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Front. Environ. Sci. Engin.

China 2010, 4(1): 102–107


DOI 10.1007/s11783-010-0001-z

REVIEW ARTICLE

Possible solutions for sludge dewatering in China

Wei WANG (✉)1, Yuxiang LUO1, Wei QIAO2


1 Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China
2 College of Chemical Engineering, China University of Petroleum, Beijing 102249, China

© Higher Education Press and Springer-Verlag 2009

Abstract In China, over 1.43107 tons of dewatered In 2007, 3.102109 tons of municipal wastewater was
sewage sludge, with 80% water content, were generated generated, and 49.1% was treated by biological processes
from wastewater treatment plants in 2007. About 60% of [1]. Accordingly, large amounts of sewage sludge were
the COD removed during the wastewater treatment process generated in these sewage treatment facilities. Sludge is
becomes concentrated as sludge. Traditional disposal composed primarily of organic microbes and inorganic
methods used by municipal solid waste treatment facilities, minerals, and will pose a serious environmental risk if its
such as landfills, composting, or incineration, are unsui- disposal is inadequately managed.
table for sludge disposal because of its high water content. Approximately 1.43107 tons of dewatered sewage
Disposal of sludge has therefore become a major focus of sludge with 80% water content were generated in China in
current environmental protection policies. The present 2007. The annual generation of dewatered sewage sludge
status of sludge treatment and disposal methodology is in China over the past two decades, illustrated in Fig. 1,
introduced in this paper. Decreasing the energy consump- was estimated from the amount of annual treated municipal
tion of sludge dewatering from 80% to 50% has been a key wastewater [1] and a survey of dry sludge generation ratios
issue for safe and economic sludge disposal. In an analysis in WWTPs by Zhu et al. [2]. The treatment and disposal of
of sludge water distribution, thermal drying and hydro- these large and rising quantities of sludge is now attracting
thermal conditioning processes are compared. Although increasing attention. The biological gel structure of sludge
thermal drying could result in an almost dry sludge, the is now recognized as one of the key limitations to the
energy consumption needed for this process is extremely efficient dewatering and anaerobic digestion that are
high. In comparison, hydrothermal technology could needed for its safe disposal [3].
achieve dewatered sewage sludge with a 50%–60%
water content, which is suitable for composting, incinera- 1.2 Status of sludge disposal
tion, or landfill. The energy consumption of hydrothermal
technology is lower than that required for thermal drying. A survey, carried out by the author, showed that the
WWTPs, each with a capacity of over 2105 tons per day,
Keywords sewage sludge disposal, water content, ther- treated 2.273107 tons of sewage per day in 2006, which
mal drying, hydrothermal conditioning represents about 50.9% of the total sewage treated in
China. These plants produced annually 6.14106 tons of
dewatered sewage sludge with 80% water content. The
1 Status of sludge generation and disposal disposal status of sludge from those plants is illustrated in
in China Fig. 2. 83% of this sludge was not disposed of properly.
Potentially contaminated industrial wastewater treated in
1.1 Generation of sewage sludge WWTPs diminishes the quality of sludge as a fertilizer
which farmers now rarely use. Neither can city virescence
Over the past two decades, many wastewater treatment engineering use such large amounts of sludge. As shown in
plants (WWTPs) have been built to treat municipal Fig. 2, a mere 10% of the sludge was disposed of by direct
wastewater in order to control environmental pollution. drying, the main method for sludge disposal used in
developed countries. Another 6% was disposed of in
landfills and 1% by composting. The remaining sludge,
Received April 11, 2009; accepted September 22, 2009 dumped without any treatment, presents a considerable
E-mail: solid@tsinghua.edu.cn environmental risk.
Wei WANG et al. Possible solutions for sludge dewatering in China 103

