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6 Chem I
6 Chem I
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School Exam Number:……….…………………………..Signature:……….……….
Candidates should NOT write their Centre Name or
P525/1 Centre Number anywhere on this booklet
CHEMISTRY
Paper 1
June 2022
2 ¾ hours
ENTEBBE
Uganda Advanced Certificate of Education
CHEMISTRY
(PRINCIPAL SUBJECT)
Paper 1
2 hours 45 minutes
INSTRUCTIONS TO CANDIDATES
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1. (a) Write balanced equation for the following reactions.
Class:
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Observation:
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(b)
Reagent: 2,4 – Dinitrophenylhydrazine (2½ marks)
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Observation:
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3. (a) 50cm3 of a vaporized alcohol Y, CnH2n+1OH diffused through a small
hole in 119.85 seconds. Under the same conditions the same volume
of hydrogen diffused through the hole in 21.85 seconds.
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(ii)
The expression for the hydrolysis constant, Kh, for ethyl
ammonium chloride. (1/2 mark)
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(b)
The pH of a 0.2M aqueous ethyl ammonium chloride solution is 3.8 .
Calculate the hydrolysis constant Kh, for ethyl ammonium chloride.
State any assumptions made. (03 marks)
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6. State the conditions and write equations for the reaction between water and
(i) Iron (2 ½ marks)
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(ii) Lead (2 ½ marks)
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7. Equation for some half cell reactions are given below:
Eθ/V
Zn 2+
(aq) + 2e Zn (s) - 0.76
(a) Write the cell notation for the cell formed when the two half cells are
connected. (1 ½ marks)
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Turn Over
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(b)
Write equation for
(i) The reaction at the cathode (01 mark)
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(ii) The reaction at the anode (01 mark)
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(iii) The overall cell reaction (01 mark)
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(c) Calculate the e.m.f of the cell in (a) above. (01 mark)
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8. (a) Benzene reacts with iodomethane in presence of a catalyst to form
methylbenzene.
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(b) Dilute sulphuric acid was added to copper (l) oxide (2 ½ marks)
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SECTION B
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COOCH3
(b) from (2 ½ marks)
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(a) CH3
C NNH NO2 from CH3CH2CH2OH.
CH3
NO2 (04 marks)
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10. (a) State three properties in which manganese differs from magnesium.
(1 ½
marks)
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(b) Ammonium solution was added dropwise to an aqueous solution of a
manganese (II) salt until in excess.
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(ii) Write the ionic equation for the reaction that took place.
(1 ½
marks)
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11. Compound T contains 62.6% Tin, the rest being chlorine. (T = 190).
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(b) Draw the structure and name the shape of the molecule of T.
(1 ½
marks)
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(c) State the condition(s) and write equation for the reaction leading to
the formation of T.
(2 ½ marks)
Condition(s)
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Equation Turn Over
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(d) Write equation for the reaction between T and
(i) Water
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(ii) Acidified potassium dichromate(VI) solution
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12. Complete the following equations and each case write the accepted
mechanism for the reaction.
Br
(a) CH3 C CH3 CH3O Na+ / CH3OH (03 marks)
CH3 Heat
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conc. HNO3
(b) (03 marks)
conc. H2SO4
550C
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CH3 H+ /H2O
(c) (03 marks)
warm
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(i) Molar conductivity of silver nitrate at infinite dilution at 250 C.
(11/2
marks)
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(ii) Solubility of silver chloride at 250C. (The electrolytic
conductivity of water and that of a saturated solution of silver
chloride are 1.6 X 10-8 and 3.41X 10-6 Ω-1cm-1. (1 ½ marks)
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Turn Over
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(d) State how the solubility of silver chloride would change if its
saturated solution is treated separately with
(i) Aqueous sodium chloride (1/2 mark)
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(ii) Concentrated ammonium solution (1/2 mark)
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(ii) Iron (III) chloride (1½ marks)
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(iii) Disulphur dichloride (1½ marks)
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(b) Write equation for the reaction between sodium hydroxide solution
and
(i) Zinc chloride (1½ marks)
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(ii) Nitrogen dioxide (1½ marks)
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(iii) Aluminium oxide (1½ marks)
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15.(a) State three characteristics of chemical equilibrium (1 ½ marks)
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(c) 3.24g of hydrogen iodide were heated at 450oc in a glass bulb of volume 800
cm3 . When equilibrium was attained, the bulb was rapidly cooled to room
temperature and then broken under a solution of potassium iodide. The iodine
formed required 36.0cm3 of 0.2M sodium thiosulphate solution in the presence
of starch indicator for complete reaction.
(i) Explain why the bulb was rapidly cooled and broken under potassium iodide
solution
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(ii) Calculate the equilibrium constant, Kc for the reaction at 450oC.
(05 marks)
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16. (a)
20.0cm3 of 0.50M hydrochloric acid was added to 230cm 3 of water.
Calculate the pH of the resultant solution. (02 marks)
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(b)
Calculate the mass of ammonium chloride that should be added to
1dm3 of a 0.1M ammonia solution at 250C to give a solution whose
pH is 8.7. State any assumptions made. (The base dissociation
constant, Kb =1.8 X 10-5 mol dm-3 at 250C. (5 ½ marks)
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(c) Few drops of aqueous sodium hydroxide were added to the solution in
(b).
END
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