Water(aq KI) 50 0.1 8.5 26.6 18.1 0.0362

CALCULATION:

For system-I, (20 mL CCl4 & 50 mL aq KI)

I2 in organic layer (CCl4 layer), VI2NI2 = VNa2S2O3N Na2S2O3

20NI2 = 21.10.1

NI2 = 0.1055 N

[I2] in CCl4 = 0.05275 M (For I2 e=2)

I2 in aqueous layer, VI2NI2 = VNa2S2O3N Na2S2O3

50NI2 = 27.80.1

NI2 = 0.0556 N

[I2] in aqueous layer = 0.0278 M (For I2 e=2)

Here, Distribution Co-efficient, KD = 82

So, Free [I2] in aqueous layer = ([I2] in CCl4)/ KD

= 0.05275/82

= 6.4310-4 M

Now, [KI3] in equilibrium = Free [I2] in aqueous layer & in [KI3] - Free [I2] in aqueous layer

= 0.0278 - 6.4310-4

= 0.0272 M

[KI] in equilibrium = [KI]initial – [KI]reacted

= 0.1- 0.0272

= 0.0728 M

Now,

Kc = ([KI3] in eqb)/([I2] in eqb[KI] in eqb)

= 0.0272 / (6.4310-40.0728)

= 581.1 Lmol-1

For system-II, (10 mL CCl4 & 50 mL aq KI)

I2 in organic layer (CCl4 layer), VI2NI2 = VNa2S2O3N Na2S2O3

10NI2 = 5.50.1

NI2 = 0.055 N

[I2] in CCl4 = 0.0275 M (For I2 e=2)

I2 in aqueous layer, VI2NI2 = VNa2S2O3N Na2S2O3

50NI2 = 18.10.1

NI2 = 0.0362 N

[I2] in aqueous layer = 0.0181 M (For I2 e=2)

Here, Distribution Co-efficient, KD = 82

So, Free [I2] in aqueous layer = ([I2] in CCl4)/ KD

= 0.0275/82

= 3.35510-4 M

Now, [KI3] in equilibrium = Free [I2] in aqueous layer & in [KI3] - Free [I2] in aqueous layer

= 0.0181 – 3.35510-4

= 0.01776 M

[KI] in equilibrium = [KI]initial – [KI]reacted

= 0.1- 0.01776

= 0.08224 M

Now,

Kc = ([KI3] in eqb)/([I2] in eqb[KI] in eqb)

= 0.01776 / (3.35510-40.08224)

= 643.7 Lmol-1