Fig. 1 Generation of municipal sewage and dewatered sewage sludge in China

According to the latest national standard‘Disposal of


Sludge from Municipal Wastewater Treatment Plant:
Sludge Quality for Co-landfill’, issued in 2007, only
sludge with a water content below 60% can be accepted by
landfills. In fact, this standard has become a great barrier
for sludge disposal through landfills. Taking the situation
in Beijing as an example, 1731 tons of dewatered sewage
sludge was generated every day in 2007 [1]. Because of the
standard limitation, none of the landfills located in this
urban area were permitted to accept the sludge. Only a
small amount of the sludge generated in the WWTPs in the
suburbs entered the gates of nearby landfills. In recent
years, a new disposal method was studied that combined
the sludge with aged refuse in landfills [7]. Landfill is the
major disposal method for sludge in Chongqing, and lime
is added to decrease the water content and to increase the
shear strength of the sludge [8]. On the whole, there is little
evidence that the situation of landfills for sludge disposal
will undergo any significant change, restricted as it is by
Fig. 2 Disposal status of sludge generated from WWTPs with a the national standard and the unwillingness of landfill
capacity over 2105 tons per day in 2006 managers. Zhu et al. [9] developed a solidification/
stabilization method for sludge landfill and a pilot study
2 Status of sludge disposal technology in has been completed. This process was used to reduce
China sludge moisture in Shenzhen and the treated sludge was
directly transported to the landfill site. A disadvantage of
2.1 Sludge disposal by landfill the method became evident when it was found that the
reagent mixed with the sludge increased the pH of the
In some developed countries, a special sanitary landfill is sludge and was likely to preclude further microorganism
required for sludge to be disposed of by way of landfill [4]. activity in the landfill.
The construction standards for these types of landfill are
stricter than for municipal solid waste landfills; thus, the 2.2 Sludge composting technology
construction cost is higher [5,6]. In China, sludge is treated
along with municipal solid waste in the same landfills. The Composting technology has matured into a well-developed
high water content creates problems with the compaction treatment method for both municipal solid waste and
of waste at the landfill site, and it also influences the sludge. The sludge compost sold well as a fertilizer about
stability of the waste body. ten years ago. However, with the development of the
104 Front. Environ. Sci. Engin. China 2010, 4(1): 102–107

WWTPs, industrial wastewater also began to be treated in or heat drying), or incineration. In general, anaerobic
the WWTPs, mixed with municipal wastewater. The high digestion does not improve sludge dewaterability. The
content of heavy metals in the industrial wastewater results of a series of surveys by the author, assessing the
decreased the scope for the application of the compost scale of sludge dewatering methods generally in use and
produced by the sludge composting processes. Chen et al. the water content demand of different sludge disposal
[10] developed a fast sludge composting process that has methods are summarized in Fig. 3. Sludge composting
been used in several projects. With this process, a capacity processes can only treat sludge with a water content below
of 300 tons per day was reached. To improve the fertilizer 60%. The water content of a sludge compost product
value, some additional measures were also examined, such should be lower than 40%, according to the national
as adding pig manure to the sludge during composting standard, the ‘Best Available Techniques Directive for
[11]. Treatment and Disposal of Sludge from Wastewater
In small urban areas, the volume of dewatered sludge Treatment Plant’ issued by the Ministry of Housing and
generated was modest, therefore the sludge compost Urban-Rural Department in 2009. Incineration is not
produced could be used as fertilizer on the farm fields suitable for dewatered sewage sludge disposal without
nearby. Even if it could not all be used as fertilizer, any other supplementary means because the heat value of
composting could also act as a bio-safety treatment for the 80% water content sludge is too low for steady incineration
sludge. However, in the large cities, composting as a and pollution control. During incineration, increased
disposal method was simply not effective enough. The amounts of auxiliary fuel need to be consumed in the
large amount of sludge took excessive areas of land for incinerator.
composting on the one hand, and on the other hand, it was According to the latest national standard, the sludge
difficult to sell all of the compost produced as fertilizer. For water content for landfill disposal must be lower than 60%.
this reason, sludge composting technology is now rarely Therefore, only if the moisture in sludge is reduced to
used in big cities. 50%–60%, can it be treated by composting, landfill, or
incineration.

