AISSE PRACTICAL EXAMINATION

1. Redox Titration (Permanganometry) 8 marks

1. Aim (Write from the question paper)

2. THEORY
PROCEDURE

Burette - Burette is filled with KMnO4 solution

Pipette – 20ml of the M/20 Mohr’s salt solution is pipetted in to a conical

flask.
Indicator- KMnO4 solution (self indicator)
End point- Appearance of pale pink colour

NOTE-
1 test tube of dilute sulphuric acid is added while preparing mohr’s salt
solution to prevent hydrolysis of the salt.

1 test tube of dilute sulphuric acid is added to the pipetted solution before
titration to provide acidic medium.
Calculation of Molarity and strength

Molarity of KMnO4= M1= ?

Volume of KMnO4 solution = V1ml = ( your concordant value)

Molarity of mohrs salt solution = M2 = 0.05M

Volume of mohr’s salt solution = 20 ml ( volume pipetted)

M1 =

Strength of the given KMnO4 solution = Molarity x Molecular mass

= M1 X 158 g/l
RESULT

1. Molarity of the given KMnO4 solution = --------mol/l or M

2. Strength of the given KMnO4 sOlution= ……….. g/l

MOLARITY to be calculated up to 4 decimals

b) KMnO4 Vs Oxalic acid

Aim- Write from the question paper

Theory-
PROCEDURE

Burette - Burette is filled with KMnO4 solution

Pipette – 20ml of the M/20 oxalic acid solution is pipetted in to a conical

flask.
Indicator- KMnO4 solution (self indicator)

End point- Appearance of pale pink colour

NOTE-
1 test tube of dilute sulphuric acid is added to the pipetted solution and
heated the flask to 60 degrees.
b) Strength of the KMnO4 solution

Strength of the KMnO4 solution =Molarity x molar mass of KMnO4

= M1 x 158

Strength = ---- x158 = -----g/l

RESULT

1. Molarity of the given KMnO4 solution = --------mol/l or M

2. Strength of the given KMnO4 sOlution= ……….. g/l

MOLARITY to be calculated up to 4 decimals

SALT ANALYSIS 8 marks

1. Ammonium carbonate
2. Lead acetate
3. Calcium chloride
4. Aluminium nitrate
5. Lead nitrate
6. Ammonium sulphate
Organic Analysis 6 marks

Study all the functional groups which you wrote in Record book

1. Aldehyde
2. Phenol
3. Carboxylic acid
4. Alcohol
5. Ketone ( Any two will be given)
Record +viva – 4 marks
Project + viva – 4 marks
SAMPLE
COLUMN
NO NEED TO WRITE IN THE ANSWER SHEET-
understand the Procedure and do the titration accordingly-

Weigh out 1.96 g of mohr’s salt and transfer in to a 100ml standard flask . Add one test
tube sulphuric acid and make up to 100ml.

Rinse and fill the burette with the given KMnO4 solution

Pipette out 20 ml mohrs salt solution in to a conical flask and add 1 test tube of sulphuric
acid

Add KMnO4 from burette till a light pink colour is imparted to the solution in the flask.

Note initial and final reading of the burette.

Repeat titration till you get concordant values.
NO NEED TO WRITE IN THE ANSWER SHEET
UNDERSTAND and do the titration accordingly-

Weigh out 0.63 g of oxalic acid and make up to 100ml in a standard flask.

Rinse and fill the burette with the given KMnO4 solution

Pipette out 20 ml oxalic acid solution in to a conical flask , add 1 test tube of sulphuric acid
and heat up to 60 degrees.(till you see fumes coming out)
Add KMnO4 from burette till a light pink colour is imparted to the solution in the flask.

Note initial and final reading of the burette.

Repeat titration till you get concordant values.