TABLE 1: Data table to determine the concentration of I2 solution in organic and aqueous layer:

Required
Volume
Conc. of Burette Reading Volume Conc. of
Of I2
Layer Na2S2O3 Of I2
Solution
(N) Na2S2O3 (N)
(mL) Initial Final
(mL)
CCl4 20 0.1 5.1 26.2 21.1 0.1055
Water 50 0.1 7.8 35.6 27.8 0.0556
CCl4 10 0.1 2.0 7.5 5.5 0.055
Water 50 0.1 8.5 26.6 18.1 0.0362

CALCULATION:

For system-I, (20 mL CCl4 & 50 mL KI(aq))

I2 in CCl4 layer,

VI2NI2 = VNa2S2O3N Na2S2O3

20NI2 = 21.10.1

NI2 = 0.1055 N

[I 2 ]CCl = 0.05275 M
4
(For I2 e=2)

I2 in aqueous layer, VI2NI2 = VNa2S2O3N Na2S2O3

50NI2 = 27.80.1

NI2 = 0.0556 N

[I 2 ]aq = 0.0278 M (For I2 e=2)

Here, Distribution Coefficient, Kd = 82

 [ I 2 ] ∈CCl4
So, Free [I2] in aqueous layer =
Kd

= 0.05275/82

= 6.4310-4 M

Now, [KI3]eq = [I2]total - [I2]aq

= 0.0278 - 6.4310-4

= 0.0272 M

[KI]eq = [KI]initial – [KI3]eq

= 0.1- 0.0272

= 0.0728 M

Now,

Kc = ¿¿

0.0272
=
( 6.43 10−4 0.0728 )

= 581.1 Lmol-1

For system-II, (10 mL CCl4 & 50 mL aq KI)

I2 in CCl4 layer, VI2NI2 = VNa2S2O3N Na2S2O3

10NI2 = 5.50.1

NI2 = 0.055 N

[I 2 ]CCl = 0.0275 M
4
(For I2 e=2)

I2 in aqueous layer, VI2NI2 = VNa2S2O3N Na2S2O3

 50NI2 = 18.10.1

NI2 = 0.0362 N

[I 2 ]aq = 0.0181 M (For I2 e=2)

Here, Distribution Coefficient, Kd = 82

[ I 2 ] ∈CCl4
So, Free [I2] in aqueous layer =
Kd

= 0.0275/82

= 3.35510-4 M

Now, [KI3]eq = [I2]total - [I2]aq

= 0.0181 – 3.35510-4

= 0.01776 M

[KI]eq = [KI]initial – [KI3]eq

= 0.1- 0.01776

= 0.08224 M

Now,

Kc = ¿ ¿

0.01776
=
( 3.355 10−4 0.08224 )

= 643.7 Lmol-1

Result:
For System 1, Eq. constant, Kc = 581.1 L.mol-1

For System 2, Eq. constant, Kc = 643.7 L.mol-1