CHEMISTRY-XI 27

BSE CHEMISTRY Q.7. Aldehydes and ketones can be distinguished by:

(a) Alkaline KMnO,
(c) Ammonia
(b) Fehling solution
d) H,SO
Q. 14. In the following reaction, product

Y
Y is:

Question Paper Issued by Boiling

lass-XII [Based on Latest Sample CBsa Ans. (b) Fehling solution
(a) o-Methyl phenol b) Benzoic cid
Q. 8. Which of the following compounds is most acidic?

Solved
(C) p-Methyl phenol d Benzyl acohol

OH OH Ans. (d) Benzyl alcoho

NO CH Br CHOH
CH,
OH Boilinng NaBr
(d) CI-CH,CH,OH Tolucne

4
aichol

Sample Question Paper Ans. (a)

OH Q. 15. An organic compound which
carboxylic acid group is:
is acid without a

NO, (a) Picric acid b) Oxalic acid

Time Allowed :3 hours Q. 9. Unpleasant smell of carbylamine is obtained when (c) Vinegar dAscorbicacid
chloroform and alcoholic KOH are heated with: Ans. (a) Picric acid. 24,6-tri-itrophenol)
Max. Marks: 70
(a) any amine (b) any aromatic amine
No. 16
In the following questions (Q. to 18, a stateme
- -

General Instructions: (c) any primary amine (d) any aliphatic amine
Same as CBSE Sample Question Paper-1. Ans. (c) any primary amine
of assertion followed by a statemet of reason 5
Choose the correct answer out of the following choice

Q. 10. Curdling of milk is an example of: (a) Assertion (A) and Reason R) both are cora
staterments and Reason (R) is comect expiaraion
(a) breaking of peptide linkage
(b) -1.25 V
Section A (a) 1.25 V
C) 1.75 V (d) 2.00 V
(b) hydrolysis of lactose
(c) breaking of protein into amino acids
for Assertion (A)
(b) Assertion (A) and Reason R boh arR o e e
The following questions (Q. No. 1 to 18) are multiple Ans. (c) 1.75 V statements but Reason RIS DO comec
choice questions with one correct answer. Each question (d) denaturation of prolein explanation for Assention (A.
carries 1 mark There is no internal choice in this section. Eellcathodeanode Ans. (d) Curdling of milk is an example of denaturation of (c) Assertion (A) is corTect saemet br Reson
Q. 1. Which of the folowing modes of expressing the protein. (R) 15 wrong statement
concentration is independent of temperature? = 1.5 V-(-0.25 V) Q. 11. Disaccharides that are reducing in nature are: (d) Assertion (A) is wrong saement but Reason
(a) Normality (b) Molarity = 1.5 V +0.25 V = 1.75 V (a) Sucrose and lactose is corect statement
(C) Molality (d Fomality (b) Sucrose and maltose Q. 16. Assertion (A: pcesol is a wezke c d hn hrol
Ans () Molaliry
Q.4. The oxidation number of cobalt in K
(a))+1 b) +3
[Co(CO)Jis (c) Lactose and maltose Reason (R CH, group desabilizes e i e n i
Q. 2. The standard emf of a cellis 1.10 v. The maximum (c) -1 (d)-3 (d) Sucrose, lactose and maltose on

electrical work obtained from the cell Gf n = 2) Ans. (c) -1 Ans. (c) Lactose and maltose are reducing sugars. Ans. () Assertion (A) is wrong so Rn R
s CoTet statemnL
Here, 1+ X+4 Q. 12. Which is most basic?
(a) 175.4 k (b) 212.3 k
x0=0 *=- Q. 17. Assertion (AE DNA ass s doutie beln a e
(a) CH NH (b) (CH)NH
9.5. Which of the following gives blood red colour
(C)106.15 k (d 53.07 k (d) (CH,),NH RNA exists as single heln
with KCNS? (c) CH,NH,
Ans. (b) 2123 Ans. (d) (CH NH
Reason: Soth DNA and RNA ae polhoucieoties
Maumum work W = - AG° =+ nE°F
(a) Cu2 (b) Fe It has two electron donatingCH, groups. Ans () Aserioa (A) is corat
u
c)A (d) Zn* Swrong Statemen
2x1.1 Vx
=
96500 Coulomb Ans. (b) Fe Q. 13. The half lives of two samples are 0.1 and 0.4
=
21230 CV molr second. Their respective concentrations are 200 and Q. 18. Asertion (Ak CrONsoptically active
21230 J mol"(CV = J) FeCl+3KCNS FeCNS), + 3KC
50 respectively. The order of reaction is: Raaxe [CnOndces x hae plae a ammn
Blood red
2123 kJ mor (a) (6) Ans (a) Aetion (A) d Reasn R) e am
Q. 6. EDTA has coordination number: statements a i Reason (R) s x c t ergia e
Q. 3. The emí of the cell: (c) 2 (d)
for Aaertion (AL
Ni/N (1.0 M) I Au* (1.0 M)/Au (a) 3 (b) 4 Ans. (c) 2 a ' n

