Sec: SR.

IIT_CO-SC WAT-50 Date: 11-07-21

Time: 3HRS 2017_P2 Max. Marks: 183
KEY SHEET
PHYSICS
1 B 2 B 3 C 4 C 5 C
6 A 7 D 8 ABCD 9 ABCD 10 BD
11 ABCD 12 ABCD 13 ABC 14 ABC 15 C
16 B 17 A 18 A

CHEMISTRY
19 D 20 C 21 C 22 B 23 A

24 B 25 C 26 ABC 27 ABD 28 ABD

29 BC 30 AB 31 CD 32 ABD 33 A

34 C 35 A 36 B

MATHEMATICS
37 C 38 A 39 B 40 C 41 B

42 A 43 B 44 ABCD 45 BCD 46 BC

47 AB 48 ABCD 49 ACD 50 BCD 51 B

52 A 53 C 54 D
Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
SOLUTIONS
PHYSICS
1. Let us consider the particles A and B together as a system. The momentum of the system before the
collision is
  
p i  p A  p B   h /  A  i   h / B  i

The particles A and B combine together in a perfectly inelastic collision. The momentum of
combined particle will be towards i if p A  pB otherwise it will be towards i . The final
momentum of the system when p A  pB is

p  pi ,
f

Where p > 0. The momentum of the system is conserved

 
i.e., p i  p f , which gives
p  h / A  h / B
Note that A  B when p A  pB . The de Broglie wavelength of the particle P is
h h  
   A B
p h /  A  h / B  B   A
The final momentum of the system when p A  pB is

p f   pi
 
The conservation of momentum, p i  p f , gives
p   h / B  h / A 
Note that A  B in this case. The de Broglie wavelength of the particle P is
h h  
   A B
p h / B  h /  A  A   B
The results of above two cases can be combined as
  A B
 A B     , if A  B ;

  A B

 A   B   A B
, if A  B
 B  A
2. The de-Broglie wavelength of a particle of mass m, momentum p, and kinetic energy E is given by
1  h / p  h / 2mE …. (1)
The wavelength of a photon of energy E is given by
2  hc / E …. (2)
Divide equation (1) by (2) to get
1 / 2  E /  2mc 2 
We encourage you to calculate 1 and 2 for the given energy
Ans: B

SR.IIT_CO-SC Page 2

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
 
3. Initial velocity of the electron is 0  0 i  0 j , its momentum is p 0  m0 i  m0 j and its de
Broglie wavelength is
h h
0    …. (1)
p0 2m0
  
The force on an electron of charge q = -e in an electric field E   E0 k is F  qE  eE0 k . The
acceleration of the electron is

 F eE
a   0 k .
m m

The electron moves with a constant acceleration a . Its velocity at time t is given by
   eE t
   0  at  0 i  0 j  0 k
m
The magnitude of its momentum at time t is
  e 2 E02t 2
p  m   2m0 1 
2m 202
The de Broglie wavelength of the electron at time t is
h h
   
p e 2 E02t 2
2m0 1 
2m 202
0
 2
(using (1))
e 2 E02t
1
2m 202
4. The number of photoelectrons striking the plate B per second is
n i/e.
The maximum kinetic energy of the ejected photoelectrons is
K max  hv  
All photoelectrons are not ejected with the maximum kinetic energy. They have a distribution of
energy varying from zero to Kmax. Let K be kinetic energy of a photoelectron at the plate A. After
ejection, the electron is accelerated by a potential difference V. Thus, kinetic energy of the electron
at B is
K B  K  eV
The momentum of the photoelectron just before striking the plate B is
pB  2mK B  2m  K  eV 
 2m  K max  eV 
 2m  hv    eV 
Thus, the force on the plate B due to incident photoelectrons is
i
F  npB  2m  hv    eV 
e
5. The electric field at the origin varies with time as
 
E  E 0 1  cos 1t  cos 2t

 E 0  cos t t  cos 1t cos 2t 

SR.IIT_CO-SC Page 3

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
 
 E0 E0
 E 0 cos 2t  cos 1  2  t  cos 2  1  t
2 2
It is the superposition of three waves of frequencies
  1 42  6
v1  2   1014  5.73  1014 Hz ,
2 2
 42
v2  2   1014  6.69  1014 Hz
2 2
  2 6  42
v3  1   1014  7.64  1014 Hz
2 2
Since v3 is the highest frequency, the photons of this frequency are most energetic. These photons
eject electrons with the maximum kinetic energy
K max  hv3  


