You are on page 1of 94

Previous Year JEE Questions

Periodic Classification
s-block
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Outermost electronic configuration of a group 13 element, E, is 4s2 4p1 .


The electronic configuration of an element of p-block period-five placed
diagonally to element, E is
JEE MAIN July 2021

1 [Xe]5d106s26p2

2 [Ar]3d104s24p2

3 [Kr]3d104s24p2

4 [Kr]4d105s25p2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Outermost electronic configuration of a group 13 element, E, is 4s2 4p1 .


The electronic configuration of an element of p-block period-five placed
diagonally to element, E is
JEE MAIN July 2021

1 [Xe]5d106s26p2

2 [Ar]3d104s24p2

3 [Kr]3d104s24p2

4 [Kr]4d105s25p2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The absolute value of the electron gain enthalpy of halogen satisfies


JEE MAIN Mar 2021

1 I > Br > Cl > F

2 Cl > Br > F > I

3 Cl > F > Br > I

4 F > Cl > Br > I


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The absolute value of the electron gain enthalpy of halogen satisfies


JEE MAIN Mar 2021

1 I > Br > Cl > F

2 Cl > Br > F > I

3 Cl > F > Br > I

4 F > Cl > Br > I


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order
JEE MAIN July 2021

1 Al3+ < Mg2+ < Na+ < K+

2 Al3+ < Mg2+ < K+ < Na+

3 K+ < Al3+ < Mg2+ < Na+

4 Na+ < K+ < Mg2+ < Al3+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order
JEE MAIN July 2021

1 Al3+ < Mg2+ < Na+ < K+

2 Al3+ < Mg2+ < K+ < Na+

3 K+ < Al3+ < Mg2+ < Na+

4 Na+ < K+ < Mg2+ < Al3+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The set of elements that differ in mutual relationship from those of


the other sets is:
JEE MAIN Mar 2021

1 Li - Mg

2 B - Si

3 Be - Al

4 Li - Na
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The set of elements that differ in mutual relationship from those of


the other sets is:
JEE MAIN Mar 2021

1 Li - Mg

2 B - Si

3 Be - Al

4 Li - Na
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radius of Na+ ions is 1.02 Å. The ionic radii (in Å) of Mg2+ and
Al3+, respectively are:
JEE MAIN Mar 2021

1 1.05 and 0.99

2 0.72 and 0.54

3 0.85 and 0.99

4 0.68 and 0.72


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radius of Na+ ions is 1.02 Å. The ionic radii (in Å) of Mg2+ and
Al3+, respectively are:
JEE MAIN Mar 2021

The ionic radii order is


1 1.05 and 0.99
Na+ > Mg2+ > Al3+

2 0.72 and 0.54

3 0.85 and 0.99

4 0.68 and 0.72


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Consider the elements Mg. Al, S, P and Si, the correct increasing order of
their first ionization enthalpy is :
JEE MAIN Feb 2021

1 Mg < Al < Si < S < P

2 Al < Mg < Si < S < P

3 Mg < Al < Si < P < S

4 Al < Mg < S < Si < P


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Consider the elements Mg. Al, S, P and Si, the correct increasing order of
their first ionization enthalpy is :
JEE MAIN Feb 2021

Mg < Al < Si < S < P In general from left to right in a period,


1 ionisation enthalpy increases due to
effective nuclear charge increases. but
Al < Mg < Si < S < P due to extra stability of half filled and
2
full filled electronic configuration,
required ionisation enthalpy is more
3 Mg < Al < Si < P < S from neighbouring elements. i.e. first
ionisation enthalpy order is
Al < Mg < Si < S < P
4 Al < Mg < S < Si < P
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of electron gain enthalpy is


JEE MAIN Feb 2021

1 S > Se > Te > O

2 Te > Se > S > O

3 O > S > Se > Te

4 S > O > Se > Te


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of electron gain enthalpy is


JEE MAIN Feb 2021

1 S > Se > Te > O

2 Te > Se > S > O

3 O > S > Se > Te

4 S > O > Se > Te


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In general, the property (magnitude only) that shows an opposite trend


in comparison to other properties across a period is:
JEE MAIN 2020

1 Ionization enthalpy

2 Electronegativity

3 Electron gain enthalpy

4 Atomic Radius
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In general, the property (magnitude only) that shows an opposite trend


in comparison to other properties across a period is:
JEE MAIN 2020

1 Ionization enthalpy On moving left to right along


a period in the periodic table,
atomic radius decreases
2 Electronegativity while electronegativity,
electron gain enthalpy and
ionisation enthalpy
3 Electron gain enthalpy increases, along a period.