E 0.25 V for Nif*/Ni; 1.5 V for (c) (d) 6

(200 ==J
4'-
=

Au*IAu is:
Ans. (d) 6 0.1 (50)-
0.4
Thus, -I = I-n or n= I+| =2

26
 Rohit CBSE SAMPLE PAPERS 29
cRCHEMISTRY-X
(Units L mol s show that it is zero

Section B reaction.
orde Ans. 2303, 100
(n Units L mol s' indicate that it is second () Ammoniacal silver nitrate solution is called J0 00-99
short a n s w e r
No. 19 to 25) are Tollen's reagent. It is used to detect aldehydic 100
The following questions (Q.
h o marks each.
reaction.
group in an organic compound
250 jog 1OD
p e and carn

terms Q. 21. On the basis of

valence bond theory, show (i) CHCHCH, < CH,CHO < CH,CH,OH 2305
Q. 19. Define the following [NiCO)I complex is tetrahedral and diamagnetic 3
Molality () Mole fraction Ans. (Ni(C0),1 Complex. The ouler electronic configuraio Q. 24. () Name the bases present in RNA. Which one
the number of moles of is not present in
Ans ( Molality is defined as
1000 g of solvent.
of Ni (28) is 3d*4s*. DNA Dividing (ii) by (1)
solute dissolved per ke or
The oxidation state of Ni in it is zero. (in What products are expected when lactose is 23033
(Mole fraction is defined as the ratio of number hydrolysed?
component to the total
(r+4 x0 =0 * = 0) 30
of moles of a particular
in a
Ans. 'sr 230303010 03010
numher of moles ot all the componcnts Ni atom:
3d 4s () Bases present in RNA
solutuon. Hence, , 9 s = 10 x g
() Adenine (i) Guanine
OR (ii) Cytosine (iv) Uracil Q. 27. 15.0 g of an unknown molecular material is
CO is a strong ligand which forces the 4s electrons to
Calculate the mass of a non-volatile solute (molar Uracil is not present in DNA. dissolved in 450 g of water. The resuting solution
in pair up wih 3d electrons. Thus: freezes at -0.34°C. What is the molar mass of the
mass 40 g mo") which should be dissolved (i) Glucose and galactose
114 g octane to reduce its vapour pressure to 80% Formation of[Ni(CO),l: material? (k, for water = 186 k kg mo)
Q. 25. How will you convert phenol to picric acid? Sol. We know that
o i) Phenol is more acidic than ethanol. Explain.
WIM 4
AT,=k, xm
pairs of elcctrons from
4C0 Ans.
where m = molality of the soluDo
Where X is the mole fraction of component B.
Molar mass of octane. CH,(CH.),CH
Ni is in sp hybridization in this complex. Hence, is OH OH Here, depression in freezing poi
shape is tetrahedral. Since this complex does nol above O,N NO,
= 12 -3 - 6 (12 2 ) 12 + 3 = 114 g mol 100°C AT, = 0C--034©)
have any unpaired electron, it is diamagnetic in
Vapour pressure is reduced to 80%
nature 3HNO 3H,O = 034C=034 K
Conc.
It means if P, = 100, P, = 80
Q.22. Write the lUPAC name ofCH,=CHCH,Br Phenoi Molar depression constart
(in ldentify the chiral molecule in the following NO, k, = 1.86 K kg moli
100-80 w/40 200 * pair: 2,4,6-Trinitrophenol
100 114/114 100 40 (Picric cid) W
Mass of solute, w =
20x40 and C M (i) Phenyl group shows -/ effect (electron with- a7,=k,MR
100 drawing nature) whereas alkyl group shows +/ Molar mass of solute
effect (electron releasing nature).
Q. 20. Define the order of a reaction. For the reaction:
s. () CHCH°CH,Br is 3-Bromoprop-1-ene. k,xxW
a2NO 2NOC
(i) First molecule of the pair i.e.. CH,CHCHCICH OH R-OH
C,H, OH M AT, xW
write the rate law.
(2 chlorobutane) is chiral.
-I effect +I effect +I effect
What is the overall order of this reaction? OR Thus, phenyl group releases H ion from -OH
L86 Kkg molx15
Ans. The sum af powes
(exponents) of concentration more easily while release of Hn is difficult
0 x450 g/1000 k
terms () Give the lUPAC name of: group
t h e rait lzw
expression is called order of that
in alcohols. Hence, phenol is more acidic than LS6x15x1000 g o = 1 2o
chemical reaction
Thus. f
CH CH, ethanol. 0 50
rzte of reaction k
=
[A} [B} {CF CH,CH-C CH.Br Q. 28. How will convert the
you rollowing?
Pse law
Order = I +J +2
Rate &
Gn Write the product formed when ethylbromior Section C () Nitrobanzene into aniline

