based,

PMTS and JEE Main questions

This section inchudes previoUS years' NCERT Core conten
Maior prot 'B of the following reaction sequence is 6 The major product in the reaction
CH,
AHy B CH,
CHH-CH, CHOH (major product) CH, -Ç-C+ KO
CH, CH,
(a) t-butyl ethyl ether (b)
CH, CH,’is
(a) cHH-CH, (b) CH-¢-H-CH, (c) 2-methylpent-1-ene (d) 2,2-
CH,
Br OH
(c) CH-CH-CH, () CH;-¢-H-CH,
CH,
7. The correct sequence of
bond is
2-mh
ei
tm
hie
p
bond enthalpy
th
royb
p tan
o
e
(a) CH-Cl> CH;-F>(
CH, CHs (JEE Main)
(b) CH,-F< CH;-Cl < CH,-Br >CHi
CH;F>CH,-Cl > CH,-Br<
Which of the following is suitable to synthesize
chlorobenzene?
(c) CH,-i
CH,-Br >CH,
(a) Benzene. Cl, anhydrous AlCI, (d) CH,-F< CH,-Cl > CH;-Br
(b) Phenol, NaNO, HCI, CuCI
(c) HCI (d)
yNH,
,HCI, heating
8 The major product of the
ÇH, followingr>CH- 10E
reaction is
C
(NEET) NaOH
3.
CGH,OH Major product
The major product formed in dehydrohalogenation
reaction of 2-bromopentane is pent-2-ene. This
product formation is based on? (a) (b)
(b) Saytzeff's Rule OH
(a) Huckel's Rule
(c) Hund's Rule (d) Hofmann Rule(NEET) ÇH,
ÇHs OH
4. The incorrect statement regarding chirality is (c) (d)
(a) Syl reaction yields 1:1 mixture of both
enantiomers HO

(b) the product obtained by SN2 reaction of

haloalkane having chirality at the reactive site 9. IUPAC name of CH;e-Ç-CH, 5
shows inversion of configuration CH, CI
(c) enantiomers are superimposable mirror images (a) 3-chloro-2, 2, 3-trimethylbutane
of each other
(b) 2-tert-butyl-2-chloropropane
(d) aracemic mixture shows zero optical rotation. (c) 1-chloro-1,1-dimethyl-2,2-dimetiylpropat
(NEET)
(d) 2-chloro-2, 3, 3-trimethylbutane. (PM
5. Product 'A' of following sequence of reactions is 10. The hydrolysis reaction that takes place at the
(i) Br,, Fe
Ethylbenzene (iü) Cl,, A
'A' slowest rate, among the following is
(ii) alc. KOH Major Product aq. NaOH
Br (a) Cl

=CH, =CH, CH, CH,

H,C-CH,-0H
ag. NaOH
(b) (b) H,C-CH,-Cl:
. NaOH
HÇ=CH, (c) H,C=CH-CH,CI H,C=CH-CH,OH

(d)
a9.NaOH CH,OH
(JEE Main) (d)
Br Br