HOLIDAY HOMEWORK (WINTER BREAK )

1. Give difference between molarity and molality.

2. State Henry’s Law. Give its two applications.
3. Define (a) Faraday’s constant? (b) Kohlrausch’s Law with applications (c) Molar
conductivity.
4. Depict the galvanic cell in which the reaction takes place. Zn(s) + 2Ag+ (aq) →Zn2+ (aq) + 2Ag
Further show:
(i) Which of the electrode is negatively charged?
(ii) The carriers of the current in the cell.
(iii) Individual reaction at each electrode
5. Differentiate between Rate of reaction and reaction rate constant.
6. Explain Pseudo first order reaction with example.
7. . Give reason
(a) Zinc is not regarded as a transition element
(b) Why Copper (I) ion is not known in aqueous solution?
(c) Actinoids exhibit greater range of oxidation states than lanthanoids, why?
8. Describe the preparation of potassium dichromate.
9. [NiCl4] 2 - is paramagetic whil [Ni(CO)4] is diamagnetic though both are tetrahedral ,why ?
10. [Fe(H2O)6] 3+ is strongly paramagnetic whereas [Fe(CN)6] 3- is weakly paramagnetic ? why
11. Draw the structures of optical and geometrical isomers of: [Cr(en)2Cl2]+
12. Define (a) Glycosidic linkage (b) Peptide linkage (c) Phosphodiester
linkage
13. Give difference
(a) Reducing and non-reducing sugars (b) DNA and
14. Explain the following reactions
(a) HVZ reaction (b) Haffmann Bromamide reaction (c) Carbyl amine reaction
15. Give chemical distinguish between
(1) phenol and ethanol
(2) Propanal and propanone
(3) Primary , secondary and tertiary amines
16. Give all the steps involving in mechanism of reaction in which produce diethyl ether from
ethanol.