3 Influence of sludge dewatering 3.2 Influence of water distribution on sludge dewatering


performance on disposal practice
The most challenging problem in sludge treatment is to
3.1 Influence of water content on sludge disposal reduce the water content to 60% through effective and
cost-effective methods. Essentially, the dewaterability is
Dewatering is a key issue for reducing sludge amounts. determined by the water distribution in the sludge. In the
Conventional dewatering methods, such as centrifugal early 1970 s, Vesilind [12] classified the following kinds of
force or pressurized filters, removes excess water from water in sludge: free water, interstitial water, surface or
thickened sludge, and then the dewatered sewage sludge is vicinal water, and hydration water. The special cellular and
disposed of by composting, landfill, drying (e.g., pelletized colloid structure creates difficulties in sludge dewatering,

Fig. 3 Scale of sludge dewatering methods and water content demand of different sludge disposal methods
Wei WANG et al. Possible solutions for sludge dewatering in China 105

and the high water content is the bottleneck in the sludge


treatment and disposal process. At present, conventional
dewatering methods can only remove 15%–30% of the
water from concentrated sludge with a water content of
95%. Carberry [13] gave a quantitative water distribution
for concentrated sludge, indicating that 70% of the total
water was interstitial water, 22% was surface and capillary
water, and 8% was cellular water.
In recent years, substantial numbers of tests have been
carried out to determine the bound water and free water in
dewatered sludge. Interstitial water, surface or vicinal
water, and hydration water are also classified as bound
water. The bound water is defined as that portion of water
that is not removed by mechanical dewatering. A precise
measurement of bound water content is desirable for
sludge treatment engineering. Several comprehensive
studies to measure the bound water in sludge are available.
The aqueous phase is generally described as free water and
bound water. The bound water requires much more energy Fig. 4 Relationship between dewatering energy demand and
to be removed. The bound water content is one of the sludge water content
major limiting factors for water removal efficiency.
Different methods are used to define bound water and to 4 Improve sludge dewatering by thermal
measure the energy in the bound water of the sludge solids. drying and hydrothermal treatment of sludge
Heukelekian [14] defined bound water as the water that is
still not free when the temperature is below 0°C. Kopp [15] 4.1 Application of thermal drying technology
found that hydrolyzation of organic materials by heating
the sludge is conducive to the removal of bound water. In order to release bound water from sludge, different
Specific resistance to filtration (SRF) and capillary suction methods have been developed based on the sludge cell
time (CST) also decreased after heat treatment. disruption, such as hydrothermal treatment, chemical
Heat treatment has been recognized for many years as a treatment [19], ultrasonic treatment [20], thermal chemical
useful means of sludge conditioning [16]. In heat treatment [21], and the freeze-thaw method. Direct thermal
treatment, liquid sludge is heated up to about 160°C– drying is another method that can result in a nearly entirely
180°C for over 30 min. This method effectively breaks dry sludge. The water in the sludge is vaporized by contact
down the sludge gel network and decreases the water with a heating interface or a high temperature gas. As a
affinity of the sludge solid. As a result, the sludge can be popular dewatering method, sludge thermal drying has also
readily dewatered. The hydrolysis of organics is a been used in China. In 2004, the first sludge thermal drying
dominant characteristic that distinguishes heat treatment plant was constructed at the Shanghai Shidongkou WWTP,
from other pretreatment methods. The viscosity of heat- with a capacity of 200 tons of dewatered sewage sludge per
treated sludge decreases significantly. In general, the day [22–23]. However, the operation and cost of this
energy input of sludge water removal follows a rising facility has not yet been reported in any scientific journal.
curve. Based on the experimental methods of Lee et al. The dried sludge was incinerated at the end of the process,
[17] and Chu et al. [18], a comparison of the binding but there are no further operational details available.
strength between a series of raw sludge samples and heat- Another sludge drying facility is under construction in
treated sludge samples was made by the author and is Gaobeidian WWTP, which should be able to treat 800 tons
illustrated in Fig. 4. In the low water content range, the of dewatered sewage sludge per day.
binding strength was low and nearly 20% of the water was Sludge drying is a popular technology, as it is effective
readily removed. Once the water content decreased to for the reduction of retained water in sludge. However, it
about 80%, the binding strength of the raw sludge rose has the disadvantage of consuming a very large amount of
sharply. This inferred that the sludge could no longer be energy. The energy obtained from the thermal output of dry
dewatered, probably because the general dewatering sludge incineration is less than the energy input required
equipment could no longer provide sufficient force. For for sludge drying, considering the thermal efficiency of
heat-treated sludge, the curve inflexion appeared at a water incineration and drying, making it a particularly inefficient
content of about 55%, which meant that the heat-treated overall process. The latent heat of vaporizing 1 kg of water
sludge could be dewatered to 50% by traditional dewater- was 3150 kJ, which is the largest part of the energy
ing methods. consumption during the drying process and accounts for
106 Front. Environ. Sci. Engin. China 2010, 4(1): 102–107