4 Atomic Radius
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of the ionic radii of O2- , N3- , F- , Mg2+ , Na+ and Al3+ is:
JEE MAIN 2020

1 Al3+ < Mg2+ < Na+ < F- < O2- < N3-

2 Al3+ < Na+ < Mg2+ < O2- < F- < N3-

3 N3- < F- < O2- < Mg2+ < Na+ < Al3+

4 N3- < O2- < F- <Na+ < Mg2+ < Al3+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of the ionic radii of O2- , N3- , F- , Mg2+ , Na+ and Al3+ is:
JEE MAIN 2020

1 Al3+ < Mg2+ < Na+ < F- < O2- < N3- For isoelectronic
species, as the no. of
protons increases,size
2 Al3+ < Na+ < Mg2+ < O2- < F- < N3- of ions decreases. Thus
order (1) is correct.

3 N3- < F- < O2- < Mg2+ < Na+ < Al3+

4 N3- < O2- < F- <Na+ < Mg2+ < Al3+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The element having greatest difference between its first and


second ionisation energy, is
JEE MAIN 2019

1 Ca

2 Sc

3 Ba

4 K
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The element having greatest difference between its first and


second ionisation energy, is
JEE MAIN 2019

Ca K(19) = 1s2 2s2 2p6 3s2 3p6 4s1


1
After removal of one electron, the second
electron we have to remove from another
2 Sc
shell which has an octet configuration,
hence there is a large difference between
3 Ba first and second ionization energies.

4 K
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In general, the properties that decrease and increase down a


group in the periodic table, respectively are
JEE MAIN 2019

1 E.N and atomic radius

2 E.N and electron gain enthalpy

3 Electron gain enthalpy and E.N

4 Atomic radius and E.N


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In general, the properties that decrease and increase down a


group in the periodic table, respectively are
JEE MAIN 2019

1 E.N and atomic radius Electronegativity


decreases and atomic
radius increases down a
2 E.N and electron gain enthalpy group in the periodic table.

3 Electron gain enthalpy and E.N

4 Atomic radius and E.N


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radii (in Å) of N3- ,O2- and F- respectively are


JEE MAIN 2019

1 1.36, 1.40 and 1.71

2 1.36, 1.71 and 1.40

3 1.71, 1.40 and 1.36

4 1.71, 1.36 and 1.4


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ionic radii (in Å) of N3- ,O2- and F- respectively are


JEE MAIN 2019

1 1.36, 1.40 and 1.71 All the three species have each 10
electrons, hence they are isoelectronic
species.
2 1.36, 1.71 and 1.40 It is considered that, in case of
isoelectronic species as the negative
charge increases, ionic radii increases
3 1.71, 1.40 and 1.36 and therefore the value of ionic radii

4 1.71, 1.36 and 1.4


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which of the following represents the correct order of increasing first


ionisation enthalpy for Ca, Ba, S, Se and Ar?
JEE MAIN 2013

1 Ca < S < Ba < Se < Ar

2 S < Se < Ca < Ba < Ar

3 Ba < Ca < Se < S < Ar

4 Ca < Ba < S < Se < Ar


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which of the following represents the correct order of increasing first


ionisation enthalpy for Ca, Ba, S, Se and Ar?
JEE MAIN 2013

Ionisation energy increases along a


1 Ca < S < Ba < Se < Ar
period from left to right and decreases
down a group.

2 S < Se < Ca < Ba < Ar

3 Ba < Ca < Se < S < Ar

4 Ca < Ba < S < Se < Ar


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The set representing the correct order of first ionisation potential is


AIEEE 2001

1 K > Na > Li

2 Be > Mg >Ca

3 B >C > N

4 Ge > Si >C
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The set representing the correct order of first ionisation potential is


AIEEE 2001

Size increases as we move down the group.