Oróer of rcacuon
Cl INOF (Mono-bromoethane) is treated with This section contains 5 questions (Q. No. 26 to 30) with in Aniline into N-phenylethananide
=
Sum of
(a) aqueous KOH (b) alcoholic KOH internal choice in one question. The following
exponents questions (in) Ethanoic acid into methananine
I -2 =3 are short answer type and carry 3 marks each.
Ans
Q. 26. Show that in a first order reaction, time required
OR Ans. () CH{CH= - H.CH,
for completion of 99.9% is 10 times of half life Niadeae
- HCT
identify the reaction order from each 4-Bromo-3 methyl pent-2-ene
of the o f the reaction. (log 2 0.3010).
folowing units of the reactüon rale
constant: (i) (a)C.H,OH (b)cH, (CH,=CH,) 2.303 100 ()CHNHH a ai
Ans.
G)1mols
Us ralr Csizn,
Gi)Lmol 23. ) What is Tollen's reagent? Write one sefulnes
Sol.
sos 100-50 230 1og? Anuhx Al l n
1or nth ordcr
Lmo! reacuon are of this reagent. 2303 x 03010
in the
H-CHAHCUCH
G) Rearrange following compounds
the
increasing order of their boiling poinl
CH,CHO, CH,CH,OH, CH,CH,CH
 Rohit CBSE SAMPLE PAPERS
CHEMISTRY-XII 31
30
Gn Reimer-Tiemann Reaction: On treating phep
NH, Heat with chloroform in presence of sodium hydroxide not form ether but the major product formed is an
(ii) CH,0OH CHCOONH,
-HO a-CHO group is introduced at ortho position. I alkene, 2-methylpropene. (b) Mole fraction of A, X = A
Ethanoic acid
Ammo. acetate