Fig. 5 Solid-liquid separation of sludge before and after hydrothermal treatment. (a) Untreated sludge (300); (b) hydrothermally
treated sludge (300)

around 50% of the total thermal drying process cost. The a capacity of 15 tons of dewatered sewage sludge per day.
application of sludge drying technology has therefore been This process allowed an increased sludge feed concentra-
restricted due to its prohibitive energy costs. tion, which resulted in energy savings in the sludge heating
process. Figure 6 shows a photograph of the pilot plant
4.2 Principal and technology of sludge hydrothermal apparatus.
treatment

Hydrothermal treatment is another pre-treatment method


used for improving the dewaterability of sludge [24].
During this process, the sludge is heated to between 160°C
and 180°C for 30–60 min at the corresponding vapor
pressure. A partial solution is made from the sludge treated
by thermal hydrolysis, and the biological cells are
disintegrated. This creates a sludge that is more suitable
for dewatering and digestion. Dewaterability tests carried
out as a Cambi process showed an increase in the
dewaterability [25]. As cell water is set free by thermal
hydrolysis, the viscosity of the sludge also decreased.
Thus, a sludge of about 12% dry solid (DS) could be
handled in the same way as a raw sludge of 5%–6% DS. Fig. 6 Hydrothermal process pilot (2008, Dongguan)
Hydrothermal technology, by significantly increasing the
dewaterability of the sludge, therefore provides a promis- 5 Conclusions
ing way for using a higher sludge concentration in the
digester feed, for providing a higher buffer capacity, and The proper disposal of sewage sludge is an important
for ensuring a stable digestion process. measure for environmental protection, especially in highly
Figure 5 [26] shows the change of sludge solid-liquid populated cities in China. The large volume of sewage
separation performance after a hydrothermal treatment. sludge and its low disposal rate has become a bottleneck
Differential scanning calorimetry (DSC) was used to for urban development. Landfill, composting, and incin-
analyze water distribution of the sludge. The bound eration are the three traditional disposal methods for
water content decreased from 3.6 g per solid sludge to municipal solid waste, and have also been incorporated in
1.0 g. The bound water proportion of the total sludge sludge disposal. However, the low dewatering and
decreased from 70% of the raw sludge to 30%–40% of the digestion properties of the sludge currently limit the
treated sludge. application of these three methods as effective means of
The hydrothermal process was also studied in a sludge sludge disposal. Decreasing the water content from 80% to
treatment field in China. The first pilot plant was built in 50% has been a key issue in improving sludge disposal
2002 at the Qinghe WWTP in Beijing and used a low- efficiency. Thermal drying technology and hydrothermal
pressure oxidation process [27]. In 2008, an innovative technology are two promising methods for sludge
pilot project, based on a hydrothermal process, was dewatering. Thermal drying technology can decrease the
developed by the author’s group in Dongguan City, with water content to lower levels than can hydrothermal
Wei WANG et al. Possible solutions for sludge dewatering in China 107

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