1 K > Na > Li
Therefore, the outer electrons experience
less attraction due to increase in distance,
2 Be > Mg >Ca
i.e., the effective nuclear charge
experienced is less. Less the effective
3 B >C > N nuclear charge less the I.P. Therefore, I.P of
Be>Mg>Ca.

4 Ge > Si >C
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of radii is


AIEEE 2000

1 N < Be < B

2 F- < O2- < N3-

3 Na < Li < K

4 Fe3+ < Fe2+ < Fe4+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The correct order of radii is


AIEEE 2000

Among isoelectronic species,


1 N < Be < B
greater the negative charge,
greater the ionic size, hence
2 F- < O2- < N3-
F- < O2- < N3-

3 Na < Li < K

4 Fe3+ < Fe2+ < Fe4+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Amongst the following elements (whose electronic configurations are


given below), the one having the highest ionisation energy is
AIEEE 1990

1 [Ne]3s23p1

2 [Ne]3s23p3

3 [Ne]3s23p2

4 [Ar]3d104s24p3
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Amongst the following elements (whose electronic configurations are


given below), the one having the highest ionisation energy is
AIEEE 1990

1 [Ne]3s23p1

2 [Ne]3s23p3

3 [Ne]3s23p2

4 [Ar]3d104s24p3
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The electronegativity of the following elements increases in the


order
AIEEE 1987

1 C, N, Si, P

2 N, Si, C, P

3 Si, P, C, N

4 P, Si, N, C
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The electronegativity of the following elements increases in the


order
AIEEE 1987

1 C, N, Si, P Electronegativity increases from left to right


in a period and decreases from top to
bottom in a group. Variation is more rapid in
N, Si, C, P group than in a period, hence the desired
2 order is
Electronegativity : Si < P < C < N

3 Si, P, C, N

4 P, Si, N, C
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The hydration energy of Mg2+ is larger than that of


AIEEE 1984

1 Al3+

2 Na+

3 Be2+

4 Mg2+
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The hydration energy of Mg2+ is larger than that of


AIEEE 1984

Hydration energy depends on charge of ion and


3+
1 Al ionic radius. Higher the charge, greater the
hydration energy.

On the other hand, smaller the size, greater the


2 Na+ hydration energy.

Charge is considered first for comparison.


2+
3 Be Hence, Mg2+ has higher hydration energy than
Na + .

4 Mg2+
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which is the correct order of second ionisation potential of C, N, O


and F in the following?
AIEEE 1981

1 O>N>F>C

2 O>F>N>C

3 F>O>N>C

4 C>N>O>F
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which is the correct order of second ionisation potential of C, N, O


and F in the following?
AIEEE 1981

1 O>N>F>C

2 O>F>N>C

3 F>O>N>C

4 C>N>O>F
wassimbhatt
Previous Year JEE Questions
Chemical Bonding
s-block
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The hybridisation of the atomic orbitals of nitrogen in


NO2– , NO2+ and NH4+ respectively are :
JEE Main July 2021

1 sp2 , sp and sp3

2 sp, sp2 and sp3

3 sp3 , sp and sp2

4 sp3 , sp2 and sp


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The hybridisation of the atomic orbitals of nitrogen in


NO2– , NO2+ and NH4+ respectively are :
JEE Main July 2021

1 sp2 , sp and sp3

2 sp, sp2 and sp3

3 sp3 , sp and sp2

4 sp3 , sp2 and sp


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The Azimuthal quantum number for the valence electrons in


Ga+ ion is: (Atomic number of Ga = 31)
JEE Main July 2021

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The Azimuthal quantum number for the valence electrons in


Ga+ ion is: (Atomic number of Ga = 31)
JEE Main July 2021

Answer = 0

Ga = 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p1


Ga+= 1s2 2s2 2p6 3s2 3p6 3d10 4s2
Thus ‘l’ for valence shell e- = 0

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The number of lone pairs of electrons on the central ‘I’ atom in


I3- is
JEE Main July 2021

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The number of lone pairs of electrons on the central ‘I’ atom in


I3- is
JEE Main July 2021

Answer = 3

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Match List-I with List-II


JEE Main July 2021

List I (Species) List II (Hybridisation)


