Mid Sem 2021-2022 subject code CY2102

First and last name

Question 1/20 (1 p.)

Order the following in the decreasing order of nucleophilicity.

A.

B.

C.

Question 2/20 (2 p.)

Justify your answer.

A.

B.

C.

D.

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 Mid Sem 2021-2022 subject code CY2102

Question 3/20 (2 p.)

Which of the following molecules is most likely to proceed by SN1 reaction.

A.

B.

C.

Question 4/20 (1 p.)

Which SN2 reaction of the following pair takes place more rapidly in a protic solvent.

A. a
B. b

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 Mid Sem 2021-2022 subject code CY2102

Question 5/20 (2 p.)

Write mechanism.

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 6/20 (2 p.)

Justify your answer.

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 7/20 (2 p.)

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 8/20 (1 p.)

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 9/20 (2 p.)

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 10/20 (2 p.)

A.

B.

C.

Question 11/20 (2 p.)

A.

B.

C.

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 Mid Sem 2021-2022 subject code CY2102

Question 12/20 (3 p.)

Write the product of the following reaction. Write the mechanism in the work sheet.

A.

B.

C.

D.

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 Mid Sem 2021-2022 subject code CY2102

Question 13/20 (1 p.)

List the following in the decreasing order of Keq for hydrate formation.

A. b > c > a> d

B. d > c > b > a
C. a > c > b > d
D. c > d > a > b

Question 14/20 (1 p.)

Which of the following reaction leads to formation of a malonic ester?

A. a
B. b
C. c
D. d

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 Mid Sem 2021-2022 subject code CY2102

Question 15/20 (1 p.)

A. I
B. II
C. III
D. IV

Question 16/20 (1 p.)

A. I
B. II
C. III
D. IV

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 Mid Sem 2021-2022 subject code CY2102

Question 17/20 (1 p.)

Write appropriate answer for A and B in the given organic reaction

A.

B.

C.

D.

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 Mid Sem 2021-2022 subject code CY2102

Question 18/20 (1 p.)

A. I
B. II
C. II

Question 19/20 (1 p.)

Which one of the following compounds will undergo self aldol condensation in presence of dil NaOH ?

A. I
B. II
C. III
D. IV

Question 20/20 (1 p.)

Enamines are formed by reaction of
A. Aldehyde with primary amine
B. Aldehyde with secondary amine
C. Ketone with primary amine
D. Ketone with ammonia

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