Physical Chemistry Assignment � GJCH

TOPICS � Atomic Structure to Electrochemistry

Single Choice

Q.1

Q.2

Q.3

Q.4 Latimer diagram for Mn illustrates its standard reduction potentials (in 1 M
acid) in oxidation states from +7 to 0.

The standard potential for two non-adjacent species can also be calculated by using
the concept that ?G0 is an additive property but potential is not an additive
property.

Mn+6 undergoes disproportionation into Mn+4 and Mn+7.

2MnO42?? 2MnO4? + MnO2 E� = 2.272 - 0.564 = +1.708 V
Which among the following statements is correct?
(A) Mn+4 undergoes disproportionation into Mn+3 and Mn+6
(B) Mn+3 undergoes disproportionation into Mn+4 and Mn+2
(C) Mn+2 undergoes disproportionation into Mn and Mn+3
(D) None of the above is correct

Q.5

(A) (B) (C) (D)

Q.6

More than one option correct type

Q.7

Q.8

Q.9

Numerical type
Q.10

Q.11

Q.12

Q.13

ANSWER KEY

1. A
2. D
3. D
4. B
5. C
6. C
7. ABC
8. ACD
9. AD
10. 7
11. 6
12. 3
13. 5