1 a-i, b-iv, c-iii, d-ii
a. SF4 i. sp3d2

b. IF5 ii. d2sp3


2 a-i, b-iii, c-ii, d-iv
c. NO2+ iii. sp3d

3 a-iii, b-iv, c-ii, d-i d. NH4+ iv. sp3

v. sp

4 a-iii, b-i, c-iv, d-iv

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Match List-I with List-II


JEE Main July 2021

List I (Species) List II (Hybridisation)


1 a-i, b-iv, c-iii, d-ii
a. SF4 i. sp3d2

b. IF5 ii. d2sp3


2 a-i, b-iii, c-ii, d-iv
c. NO2+ iii. sp3d

3 a-iii, b-iv, c-ii, d-i d. NH4+ iv. sp3

v. sp

4 a-iii, b-i, c-v, d-iv

wassimbhatt
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Identify the species having one 𝛑-bond and maximum no. of


canonical forms from the following
JEE Main July 2021

1 CO32-

2 SO3

3 O2

4 SO2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Identify the species having one 𝛑-bond and maximum no. of


canonical forms from the following
JEE Main July 2021

1 CO32-

2 SO3

3 O2

4 SO2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In the following the correct bond order sequence is:


JEE Main July 2021

1 O2 > O2- > O22- > O2+

2 O22- > O2 > O2- > O2

3 O2+ > O2 > O2- > O22-

4 O2+ > O2- > O22- > O2


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

In the following the correct bond order sequence is:


JEE Main July 2021

1 O2 > O2- > O22- > O2+ O2


(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
< (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)1

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
2 O22- > O2 > O2- > O2 O2 +
< (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)0

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
O2+ > O2 > O2- > O22- O2 -
3 < (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)2 = (𝜋* 2py)1

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
O22-
4 O2+ > O2- > O22- > O2 < (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)2 = (𝜋* 2py)2

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

A central atom in a molecule has 2 lone pairs and forms three single
bonds. The shape of this molecule
JEE Main Mar 2021

1 see-saw

2 planar triangular

3 T-shaped

4 trigonal pyramidal
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

A central atom in a molecule has 2 lone pairs and forms three single
bonds. The shape of this molecule
JEE Main Mar 2021

1 see-saw

2 planar triangular

3 T-shaped

4 trigonal pyramidal
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Amongst the following, the linear species is


JEE Main Mar 2021

1 NO2

2 Cl2O

3 O3

4 N3-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Amongst the following, the linear species is


JEE Main Mar 2021

1 NO2

2 Cl2O

3 O3

4 N3-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Among the following species, the diamagnetic molecule is


JEE Main 2018, 19

1 CO

2 B2

3 NO

4 O2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Among the following species, the diamagnetic molecule is


JEE Main 2018, 19

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝜋 2px)2 =
CO
1 CO (𝜋 2py)2 < (𝛔 2pz)2

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝜋 2px)1 =
B2 (𝜋 2py)1
2 B2
(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
NO < (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)0
3 NO
(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
O2 < (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)1
4 O2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Stability of the species Li2 , Li2- and Li2+ increases in the order of
JEE Main 2013

1 Li2 < Li2+ < Li2-

2 Li2- < Li2+ < Li2

3 Li2 < Li2- < Li2+

4 Li2- < Li2 < Li2+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Stability of the species Li2 , Li2- and Li2+ increases in the order of
JEE Main 2013

1 Li2 < Li2+ < Li2-

2 Li2- < Li2+ < Li2

3 Li2 < Li2- < Li2+


Stability order is (2) because Li2- has more
number of electrons in antibonding orbitals
4 Li2- < Li2 < Li2+ which destabilizes the species.

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING
The number of species below that have two lone pairs of electrons in their
central atom is ____
(Round off to the Nearest integer) JEE Main Mar 2021

SF4 , BF4- , ClF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING
The number of species below that have two lone pairs of electrons in their
central atom is ____
(Round off to the Nearest integer) JEE Main Mar 2021

SF4 , BF4- , ClF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6


Answer: 2

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

(i) NH3 NF3

(ii)

(iii) HF HCl HBr HI

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

(i) NH3 > NF3

(ii)
>

(iii) HF > HCl > HBr > HI

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

(i) CH3F CH3Cl CH3Br CH3I

(ii) NH3 PH3

(iii) H2O NH3

(iv) CHF3 CHCl3

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

2 1 3 4
(i) CH3F CH3Cl CH3Br CH3I

(ii) NH3 > PH3

(iii) H2O > NH3

(iv) CHF3 > CHCl3

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

(i)

(ii)

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Give the order of dipole moment of the following compounds.

