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This is to certify

DIPANKAR PANKAJ SONAWANE


of Class XI- A having CBSE ROLL NO.11112
has satisfactorily completed the
“CHEMISTRY INVESTIGATORY PROJECT”
for
ALL INDIA SENIOR SECONDARY CERTIFICATE
EXAMINATION 2021-2022

Internal Principal External


Examiner Examiner

INDEX
CERTIFICATE
INDEX
INTRODUCTION
PREPARATION
EXPERIMENT
ACKNOWLEDGEMENT
I would like to express my special thanks of
gratitude to our Principal , Mr. Deepak Singh Bhati
and My Computer Teacher Mrs. Angayark anni
who gave me the golden opportunity to do this
wonderful project on the topic Hangman game,
which also helped me in doing a lot of Research and I
came to know about so many new things I am really
thankful to them.
Secondly I would also like to thank my parents who
helped me a lot in finalizing this project within the
limited time frame..
Introduction
Soap is an anionic surfactant used in conjunction with water for
washing and cleaning, which historically comes either in
solid bars or in the form of a viscous liquid. Soap consists
of sodium or potassium salts of fatty acids and is obtained by
reacting common oils or fats with a strong alkaline in a process
known as saponification. The fats are hydrolyzed by the base,
yielding alkali salts of fatty acids (crude soap) and glycerol. The
general formula of soap is Fatty end water soluble end CH3-
(CH2) n -              COONa Soaps are useful for cleaning because
soap molecules have both a hydrophilic end, which dissolves
in water, as well as a hydrophobic end, which is able to
dissolve non polar grease molecules. Applied to a soiled
surface, soapy water effectively holds particles in colloidal
suspension so it can be rinsed off with clean water. The
hydrophobic portion (made up of a long hydrocarbon chain)
dissolves dirt and oils, while the ionic end dissolves in water.
The resultant forms a round structure called micelle. Therefore,
it allows water to remove normally-insoluble matter

by emulsification.
Preparation of soap
In cold-process and hot-process soap making, heat may be
required for saponification. Cold-process soap making takes
place at a sufficient temperature to ensure the liquification of
the fat being used. Unlike cold-processed soap, hot-processed
soap can be used right away because the alkali and fat saponify
more quickly at the higher temperatures used in hot-process
soap making. Hot-process soap making was used when the
purity of alkali was unreliable.

Commercial production of soap


The most popular soap making process today is the cold
process method, where fats such as olive oil react with strong
alkaline solution, while some soapers use the historical hot
process. Handmade soap differs from industrial soap in that,
usually, an excess of fat is sometimes used to consume the
alkali (super fatting), and in that the glycerin is not removed,
leaving a naturally moisturizing soap and not pure detergent.
Often, emollients such as jojoba oil or Shea butter are added 'at
trace' (the point at which the saponification process is
sufficiently advanced that the soap has begun to thicken), after
most of the oils have saponified, so that they remain unreacted
in the finished soap. Fat in soap Soap is derived from either
vegetable or animal fats. Sodium Tallowate, a common
ingredient in much soap, is derived from rendered beef fat.
Soap can also be made of vegetable oils, such as palm oil, and

the product is typically softer. An array of saponifiable oils and


fats are used in the process such as olive, coconut, palm, cocoa
butter to provide different qualities. For example, olive oil
provides mildness in soap; coconut oil provides lots of lather;
while coconut and palm oils provide hardness. Sometimes
castor oil can also be used as an ebullient. Smaller amounts
of unsaponifable oils and fats that do not yield soap are
sometimes added for further

HOT PROCESS
In the hot-process method, alkali and fat are boiled together at
80–100 °C until saponification occurs, which the soap maker
can determine by taste or by eye. After saponification has
occurred, the soap is sometimes precipitated from the solution
by adding salt, and the excess liquid drained off. The hot, soft
soap is then spooned into a mold.
Cold process
A cold-process soap maker first looks up the saponification
value of the fats being used on a saponification chart, which is
then used to calculate the appropriate amount of alkali. Excess
unreacted alkali in the soap will result in a very high pH and can
burn or irritate skin. Not enough alkali and the soap are greasy.
The alkali is dissolved in water. Then oils are heated, or melted
if they are solid at room temperature. Once both substances
have cooled to approximately 100-110°F (37-43°C), and are no
more than 10°F (~5.5°C) apart, they may be combined. This
alkali-fat mixture is stirred until "trace". There are varying levels
of trace. After much stirring, the mixture turns to the
consistency of a thin pudding. "Trace" corresponds roughly to
viscosity. Essential and fragrance oils are added at light trace.

Introduction to the experiment


Soap samples of various brands are taken and their foaming
capacity is noticed. Various soap samples are taken separately
and their foaming capacity is observed. The soap with the
maximum foaming capacity is thus, said to be having the best
cleaning capacity. The test requires to be done with distilled
water as well as with tap water. The test of soap on distilled
water gives the actual strength of the soaps cleaning capacity.
The second test with tap water tests the effect of Ca2+ and
Mg2+ salts on their foaming capacities. Objective: To compare
the foaming capacity of various soaps.
Theory
The foaming capacity of soap depends upon the nature of the
soap and its concentration. This may be compared by shaking
equal volumes of solutions of different samples having the
same concentration with same force for the same amount of
time. The solutions are then allowed to stand when the foam
produced during shaking disappears gradually. The time taken
for the foam to disappear in each sample is determined. The
longer the time taken for the disappearance of the foam for the
given sample of soap, greater is its foaming capacity or
cleansing action.
Procedure
1. Take five 100ml conical flasks and number them 1,      2,3,4,5.
Put 16ml of water in each flask and add 8 Gms of soap.
2. Warm the contents to get a solution.
3. Take five test tubes; add 1ml of soap solution to 3ml of
water. Repeat the process for each soap solution in different
test tubes.
4. Close the mouth of the test tube and shake vigorously for a
minute. Do the same for all test tubes and with equal force.
5. Start the timer immediately and notice the rate of
disappearance of 2mm of froth. Observations:
The following outcomes were noticed at the end of the
experiment Test Tube no Vol. of soap solution Vol. of water
added Time taken for disappearance of 2mm
1. Dove 8ml 16ml 11’42
2. ” 2.    Lux 8ml 16ml 3’28”
3. 3.    Tetmosol 8ml 16ml 5’10”
4. 4.    Santoor 8ml 16ml 15’32”
5. 5.    Cinthol 8ml 16ml 9’40”

Result The cleansing capacity of the soaps taken is in the


order
: Santoor > Dove > Cinthol > Tetmosol > Lux
From this experiment, we can infer that Santoor has the
highest foaming capacity, in other words, highest cleaning
capacity
. Lux, on the other hand is found to have taken the least
amount of time for the disappearance of foam produced
and thus is said to be having the least foaming capacity
and cleansing capacity. Test for hardness in water

Test for hardness in water


Test for Ca2+ and Mg2+ salts in the water supplied
Test for Ca2+ in water H2O +NH4Cl + NH4OH +
(NH4)2CO3
No precipitate
The tests show negative results for the presence of the
salts causing hardness in water. The water used does not
contain salts of Ca2+ and Mg2+. The tap water provided
is soft and thus, the experimental results and values hold
good for distilled water and tap Water

END

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