this way. salicyladehyde (o-hydro

n+n
where n= Number of moles of A
(aceic acid)
Br+ 4KOH benzaldehyde) is formed. H
CH,CONH, and nn= Number of moles of B
CHNH ONa CH--Br+ Na o CH CH- CH,
Methanamine
H.B. reactuon Ethanamide OH ONa (c) Molality is preferred for expressingE
2-Methyl propene
(Methyl amine) (Acetamide)
CHC,
CHC NaOH CH(OH), | CH
(3 halide)
Sod. methoxide
concentration of a solution because it is a mass/
mass relationship which does not change with
OR aq NaOH + NaBr +
CH,OH
Methanol temperature.
)Why do amines behave as nucleophiles? Phenol Intermediate Unstable H.0 Molar Mass
(a)Why ethers have low boiling point as compared (d) Normality =
Molanty
in) Distinguish between aniline and
OH Ona to alcohols? Equivalent Mass
N-methylaniline. CHO CHO (6) Why ethers are insoluble in water?
(in) Arrange the following in the increasing order H () Why ethers are used as solvent in industry? ( Section E
of their basic strength:
Salicyladehyde ()Ether fire is not extinguished by water. Explain. Following questions (Q. No. 33 to 35) are long answer type
Aniline, p-nitroaniline, p-methylaniline and carry 5 marks each:
(i) Willianmson synthesis: An alkyl halide react Ans.
Ans.
) Nucleophiles are negatively charged or neutral with sodium alkoxide to form ether. (a) It is due to the absence of H-bonds between Q. 33. Account for the following:
ether molecules. () Transition metals form a large number of
species having lone pair of electrons. They are RX+Na OR R-0-R + Nax
nucleus loving species like NH,. Anines contain (6) Ethers have least tendency to form H-bonds with complexes.
Alkyl Sod. Ether
a lone pair of electrons on nitrogen atom
o Water molecules. (in Many of the transition elements are known to
halide alkoxide
amino group. Hence, like ammonia, amines are (c)Ethers are used as solvents because they are form interstitial compounds.
good nucleophiles. Q. 30. Write the main structural and functional difierences inert in nature. (iin With the same dorbital configuration (d
between DNA and RNA. (d) Ether (C,H,-0-C.H,) has low boiling point C i s reducing agent white Mn* is an
NH, RNH Ar-NH,
Ammonia2 Aliphatic amines
Ans. Diferences between DNA and RNA: (74°C). It is lighter than water and has very low oxidising agent.
Aromatic amines
Structural Diferences: solubility in water. When water is sprayed over (iv) Name the transition elements of 3d series Sc
() Carbylamine test: On waming with chloroform
ether fire, ether forms upper layer over water and to Zn) which show only +3 oxidation state
in
presence of alcoholic kOH, aniline gives
1. DNA has deoxyribose aspentose sugar while RNA| keeps on burning. Hence, ether fire is not and maximum number of oxidation states.
carbylamine which has extremely foul smell but has ribose a ntose suga
extinguished by water. () There is much more frequent metal bonding
N-methylaniline does not give this test. 2 DNA has thymine but not uracil while RNA ha in compounds of 3d series of transition metak
(Lu) uracil but no thymine base. Q. 32. Read the passage given below and answer the
Ans.
3. DNA has double bond stranded structure but RNA| following questions:
o.N- NH, < - NH, CH,- NH has single stranded structure. A solution is a homogeneous mixture of two or more
() This is due to smaller ionic sizes or higher ionic
charge and availability of d-orbitals
Functional Differences: substances. Solutions are of nine types. For example,
-NItroanilne Aniline
P-methylaniline air is a mixture of O, (21%) and N, (78%). It is a Gi) Transiion elements have vacant space or holes
.DNA controls heredity in living beings. Hence, between their atoms. These holes can
p-toluidine) solution of a gas in a gas. Amalgam is a solution of
Q. 29. Explain the following reactions: Is
genetic material but all the three types of RNA accommodate small atoms of non-metals like B.
n, , ) cary out protein synthesis in the cell.
mercury (liquid) with sodium (solid). The
) Kolbe's reaction C. N, O and F. Such covalent compounds formai
concentration of solutions are expressed in terms of
DNA has a unique property of replicauon ou are called interstitial compounds
n Reimer-Tiemann reaction mass percentage, nomality, molarity and molality.
RNA does not cause replicaüon. i ) Cr* has a tendency to ovidise to Cr* with
Gii) Williamson synthesis Answer the following questions: change from d* to d*. The d configuraion has
Ans. (i) Kolbe's Reaction: On (a) Give an example of a solution containing a
reacting sodium salt of half filled orbitals.
phenol with CO, gas, salicylic acid is formed. | Section D solid solute in a solid solvent. Hence, C is a reducing agent.
OH ONa he following questions (Q. No. 31 and 32) are case baseu 6) Write an expression for mole fraction of a Mn* has a tendency to form Mn" by gaining
questions which carry 4 marks each. Read the pas> componentA present in a solution with another an electron. Mn** has half filledd° configuranon
CO caretully and answer the questions that follow: component B. which has extra stability. Hence. Mn* ats as an
Under pressure Q. 31. Read the passage given below and swer 1 ()Why is molality preferred to molarity for oxidising agent.
PDeDO Sod. phenate expressing concentration of a solution? (v) Scandium (,Sc) shows only +3 oxidation state
following questions:
OH
OH Williamson synthesis is not suitable for (d)Writethe relationship between normality and
molarity of a solution.
due to
ad contigurakon.
COOH CO ONa preparation of ethers if tertiary alkyl halide i5u
ISed.
Ans. (a) Brass is an alloy of Cu (about 70%) and Zn
Manganese (AIn) shows mavimum number of
Oxidation states due to s outer elartronic
Actually, in this case an alkene is tormedn of (about 30%). It is a solution of solid solute configuration.
Salicylic acd elimination reaction. For example, the reace ()This is barause ot high enthalpy of atomisadon
Sd. salicylate zinc (Zn) in solid solvent copper (Cu).
sodiun methoxide with
tertiary butyl bromioe ot Sd senes.
 TRohe CBSE SAMPLE PAPE
32
(i) CH,CONH,
OR (ii) CH,CoOH
Account for the following: (b) () The positive charge on carbonyl carbom
not considered
CH,CHO decreases to a lesser extent
) Zn, Cd and Hg are normally
to +I effect of one CH, group as
as transition elements. compa
blue. to CH,COCH, which has two clec
while Cu2* salts are
(in Zn* salts are white releasing CH, groups. Hence CH,CH
in solution.
(in Cu ion is unstable aqueous more reactive than CH,COCH,
stable than Fe towards
(iv) Mn2 is more (i) It is due to carboxylate ion (conjugate ha
oxidation to +3 state. which is more stabilized by resonance
not exhibit variable
()Scandium (Z =
21) does phenoxide ion.
oxidation states.
filled Q. 35. (a) Account for the following:
Ans. ) Zn. Cd and Hg do not have partially
CICH,coOH is a stronger acid th
They have (n 1) d'0 configuration (
-