 6.63 10  7.64 10   2.39
34 14

1.6 1019
We encourage you to compare the contributions of v1, v2 and v3 on the photocurrent. It is intersecting
and challenging, give it a try
6. The fastest emitted electron will have the maximum kinetic energy. Thus, K max  mv 2 / 2 for the
wave length  and K max  mv '2 / 2 for the wavelength 3 / 4 . Substitute these values in equation
K max  hc /    to get
1 2 hc
mv   … (1)
2 
1 hc
mv '2   …..(2)
2 (3 / 4)
Subtract equation (1) from (2) and simplify to get
2hc
v '  v2  … (3)
3 m
From equation (1)
2hc 2
 v2   v2 …. (4)
m m
Use inequality (4) in equation (3) to get
2hc v2 4
v '  v2   v2   v
3 m 3 3
7. Here,  is the wavelength of incident light and d is the de Broglie wavelength of the fastest
photoelectron. The fastest ejected photoelectron has the maximum kinetic energy which is given by
hc
K max   0 …. (1)

p2
The de Broglie wavelength of the photoelectron having kinetic energy K max  is given by
2m
h h
d   ….(2)
p 2mK max
Where m is the mass of the electron and p is its linear momentum. Eliminate Kmax from equations (1)
and (2) to get

SR.IIT_CO-SC Page 4

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
2
h hc
  0 … (3)
2md 2

Differentiate equation (3) we get
h2 hc
 2  d   1 2 
2md 3

Which gives
d mcd3

 h 2
8. The particles of same wavelength will have equal momentum. Thus, the momentum of an electron
and a photon of same wavelength   4 Ao is
h 6.63 1034
p   1.66  1024 kgm / s
 4  1010
The energy of a photon of wavelength   4 Ao is
hc 12400 Ao eV
Ep    3100eV
 4 Ao
The kinetic energy of an electron of de Broglie wavelength   4 Ao is

Ee 
p2  h /  

2


 hc /  2 
2m 2m 2mc 2
 3100 
2

  9.4eV
2  0.511 106 
Note that the particles of same wavelength will have equal momentum but different energies
9. The kinetic energy of a thermal neutron is
K  kT  1.38  1023   300  J  4.14  1021 J
4.14  1021
 eV  0.025eV
1.6  1019
Note that the kinetic energy of a thermal neutron is of the order of 25 meV. The speed of thermal
neutrons have a Maxwellian distribution. The speed corresponding to the kinetic energy kT is
1/ 2 1/ 2
 2K   2  4.14  1021 
v    27 
 mn   1.67  10 
=2200 m/s
The de Broglie wavelength of the thermal neutron is
h 6.63 1034
 
2mn K 2 1.6 1027  4.14 1021 
 1.8 1010 m  1.8 Ao
Note that de Broglie wavelength of thermal neutrons is of the order of atomic separations in solid
materials. The thermal neutrons will undergo diffraction when passing through the material. These
diffraction patterns are used to study the atomic structure of the material
10. The intensity of a point source at a distance r varies as I  I 0 / r 2 , where Io is a constant. Thus,
intensities of the light falling on the photoelectric cell are
I1  I 0 /  0.2  , I 2  I 0 /  0.6 
2 2

Since saturation current is proportional to the intensity

SR.IIT_CO-SC Page 5

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
 0.2  18  2mA
2
I2
i2  i1 
 0.6 
2
I1
The cut – off voltage depends on the frequency of incident light and not on its intensity. Thus, the cut
– off voltage is 0.6 V in both the cases
11. The relation between frequency v and stopping potential V0 is a straight line. The line intersect the
frequency axis at vc  5.6  1014 Hz . It passes through the points  8.0 1014 ,1 and 10.5  1014 , 2  and
its slope is
V 2 1
s 0 
v 10.5  1014  8  1014
 4 1015V / Hz
Thus, the equation of the line is
V0  4.0  1015  v  5.6  1014 
 4.0 1015 v  2.24 ….(1)
Write Einstein’s equation in terms of the stopping potential  K max  eV0 
V0   h / e  v   e … (2)
Compare equations (1) and (2) to get Planck’s constant and the work function
h  es  1.6  10 19  4.0  10 15 
 6.4 1034 Js
  e  2.24  J  2.24eV
Substitute v = 0 in equation (1) to get intercept on the V0 axis as V0 = -2.24 V. Note that the graph
intersect the V0 axis at V0   / e
Albert Einstein was awarded Nobel Prize in 1921 for his services to theoretical physics, and
especially for his discovery of the law of the photoelectric effect.
R. Millikan was awarded Nobel prize in 1923 for his work on the elementary charge of electricity
and on the photoelectric effect
12. The energy of a photon of wavelength 200nm is
E  hc /   1240 / 200  6.2eV
The energy received by an electron from a photon is 6.2 eV. The electron may lose its entire energy
to the photoelectron at the emitter is
Kmin = 0
Metal due to collision with atoms. Thus, the minimum kinetic energy of the photoelectron at the
emitter is
Kmin = 0
An electron may not lose any energy if it skips collision. However, to come out of the metal, it need
to do work against the binding forces of the metal .This work is equal to the work
function   4.5eV . Thus, the maximum kinetic energy of the photoelectrons (at the emitter) is
K max  hc /     6.2  4.5  1.7eV
The collector plate is at a positive potential of V = 2V with respect to the emitter. Thus, each
photoelectron gains a potential energy U = eV = 2eV while travelling from the emitter to the
collector. Hence, the minimum and the maximum energy of photoelectrons at the collector are
c
K min  K min  U  0  2  2eV ,
K max  K max  U  1.7  2  3.7eV
c

SR.IIT_CO-SC Page 6

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
13. According to Einstein’s quantum theory of the photoelectric effect, light constitutes of photons. The
energy of each photon is E  hv , where v is frequency of light. The photoelectrons are ejected when
a photon of energy greater than work function (  ) collides with an electron on metal surface.
Maximum kinetic energy of ejected photoelectrons, K max  hv   , depends on the frequency of
incident radiation and not on intensity. The photoelectrons are ejected if photon’s energy is greater
than the work function, irrespective of the intensity of light. The numbers of photos striking the metal
surface per second and the number of photoelectrons ejected per second depend on the intensity of
incident radiation
14.

