DAV Centenary Public School, Jagraon

September exam ( 2021- 22)

Subject - Chemistry
Class - 11th. M.M. 40
Note: All questions are compulsory.
Each question carries 1 mark.
There is no choices between any of the questions.

Read the following paragraph and answer the following questions.

Discovery of quantum numbers was quite revolutionary in accordance with elucidationof atomic
structure. Different quantum numbers give different and useful information. For instance, spin
quantum number tells about spin of the electron. With the help of these quantum numbers, it
became easier to set certain rules regarding filling the orbitals and to discuss their configuration
and stability.

1.Which of the following is responsible to rule out the existence of definite paths or trajectories
of electrons?
A. Pauli's exclusion principle
B. Heisenberg's uncertainty principle
C. Hund's rule of maximum multiplicity
D. Aufbau's principle
2. If an electron has spin quantum number of+½ and magnetic quantum number of -1, it cannot
be present in:
A. S - orbital
B. d - orbital
C. p - orbital
D. f - orbital
3. What is the maximum number of orbitals that can be identified with the following quantum
numbers
n=3, l=1 and m=0
A. 1
B. 2
C. 3
D. 4
4. Which of the following pairs of d-orbitals will have electron density along axes?
A. dz2, dxz
B. dxz, dyz
C. dz2, dx2-y2
D. dxy, dx2-y2
5. The correct set of four quantum numbers for the valence electrons of Rb ( Z = 37) is:
A. 5, 0, 1, +½
B. 5, 0, 0, +½
C. 5, 1, 0, +½
D. 5, 1, 1, +½
Read the passage carefully and answer the following assertion-reasons.

A- if both the assertion and reason are correct and reason is the correct explanation.
B- if assertion is correct but given reason is not the correct explanation.
C- if assertion is correct but reason is wrong.
D- if assertion is wrong but reason is correct.

Modern periodic table is designed according to the increasing atomic number of elements. Their
properties follows some general trends to illustrate their properties. However, some important
exceptions are there. Various factors somehow dominants over other factors which mainly is the
reason behind these exceptions. Dominance of these factors is experimental study not all
theoretical or hypothetical.

6. Assertion: Chlorine has greater electron affinity than fluorine.

Reason: Chlorine is more electronegative than fluorine.
7. Assertion: First ionization enthalpy for nitrogen is lower than oxygen.
Reason: across a period nuclear charge increase.
8. Assertion: Alkali metals are strong oxidizing agents.
Reason: Alkali metals have very low value of ionization enthalpies.
9. Assertion: Be and He have similar outer electronic configuration ns2
Reason: Both are chemically inert.

Q10-30 are MCQ based, choose only one correct option.

10. Main axis of diatomic molecule is z. The orbitals px and py overlap to form
A. π - molecular orbital
B. σ - molecular orbital
C. δ - molecular orbital
D. No bond is formed
11. HCl gas is covalent and NaCl is an ionic compound. This is because
A. Sodium is highly electropositive
B. Hydrogen is a non-metal
C. HCl is a gas
D. Electronegativity difference between H and Cl is less than 2.1
12. Predict the correct order of repulsions among the following:
A. b.p-b.p > l.p-b.p > l.p-l.p
B. l.p-b.p > b.p-b.p > l.p-l.p
C. l.p-l.p > l.p-b.p > b.p-b.p
D. l.p-l.p > b.p-b.p > l.p-b.p
13. The shape of SF4 and XeF2 respectively are
A. Both TBP
B. T-shaped and linear
C. See-saw and linear
 D. Square planar and TBP
14. The species having bond angle of 120° is
A. ClF3
B. NCl3
C. BCl3
D. PH3
15. The ground state magnetic property of B2 and C2 molecules will be
A. B2 is paramagnetic and C2 is diamagnetic
B. B2 is diamagnetic and C2 is paramagnetic
C. Both are paramagnetic
D. Both are diamagnetic
16. Which of the following species is not paramagnetic
A. O2
B. B2
C. NO
D. CO
17. Which one of the following is sec - butylphenylvinyl methane