d-orbitals.
But
stable M* ions. CH,COOH.
of their atoms as well as

transition metals have (n- 1) d configuration. (in Carboxylic acids do not give reactionsa
Hg not considered as
carbonyl group.
Hence, Zn, Cd and
are

to illustrate t
transition elements.
(b) Write the chemical equations
is
electronic configuration of Zn (Z =30) following name reactions:
(i) The have 340
[Ar 3404s2. Zn2* ions in their salts () Rosenmund's reduction

outer configuration.
Since Zn** ions have G) Cannizzaro's reaction
4s as salts are white.
no unpaired electrons, Zné c) Out
of CH,CH,CO-CH,CH,
electronic configuration of
Cu (Z = 29) is which gives iodofom
The CH,CH,CH,COCH,
electronic configuration
[Ar] 34045. The outer Cu* has one unpaired test? wi
of Cu2 ion is 3d 4s.Thus, It is because CI acts as electron

electron. So
coloured (blue).
Cu* salts are Ans. (a) ) -/effect where
and shows
its water due to
drawing group
is unstable in shows +/ effect.
(ii) Cuprous ion (Cu*) CH, group
to Cu* and
reduction to Cu. Thus, it carbon atom
oxidation because the carbonyl
disproportionation as under: (i) It is stabilised.
undergoes carboxylic acid
is resonance

2Cu Cua)t C ) Rosenmund's reduction:

Oxidation states: +1 +2 0 (b)

because of half filled 34 stable configuration
(iv) It is Pd-Ba SOP
of Mn2
(v) It is because
3d' configuration of
scandium IO CH
and Sc (3d4s) easily goes
Benzaldehyde

(Z=21) is not stable Benzyl chloride

to +3 oxidation state. 0 Pd-BaSO RCHO +H

reactions:
Q. 34. (a) Predict the products of the following or R-C +H
9 CH,-C=o HCN (it) Cannizzaro's reaction:

Conc. NaOH CHO

CH HCHO+HCHO
Methar

Gin CH,CoOH-
NH Formaldehyde (2 mol) +HOOON

Sod. tormi
(a) KMnO4/ KOH
Gin CH-CH,-CH,
b) H Conc. OH

h) Accout for the following: or CH,CHO+C.H,CHO

reactive than Benzaldehyde (2 mol)

() CH,CHO is
more
HCN.
towards reactions with CHCH,OH CH
CHCOCH,
stronger acid than
Po. ben
is
Gn Cartoxylic acid
a Benzyl alcohol

phenol.
OH (c) CHCH,CH,COCH,

CN
Ans. i CH
CH