15. X L  18  103  500  9

1
XC   16
125  106  500
 500 
i1    sin  500t  37 
o

 15 
 500 
i2    sin  500t  53 
o

 20 
So phase difference = 90o
16. If S1 and S2 both are opened
Z  20 2
250 2
irms   12.5 A
20 2
2
 25  625
Power     20   20  3.125 KW
 2  4
17. Voltage across capacitor will lag current by 90o
200 2   
 iC  sin  t   
10  4 2
 3 
i  20 2 sin  t  
 4 

SR.IIT_CO-SC Page 7

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
  
18. iL  40 2 sin  t   53o 
 4 
  
iC  20 2 sin  t   90o 
 4 
Angle between iL and iC is  90  53o   143o

CHEMISTRY
2
22.  Ni  CN 4  : square planar complex
2
23.  Ni  NH 3 6  : paramagnetic complex
3
Cu  CN 4  : tetrahedral complex
24. Na 4  Fe  CN 5  NOS   : Fe  2 
Na 2  FeO 4  : Fe  6 
Fe 2  CO 9 : Fe(0)
3
26. Co  NH 3 6  - low spin complex
27. potassiumhexacyanidoferrate(II)
29. glycinate and oxalate ions: chelating anionic ligands
en – ethane - 1,2 – diamine and dien – diethylenetriamine – chelating neutral complexs
e  
30. A)

 Mn  CO  
6   Mn  CO  
6
EAN  37 EAN  36
0 e  1
B) V  CO   EAN  35  V  CO 6   EAN  36 
31. CoCl3 3 NH 3 : CoCl3  NH 3 3  : non - electrolyte
 Pt  NH  Cl  is a neutral complex in which the oxidation number of Pt is +2
 3 2 2
32. It does not distinguish between strong field and weak fields ligands
33. Metallic radius of Cu < Zn
The atomic size of Hf  Zr(due to lanthanide contraction)
In a group of transition elements, higher oxidation states are stable for heavier members
34. IE1 of Cu is less than that of Zn but IE2 of Cu is more than that of Zn
` Cu :  Ar  4s1 3d10 ; Zn :  Ar  4s 2 3d10

35. Mn 3 and Co3 ions are the strong oxidizing agents in aq solutions. The ions Ti 2 , V 2 and Cr 2 are
strong reducing agents and will liberate hydrogen from a dilute acid
2Cr 2  aq   2H   aq   2Cr 3  aq   H 2  g 

36. The E 0  M 2 / M  value for copper is positive

SR.IIT_CO-SC Page 8

Education consists mainly of what we have unlearned.

Narayana IIT Academy 11-07-21_SR.IIT_*CO-SC _JEE-Adv_WAT-50_KEY&SOL
MATHS
37. Using P.I.E.
5! 3 . 5C3 . 2!  2 . 5C4  1  1
38. Observe x4 can only be 1
15
i.e., x1  x2  x3  5
3
 7C5  21
39. n !  n  1 !
40.  bijection between divisors of N 2 less than N and those larger than N. Here N 2 is perfect square.
41. 4  2 ' s, 5  1' s or 1  4, 1  3, 1  2, 4  1s or 1  4, 3  2 ' s, 3  1' s
7! 7! 7!
   371
2!5! 4! 3!3!
42. A1  A2  A1  A2  A1 A2
 4 4  4 4  43
8
43. C5 ways to select rings 8 C5 ways assign 5 rings to 4 finger.
45. C) 4 + 1 + 1, 3 + 2 + 1, 2 + 2 + 2, i.e., integer partitions of 6 in 3 parts.
D) P(6) = 11
1000!
46. 1000
C500 
(500!) 2
 Exponent of 13 in 1000
C500 , 81  2  40  1
Exponent of 7 is 164  2  82  0
47. Either f ( x) is even x  A or f ( x) is odd  x  A
 M   M  1
n n

 Number of function is    
 2   2 
  M 
n
M 
( If f is even then f : A  2, 4, ..... 2    ie   choices)
  2  2
49. S (n, k )  k S (n  1, k )  S (n  1, k  1)
Set up this recurrence relation by considering two cases on the nth ball or use division and
distribution.
50. Derangement and Recurrence . S1, S2 : JEE 2012

53 & 54. Consider n  1 spaces between n 1' s

1 – 1 – 1 – 1 - ….. – 1
For each space put “+” or '')  ('' i.e., 2n1 choices. Substract 1 case of 1 + + + …… 1 = n, as atleast
2 partition required

SR.IIT_CO-SC Page 9

Education consists mainly of what we have unlearned.