18. Which nomenclature is not according to IUPAC system?

19. The correct IUPAC name for the compound

A. 4-ethyl-3-propylhex-1-ene
B. 3-ethyl-4-ethenylheptane
C. 3-ethyl-4-propylhex-5-ene
D. 3-(1-ethylpropyl)hex-1-ene
20. The correct IUPAC name for the given compound is:

A. 3-ethyl-4-methylheptan-5-en-2-one
 B. 4-ethyl-3-methylheptan-5-en-2-one
C. 2-oxo-3-ethyl-4-methylheptan-5-ene
D. All are correct
21. Among the following which one will be treated as principal functional group?
A. -OH
B. -COOR
C. -SO3H
D. -COCl
22. Which of the following is an electrophile
A. SO3
B. C2H5OH
C. Cl-
D. NH3
23. Consider the following structures,

The correct sequence of these carbonation in the decreasing order of their stability is:
A. IV, II, III, I
B. I, III, II, IV
C. IV, III, II, I
D. I, II, III, IV
24. Which of the following has minimum -I effect
A. -F
B. -OCH3
C. -NO2
D. -COOH
25. According to Bohr's theory, which of the following correctly represents the variation of
energy and radius of an election in nth orbit of H - atom?

26. The shortest wavelength of the line in hydrogen atomic spectrum of Lymann series when RH
= 109678 /cm is:
A. 1002.7 A°
B. 1215.67 A°
C. 1127.30 A°
 D. 911.7 A°
27. If the energies of the two photons are in the ration of 3:2, their wavelengths will be in the
ratio of:
A. 9:4
B. 2:3
C. 1:2
D. 3:2
28. Which of the following is the largest
A. Cl-
B. S2-
C. Na+
D. F-
29. Which is true about the electronegativity order of the following elements
A. P > Si
B. C > N
C. Br > Cl
D. Sr < Ca
30. The first ionization enthalpy of Na, Mg, Al and Si are in the order :
A. Na < Mg > Al < Si
B. Na > Mg > Al > Si
C. Na < Mg < Al > Si
D. Na > Mg > Al < Si

Questions 31-40 are assertion-reason based.

A- if both the assertion and reason are correct and reason is the correct explanation.
B- if assertion is correct but given reason is not the correct explanation.
C- if assertion is correct but reason is wrong.
D- if assertion is wrong but reason is correct.

31. Assertion: Ionic compounds tend to be non-volatile.

Reason : The internuclear forces in these compounds are weak.
32. Assertion: The dipole moment helps to predict whether a molecule is polar or non-polar.
Reason: The dipole moment helps to predict the geometry of molecules.
33. Assertion: Molecular nitrogen is less reactive than molecular oxygen.
Reason: The bond length of N2 is shorter than that of oxygen.
34. Assertion: Solubility of MgCl2 is much higher than MgF2.
Reason: Lattice enthalpy of MgCl2 is much higher than MgF2.
35. Assertion: Metamers can also be chain or position isomers.
Reason: It explains the chemical reactivity of a substance according to two possible structures.
36. Assertion: The carbanion CH2CHO is more stable than ethyl anion.
Reason: the -CHO group exerts -I effect.
37. Assertion: tertiary carbocations are generally formed more easily than primary carbocations.
Reason: Due to hyperconjugative structures formed in tertiary carbocations decreases the
stability of tertiary carbocations.
38. Assertion: Ethenyl anion is a better nucleophile than ethynyl anion.
Reason: sp2 hybridized carbon is less electronegative than sp hybridized carbon.
39. Assertion: energy of resonance hybrid is equal to the average of energies of all canonical
forms.
Reason: Resonance hybrid cannot be represented by a single structure.
40. Assertion: the free gaseous Cr atom has 6 unpaired electrons.
Reason: Exchange energy is greater but symmetry is missing.