(i) < <

< <
(ii)

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The isoelectronic set of ions is


JEE Main 2019

1 F- , Li+ , Na+ and Mg2+

2 N3- , Li+ , Mg2+ and O2-

3 Li+, Na+, O2- and F-

4 N3-, O2- , F- and Na+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The isoelectronic set of ions is


JEE Main 2019

1 F- , Li+ , Na+ and Mg2+

2 N3- , Li+ , Mg2+ and O2-

3 Li+, Na+, O2- and F-

4 N3-, O2- , F- and Na+


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The molecule which has zero dipole moment is


AIEEE 1989

1 CH2Cl2

2 BF3

3 NF3

4 ClO2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The molecule which has zero dipole moment is


AIEEE 1989

BF3 has triangular planar arrangement.


1 CH2Cl2 Three identical vectors acting in outward
direction at equal angles in a plane
cancel each other giving zero resultant,
2 BF3 hence non-polar.

3 NF3

4 ClO2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ion that has sp3d2 hybridisation for the central atom, is
JEE Main 2019

1 [ICl2]-

2 [BrF2]-

3 [ICl4]-

4 [IF6]-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The ion that has sp3d2 hybridisation for the central atom, is
JEE Main 2019

1 [ICl2]-

2 [BrF2]-

3 [ICl4]-

4 [IF6]-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Total number of lone pair of electron in I3- ion is


JEE Main 2018

1 3

2 6

3 9

4 12
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Total number of lone pair of electron in I3- ion is


JEE Main 2018

1 3

2 6

3 9

4 12
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The species having pyramidal shape is


AIEEE 2010

1 SO3

2 BrF3

3 SiO32-

4 OSF2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

The species having pyramidal shape is


AIEEE 2010

1 SO3

2 BrF3

SO3 is planar (S is sp2 hybridised),


3 SiO32- BrF3 is T-shaped and SiO3 2- is planar
(Si is sp2 hybridised).
4 OSF2
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

According to molecular orbital theory which of the following statement


about the magnetic character and bond order is correct regarding O2+

1 Paramagnetic & B.O < O2

2 Paramagnetic & B.O > O2

3 Diamagnetic & B.O < O2

4 Diamagnetic & B.O > O2


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

According to molecular orbital theory which of the following statement


about the magnetic character and bond order is correct regarding O2+

1 Paramagnetic & B.O < O2 O2


(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
< (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)1

(𝛔 1s)2 < (𝛔* 1s)2 < (𝛔 2s)2 < (𝛔* 2s)2 < (𝛔 2pz)2
2 Paramagnetic & B.O > O2 O2 +
< (𝜋 2px)2 = (𝜋 2py)2 < (𝜋* 2px)1 = (𝜋* 2py)0

3 Diamagnetic & B.O < O2

4 Diamagnetic & B.O > O2


wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

According to molecular orbital theory, which of the following will


not be a viable molecule?
JEE MAIN 2018

1 He22+

2 He2+

3 H2-

4 H22-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

According to molecular orbital theory, which of the following will


not be a viable molecule?
JEE MAIN 2018

1 He22+

2 He2+

3 H2-

4 H22-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which of the following contains maximum number of lone pairs on the


central atom?
AIEEE 2005

1 ClO3-

2 XeF4

3 SF4

4 I3-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Which of the following contains maximum number of lone pairs on the


central atom?
AIEEE 2005

1 ClO3- 3 l.p

2 XeF4

3 SF4

1 l.p 1 l.p 2 l.p


4 I3-
wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Number of lone pair(s) in XeOF4 is/are


AIEEE 2004

1 0

2 1

3 2

4 3

wassimbhatt
TOP 50 QUESTIONS: PERIODIC CLASSIFICATION & CHEMICAL BONDING

Number of lone pair(s) in XeOF4 is/are


AIEEE 2004

1 0

2 1

3 2

4 3

wassimbhatt
15 5
Batch starts on 26th July

WSCC

You might also like