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When welding stronger steel materials, Hydrogen Assisted Cold Cracking (HACC) is a real
problem. HACC is characterized by cracks that form in the weld and/or heat affected zone of the
base metal once the weldment reduces temperature. With adequate welding procedures, and care
during welding, HACC can largely be eliminated.
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A widely held theory is that hydrogen atoms diffuse through the metal, and collect at “spaces” in
the microstructure of the metal. This would typically be at inclusions in the metal, and at grain
boundaries of the metal. Once the atomic hydrogen collects, it transforms to molecular hydrogen
(H2) or even reacts with carbon to form methane at these points where it collects. Once the
hydrogen is no longer existing as a single atom, it becomes too large to easily diffuse through the
metal structure. Over time, more and more hydrogen collects and results in excessive “pressure” at
these very localized points. It is argued that the pressure can grow to be so large, that it results in
the material “splitting apart”. This splitting apart under the pressure caused by the hydrogen is then
seen as hydrogen cracking. There are problems with this theory, when taken in isolation.
Another theory is that hydrogen collects around inclusions in the metal, such as carbide inclusions.
When the material then experiences a slow plastic deformation, (as may be present when welds
shrink as they cool to room temperature) the hydrogen atoms are “dragged along” by moving
defects (called dislocations) until the hydrogen atoms effectively pin the dislocations. When this
happens, plastic deformation can no longer take place, and the material acts in a brittle manner. It
is important to note that ductility in metals is due to the movement of dislocations. If dislocations
can no longer move, then there is no longer any ductility.
Regardless of the exact mechanism, we know that hydrogen cracking occurs when all of the
following conditions are met:
Maintain a high heat input when welding: A high heat input is just another way of
saying that the amount of energy applied while welding, is high. Heat input is
generally measured as the voltage times the amperage, divided by the welding
travel speed. A high heat input generally results in slower cooling rates, which
generally results in more ductile microstructures. In addition, there is a slightly
longer time at an elevated temperature, which allows more hydrogen to “bake out”
before the temperature gets low enough to allow cold cracking to occur.
Use a material that is unlikely to form hard, brittle microstructures: Typically
this is done by using materials with low carbon equivalents. Modern steel mills
manage to obtain high material strengths with low carbon equivalents, by using the
thermo-mechanically controlled process (TMCP) when rolling the steel to final
shape.
Use a filler metal that is weaker than the parent metal being welded: If the weld
metal is significantly weaker than the base metal, and it is very ductile, then when
the weld is stressed, the plastic deformation will largely be limited to the weld metal
and not the base metal. As the weld metal does not have a susceptible
microstructure, hydrogen cracking would be unlikely. Obviously this does mean that
the weld is weaker than the base metal, so the weld does not take full advantage of
the material strength. To overcome this, the weaker weld metal is typically only
used for one or two weld runs, and the rest of the weld runs are made with over-
matching filler metal. This works, because hydrogen cracking is most prevalent in
the weld while the cross section is small. Once the weld becomes “thick enough”, it
experiences much less plastic deformation when exposed to thermal stresses, so
the probability of hydrogen cracking is reduced.
Ensure that the time delay between weld runs is minimized: As hydrogen
cracking tends to be a time dependent mechanism, the probability of cracking can
be reduced by ensuring that the next weld run, which will then raise the weld
temperature again, is placed before the weld has had enough time to cool down,
and for the hydrogen to accumulate around inclusions in the material. The most
critical time delay is between the first and second weld runs. For this reason, the
second weld run is often termed a “hot pass”. The idea being that this pass needs
to be deposited as soon as possible, while the weld is still “hot”. This hot pass also
acts to heat the weld back up to a temperature above which the hydrogen can be
“baked out” of the weld. As a general rule, if the time from the start of the root pass,
to the start of the hot pass can be kept to less than 8 minutes, then hydrogen
cracking is unlikely. Sometimes this is achieved by having more than one welder
welding on a weld at a time.
Use of an austenitic filler metal: This is unusual, but works well if there are no
problems with the use of an austenitic weld metal. This works because the
austenitic weld metal can “dissolve” all the hydrogen that will realistically be
generated during welding. This means that there is not much of a driving force for
pushing the hydrogen into the base metal, therefore hydrogen cracking is unlikely.
Unfortunately there are a number of disadvantages to this. The first is that typical
300 series weld metals are weaker than high strength steels, so you need to use
high nickel content austenitic fillers for strength matching. These fillers are
expensive. Typical 300 series stainless steel materials are also susceptible to
stress corrosion cracking in certain environments, so they would not be suitable for
those applications. Another problem is galvanic corrosion that can be experienced
when carbon steels and corrosion resistant alloys are in contact in a corrosive
environment.
Reduce the applied stresses on the weld as far as possible, until you have managed
to deposit a relatively thick weld cross section: As an example, when performing
pipeline welding, the alignment clamps holding the joint together are not removed until most
of the weld has been deposited. Another example is to ensure the best fit-up possible
between pipe ends when welding. The worse the fit-up, the greater the stresses that the
weld experiences, especially in the root region of the weld. Another example is to complete
welding before moving the weld joint. If the pipe is re-positioned when only the root run has
been deposited, then the stresses my be high enough to result in hydrogen cracking.
While most mainline pipeline welds are done with automated welding these days, a lot of pipeline
projects still use cellulosic electrodes for the “tie-in” welds. The reason is that cellulosic electrodes
have a very penetrating arc, so they are well suited to performing root runs on pipes. The slag is
also quick freezing, allowing a vertical down welding progression to be used. This further increases
the welding speed and productivity.
Pipeli
ne Welding With Cellulosic SMAW Electrodes: This situation is one of the most susceptible to
Hydrogen Assisted Cold Cracking.
The big problem with cellulosic electrodes is that they rely on moisture in the flux coating to provide
these advantages. By design then, cellulosic electrodes result in high amounts of hydrogen being
present. It must be accepted that when welding with cellulosic electrodes there is always enough
hydrogen present to result in hydrogen cracking if all the other factors are also present.
In addition to high welding productivity, pipeline economics tend to favor the use of high strength
pipeline steels. (Then the pipeline can be thinner.) Such high strength steels are typically more
prone to hydrogen cracking than lower strength steels would be. Due to this combination of high
strength steels being welded with high hydrogen welding methods, hydrogen assisted cold
cracking (HACC) is a big focus on pipeline projects. In fact, most cross country pipeline codes
have a high focus on welding variables that can result in hydrogen cracking. For this reason these
welding codes tend to have a lot of essential variables that are not addressed in other welding
codes. It is also important to note that most modern pipeline steels are Thermo-Mechanically
Controlled Process (TMCP) steels, which increases the steels’ resistance to hydrogen cracking.
It is important to note that these days there are alternatives to using cellulosic electrodes, but often
the specific economics of a pipeline project may still push the project engineers to use cellulosic
electrodes.
In the case of sub-sea pipelines the use of cellulosic electrodes are usually not allowed. This is
because time delays are normally specified between a weld being completed and the start of non
destructive testing, (NDT) when welding with a high hydrogen welding process. Typical minimum
time delays between completing the weld and commencing the NDT would be 48 hours when
using cellulosic electrodes. This is done because it allows enough time to make sure that if
hydrogen assisted cold cracking (HACC) is going to occur, that it does in fact occur before the
testing is performed. When welding on a lay barge, such time delays would add huge costs to the
pipelay operation. Technically and economically the use of cellulosic electrodes is therefore just
not feasible.
Besides the standards referenced above, there are many books that deal with the welding of steels
without hydrogen cracking, but the use of one of the standards above will probably be sufficient for
most circumstances.