CHEMISTRY

SECTION – I
(SINGLE CORRECT CHOICE TYPE )
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which ONLY ONE is correct
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 SECTION – II
(MULTIPLE CORRECT CHOICE TYPE )
This section contains 9 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct

7. In which of the following pairs size of 1st element is higher as compare to IInd?
A) Sc, Zn B) Sc, La C) Cu, Ag D) La, Hf

8.
9. When a weak monoacidic base, is titrated against HCl, which of the following is/are correct
statements?
A) Before end point, solution behaves as a basic buffer
B) At half of the neutralization, pH  14  pKb at 25 o C .
C) Equivalence point pH of solution is less than 7 at 25 o C
D) Phenolphthalein can be a suitable indicator to detect the equivalence point

10. Which can be the product of following reaction

11. Which of the following statement(s) is/are correct.

12. Identify A, B, C, D, E and F in the following

13. Which of the statements are correct about intermolecular cannizaro’s reaction.
A) The attack of base (OH  ) is rate determining step.
B) It follows third order kinetics (if concentration of alkali is low)
C) Migration of proton is rate determining step.
D) It is a disproportionation reaction.

14. Which of the following is not true about hydrolysis product of

A) Gives a pair of anomers

B) Gives a pair of enantiomers
C) Gives a pair of epimers
D) Gives a pair of functional isomers
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 SECTION - II
(COMPREHENSION TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.

Paragraph for Questions 15 and 16

The glucose molecules are the primary component of starch molecule. Starch is a natural polymer.

15. Which is true about compound (I)

A) It has acetal structure
B) It has hemiacetal structure
C) It donot react with Tollen’s reagent
D) Second carbon is anomeric carbon

16. Assuming that polymerisation of (I) take place in manner similar to its dimerisation , then the
structure of polymer (III) can be correctly represented as

Paragraph for Questions 17and 18

An organic mixture contained following compounds
(1) Benzoic acid (2)salicylaldehyde (3)P-hydroxy benzaldehyde
(4)  -napthylamine (5)Napthalene
The following sequence of reagent are used to separate this mixture
17. Soluble compound at step y is formed by compound
A) Benzoic acid B) P-hydroxy benzaldehyde
C)  -napthylamine D) Napthalene

18. Insoluble compound at step z is formed by compound

A) p-hydroxy benzaldehyde B) salicylaldehyde
C)  -napthylamine D) Napthalene

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 SECTION –III
( INTEGER ANSWER TYPE)
This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.

19. If Buckminster fullerene, C60 has x hexagonal faces and y pentagonal faces, the value of (x – y) is

20. In how many of the following reactions elimination products predominate?

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