Automatic Titrator

AUT-701
Sales Manual

DKK-TOA CORPORATION
 Contents
1. What is Titration?
2. Key Sales Points of AUT-701
3. Expansion for Your Future Needs
4. Principle
5. Maintenance
1. What is Titration?
 What is Titration?
The titration is a common laboratory method
of quantitative chemical analysis to
determine the concentration of a target
material in a sample solution.
Type of titration
AUT-701 Covers all type of titration
①Neutralization titration.
Acidic substance and basic titration by neutralization

②Redox titration
Titration of oxidation and reduction

③Precipitation titration
Titration of precipitation

④Chelatometric titration
Titration of chelate reaction
Method to detect endpoint by titration
① Indicator method
Measurement of solution color change by photometer

② Absorbance method
Measurement of solution absorbance change by photometer

③ Potentiometric titration method

Measurement of potention deference by the glass electrode
2. Key Sales Points of AUT-701
 Key Sales Points of AUT-701

1.Simultaneous dual titration System for time Save

a. Dual Titration System for different item measurement
b. Dual Automatic Multiple Sample Titration System (Dual Turn Table)
c. Maximum 10 Units of Burette,

2.Extensibility
a.Turntable, Second Turntable, Automatic Burette
b.Automatic Sampler, Balancer, Printer,
PC (LAN,RS-232C), Optional Units
(Photometric,Potentlometric,Polarization,Conductivity Titration Unit)
 1-a Dual Titration System
Allows Simultaneous Titration

Time
Saving

pH
ORP
 1-b Dual Automatic Multiple
Titration System
Turn Table Turn Table

Time
Saving
 1-c Maximum 10 Units of Burette

Auto Burette

Auto Burette

Auto Burette

Auto Burette
Main Unit
AUT-701

Connectable 10 units
AUT-701
ABT-7 at maximum ABT-7

Time
Saving

Connecting Cable
Power Cable
to the Burette
 1-d Max.４ＣＨ of Electrode Input
Standard configuration 2 pH / mV inputs
Optional titration units (photometric, polarization,
conductivity, potentiometric) can be connected to
the 3rd, 4th unit.

CH3 Optional Input

CH4 Optional Input

CH2 Electrode input

(pH / mV)

CH1 Electrode input

(pH / mV)

Time
Saving
Max 4 ch of electrode connection

Detect. Input Detect. Input

System Ａ
ＣＨ１ pH ＣＨ3 Photometer

Auto Burette Auto Burette

Titrator
Time
Main Max. 10 burette
connection in total Saving
Unit
Auto Burette Auto Burette

Detect. Input Detect. Input

System Ｂ
ＣＨ２ ORP ＣＨ4 conductivity
3. Expansion for Your Future Needs
Extensibility
Turn table TTT-710
 Easy for maintenance
Washing reservoir, electrode arm and tubes are front mounted
⇒Easy for maintenance.

Electrode
arm Washing
reservoir

Easy maintenance
for pure water Waste
pump solution
Waste solution hose
outlet hose
 Compact design
TTT-710 ：440（W）×409（H）×391（D）mm
TTT-510 ：380（W）×518（H）×542（D）mm

⇒Smaller approx.34% at volumetric than TTT-510

391mm

440mm

Main body Equipped turn table

 For connecting laboratory (Option)

532mm 532mm

593mm
566mm
For R-series and X-series For titrator
 Connection Board
Accessories & PC connections
Extensibility

USB (Host)

CH3 Optical Input

CH4 Optical Input

CH2 Electrode input

(pH & mV)

CH1 Electrode input Temperature &

(pH & mV)
Humidity sensor
Sampling or
Balancer or
Turntable Turn table
Printer

Burette PC
(MAX 10 Burttes)
LAN
“ By introducing AUT-701
you can save your time
and meet your future needs
as well”
4. Principle
Principle of Automatic titration
(Potentiometric titration)
Automatic Titration system composition
①Automatic Titrator
②Reaction unit
③Titration Burette

System composition
Printer

Reference Electrode
Display
Measurement Titration Nozzle
Input
Operation
Potentio
Input n mater
Control

Operation panel
Stirrer Unit

Automatic Titrator Reaction Unit Titration Burette

 The basic principle of the pH electrode
(potentiometric measuring electrode)
pH electrode is composed of a glass electrode and reference
electrode, Measurement the potential difference between the glass
membrane and liquid junction.
The basic composed ｐＨ Electrode
Potention
mater

Reference Electrode Glass

Electrode
Reference Inner Glass Inner
solution (KCL) solution

比較電極内極 ガラス電極内極

Liquid junction Glass membrane

Sample
 The basic composition of
ｐＨ Composite electrode

Glass Inner solution

Reference Inner solution

(KCL)

Reference Sensor Liquid junction

Reference Glass membrane

Sensor
High performance electrode
（Strong＆Float ｐＨ Electrode）

Tough pH glass electrode

10 times of Tough
5. Maintenance
 Check concentration of the electrode
inner solution
When measurement sample,
There is possibility diffusion effect.
Sample is incoming from Out side of
electrode through the junction.
Concentration of inner solution is
degrease.

When start of measurement sample.

Confirm to concentration of inner solution

Enable to check of float situation by

concentration of inner solution.
Float

Good Change inner

solution
 Check of leakage from burette syringe
piston ring

○
Check of leakage from up
×
side piston ring
Leakage from piston ring

Burette syringe
（２０ｍＬ）
 Check of titration nozzle

Air
Bubble

Good

Titration nozzle × ○
The carbon dioxide gas (CO2) absorber
tube is required when using alkaline
titration reagent.

Carbon Dioxide Gas Reagent bottle

(CO2) absorber tube
 Check of electrode

Keeping rubber plug for the replenish port open

Rubber plug
Keeping open
 Check of after measurement

Keeping electrode and nozzle in the water after measurement

For over 1 week shutdown of electrode
put the protective cap on

Close robber cap

Protective cap
For long time shutdown of the titration tube.
Expel the reagent form the syringe and tube
lines, and wash by the pure water. After wash
dischage pure water from tube and nozzle.

After wash discharge

pure water
After wash discharge
pure water

After wash discharge

pure water